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Despite the importance of the electron correlation in the first-principles description of the Li-ion cathode materials, the Coulomb interaction parameter, U is often treated as an ad hoc value. In practice, one usually relies on empirical…

Materials Science · Physics 2021-03-10 Bongjae Kim , Kyoo Kim , Sooran Kim

We propose a refined scheme of deriving an effective low-energy Hamiltonian for materials with strong electronic Coulomb correlations beyond density functional theory (DFT). By tracing out the electronic states away from the target degrees…

Strongly Correlated Electrons · Physics 2017-08-09 Motoaki Hirayama , Takashi Miyake , Masatoshi Imada , Silke Biermann

The electronic structure of Fe impurity in MgO was calculated by the linear muffin-tin orbital--full-potential method within the conventional local-density approximation (LDA) and making use of the LDA+$U$ formalism. The importance of…

Condensed Matter · Physics 2009-10-22 M. Korotin , A. Postnikov , T. Neumann , G. Borstel , V. Anisimov , M. Methfessel

The total energies and the spin states for atoms and their first ions with Z = 1-86 are calculated within the the local spin-density approximation (LSDA) and the generalized-gradient approximation (GGA) to the exchange-correlation (xc)…

Chemical Physics · Physics 2015-05-20 Eli Kraisler , Guy Makov , Itzhak Kelson

In the density-functional studies of materials with localized electronic states, the local/semilocal exchange-correlation functionals are often either combined with a Hubbard parameter $U$ as in the LDA+$U$ method or mixed with a fraction…

Materials Science · Physics 2014-07-24 Mehmet Aras , Çetin Kılıç

We present an accurate implementation of total energy calculations into the local density approximation plus dynamical mean-field theory (LDA+DMFT) method. The electronic structure problem is solved through the full potential linear…

Strongly Correlated Electrons · Physics 2009-03-16 I. Di Marco , J. Minár , S. Chadov , M. I. Katsnelson , H. Ebert , A. I. Lichtenstein

We review our recently developed electronic structure calculation methods used for the dynamics of large-scale solids or liquids with an efficient algorithm for large scale simultaneous linear equations. The electronic structure calculation…

Materials Science · Physics 2011-02-02 T. Fujiwara , S. Yamamoto , T. Hoshi , S. Nishino , H. Teng , T. Sogabe , S. -L. Zhang , M. Ikeda , M. Nakashima , N. Watanabe

We present an accurate, first-principles study of the electronic structure and absorption spectrum of bulk copper within Density Functional Theory in the Local Density Approximation (DFT-LDA), including the study of intraband transitions.…

Materials Science · Physics 2009-11-07 Andrea Marini , Giovanni Onida , Rodolfo Del Sole

The random phase approximation (RPA) for the correlation energy functional of density functional theory has recently attracted renewed interest. Formulated in terms of the Kohn-Sham (KS) orbitals and eigenvalues, it promises to resolve some…

Other Condensed Matter · Physics 2009-11-13 Hong Jiang , Eberhard Engel

The most intriguing properties of emergent materials are typically consequences of highly correlated quantum states of their electronic degrees of freedom. Describing those materials from first principles remains a challenge for modern…

Strongly Correlated Electrons · Physics 2018-04-04 Pascal Delange , Steffen Backes , Ambroise van Roekeghem , Leonid Pourovskii , Hong Jiang , Silke Biermann

Ab initio electronic structure calculations of two-dimensional layered structures are typically performed using codes that were developed for three-dimensional structures, which are periodic in all three directions. The introduction of a…

Strongly Correlated Electrons · Physics 2016-06-22 Paolo E. Trevisanutto , Giovanni Vignale

The RPA long range correlations are known to play a significant role in understanding the depletion of single particle-hole states observed in (e, e') and (e, e'p) measurements. Here the Random Phase Approximation (RPA) theory, implemented…

Nuclear Theory · Physics 2009-11-11 M. Dupuis , S. Karataglidis , E. Bauge , J. P. Delaroche , D. Gogny

We perform ab initio electronic structure calculations of the intermetallic compound CeFeGe3 by means of the Tight Binding Linear Muffin-Tin Orbitals-Atomic Sphere Approximation (TB-LMTO-ASA) within the Local Spin Density Approximation…

Strongly Correlated Electrons · Physics 2007-05-23 E. Chigo Anota , A Flores Riveros , J. F. Rivas Silva

In recent years, two-dimensional twisted systems have gained increasing attention. However, the calculation of electronic structures in twisted material has remained a challenge. To address this, we have developed a general computational…

Mesoscale and Nanoscale Physics · Physics 2025-03-17 Junxi Yu , Shifeng Qian , Cheng-Cheng Liu

Ab-initio, self-consistent electronic energy bands of rutile TiO2 are reported within the local density functional approximation (LDA). Our first principle, non-relativistic and ground state calculations employed a local density functional…

Materials Science · Physics 2012-03-23 C. E. Ekuma , D. Bagayoko

By introducing a set of auxiliary equations representing a many-body system, we have derived an extension of the Kohn-Sham scheme for the density functional theory. These equations consist of a Kohn-Sham-type equation determining…

Materials Science · Physics 2009-11-07 Koichi Kusakabe

The reliable {\it ab-initio} description of strongly correlated materials is a long-sought capability in condensed matter physics. The $GW$+EDMFT method is a promising scheme, which provides a self-consistent description of correlations and…

Strongly Correlated Electrons · Physics 2021-12-08 Francesco Petocchi , Viktor Christiansson , Philipp Werner

The random phase approximation (RPA) has emerged as a prominent first-principles method in material science, particularly to study the adsorption and chemisorption of small molecules on surfaces. However, its widespread application is…

Materials Science · Physics 2025-09-01 Edoardo Spadetto , Pier Herman Theodoor Philipsen , Arno Förster , Lucas Visscher

One of the goals in the development of large scale electronic structure methods is to perform calculations explicitly for a localised region of a system, while still taking into account the rest of the system outside of this region. An…

Materials Science · Physics 2009-10-01 J. R. Trail , D. M. Bird

The ring-diagram partial summation (or RPA) for the ground-state energy of the uniform electron gas (with the density parameter $r_s$) in its weak-correlation limit $r_s\to 0 $ is revisited. It is studied, which treatment of the self-energy…

Strongly Correlated Electrons · Physics 2015-06-25 Paul Ziesche