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The discovery of fluid states of matter with spontaneous bulk polar order is appreciated as a major discovery in the fields of soft matter and liquid crystals. Typically, this manifests as polar order superimposed atop conventional phase…

Soft Condensed Matter · Physics 2024-11-22 Jordan Hobbs , Calum J. Gibb , Damian Pociecha , Jadwiga Szydłowska , Ewa Górecka , Richard. J. Mandle

There is a large variety of bi-layered structures with smectic A type ordering. Results of this paper contribute to a theory of bi-layered phases. The difference between the \( SmC^{*}_{A} \) and \( SmC_{\alpha}^{*} \) phases is described…

Soft Condensed Matter · Physics 2017-10-18 Matej Hudak , Ondrej Hudak

Under an electric field, chiral smectic liquid crystals transit usually to the unwound SmC* phase where the helical structure is completely unrolled. Sometimes the sample transits initially towards an intermediate polar state before the…

Soft Condensed Matter · Physics 2019-10-02 H. Dhaouadi , O. Riahi , R. Zgueb , F. Trabelsi , T. Othman

Spontaneous symmetry breaking and emergent polar order are each of fundamental importance to a range of scientific disciplines, as well as generating rich phase behaviour in liquid crystals (LCs). Here, we show the union of these phenomena…

Soft Condensed Matter · Physics 2024-08-06 Calum Gibb , Jordan Hobbs , Diana Nikolova , Tom Raistrick , Helen Gleeson , Richard Mandle

In our previous study, we demonstrated the existence of an unidentified ferroelectric smectic phase in the low-temperature region of the ferroelectric smectic A phase, where the layer spacing decreases with decreasing temperature. In the…

We have structurally characterized the liquid crystal phase that appears as an intermediate state when a dielectric nematic, having polar disorder of its molecular dipoles, transitions to the almost perfectly polar-ordered ferroelectric…

We report the smectic $A_F$, a new liquid crystal phase of the ferroelectric nematic realm. The smectic $A_F$ is a phase of small polar, rod-shaped molecules which form two-dimensional fluid layers spaced by approximately the mean molecular…

Experimental and modeling/simulation studies of phase equilibrium and growth morphologies of novel polymer-dispersed liquid crystal (PDLC) mixtures of PS (polystyrene) and liquid crystals that exhibit a direct isotropic/smectic-A (lamellar)…

Soft Condensed Matter · Physics 2015-05-13 Ezequiel R. Soule , Nasser Mohieddin Abukhdeir , Alejandro D. Rey

Two-dimensional polar liquid crystals have been discovered recently in monolayers of anisotropic molecules. Here, we provide a systematic theoretical description of liquid-crystalline phases for polar particles in two spatial dimensions.…

Soft Condensed Matter · Physics 2014-01-28 Raphael Wittkowski , Hartmut Löwen , Helmut R. Brand

The smectic C (smC) phase represents a unique class of liquid crystal phases characterised by the layered arrangement of molecules with tilted orientations with respect to layer normals. Building upon the real-valued tensorial smectic A…

Soft Condensed Matter · Physics 2024-08-09 Jingmin Xia , Yucen Han

The recent discovery of spontaneous chiral symmetry breaking has demonstrated the possibility of discovering the exotic textures of ferromagnetic systems in liquid crystalline fluid ferro-electrics. We show that the polar smectic mesophase…

Soft Condensed Matter · Physics 2025-08-22 Jordan Hobbs , Calum J. Gibb , Richard J. Mandle

Recently, a new class of smectic liquid crystal phases (SmCP phases) characterized by the spontaneous formation of macroscopic chiral domains from achiral bent-core molecules has been discovered. We have carried out Monte Carlo simulations…

Statistical Mechanics · Physics 2009-11-07 Yves Lansac , Prabal K. Maiti , Noel A. Clark , Matthew A. Glaser

Ionic liquid crystals (ILCs) are anisotropic mesogenic molecules which carry charges and therefore combine properties of liquid crystals, e.g., the formation of mesophases, and of ionic liquids, such as low melting temperatures and tiny…

Soft Condensed Matter · Physics 2017-10-31 Hendrik Bartsch , Markus Bier , Siegfried Dietrich

The order parameters for the phenomenological description of the smectic-{\it A} to smectic-{\it C} phase transition are formulated on the basis of molecular symmetry and structure. It is shown that, unless the long molecular axis is an…

Soft Condensed Matter · Physics 2016-08-31 P. K. Karahaliou , A. G. Vanakaras , D. J. Photinos

The hexatic phase predicted by the theories of two-dimensional melting is characterised by the power law decay of the orientational correlations whereas the in-layer bond orientational order in all the hexatic smectic phases observed so far…

Soft Condensed Matter · Physics 2018-05-16 Lorenzo Agosta , Alfredo Metere , Mikhail Dzugutov

We present a model for smectic elastomer membranes which includes elastic and liquid crystalline degrees of freedom. Based on our model, we determined the qualitative phase diagram of a smectic elastomer membrane using mean-field theory.…

Soft Condensed Matter · Physics 2009-11-13 Olaf Stenull

The discovery of the ferroelectric nematic phase has brought with it a plethora of new polar liquid crystalline phases. One in particular is the anti-ferroelectric smectic A SmA\textsubscript{AF} phase. In this letter we show via…

We investigate the phase behaviour of a two-dimensional colloidal model system of ultra-soft particles on a substrate which varies periodically along one spatial direction. Our calculations are based on mean-field density functional theory…

Soft Condensed Matter · Physics 2021-03-17 Alexander Kraft , Sabine H. L. Klapp

Following the groundbreaking discovery of the ferroelectric nematic liquid crystal phase (NF), a series of closely-related new polar phases have also been found. An especially interesting one is the ferroelectric smectic A phase (SmAF) with…

Soft Condensed Matter · Physics 2024-11-14 Aitor Erkoreka , Minjung Huang , Satoshi Aya , Josu Martinez-Perdiguero

Smectic liquid crystals are materials formed by stacking deformable, fluid layers. Though smectics prefer to have flat, uniformly-spaced layers, boundary conditions can impose curvature on the layers. Since the layer spacing and curvature…

Differential Geometry · Mathematics 2007-05-23 Randall D. Kamien , Christian D. Santangelo
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