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In this study, variations with respect to temperature of the increments of enthalpy and Gibbs energy, arising in the dissolution of proteins in water, have been investigated by the methods of statistical thermodynamics. In this formalism,…

Statistical Mechanics · Physics 2007-05-23 G. Oylumluoglu , F. Buyukkilic , D. Demirhan

New methods are presented which enables one to analyze the thermodynamics of systems with long-range interactions. Generically, such systems have entropies which are non-extensive, (do not scale with the size of the system). We show how to…

General Relativity and Quantum Cosmology · Physics 2009-11-07 Jonathan Oppenheim

We study the problem of heat conduction in general relativity by using Carter's variational formulation. We write the creation rates of the entropy and the particle as combinations of the vorticities of temperature and chemical potential.…

General Relativity and Quantum Cosmology · Physics 2022-11-28 Hyeong-Chan Kim , Youngone Lee

This work is concerned with our recently developed formalism of non-equilibrium thermodynamics. This formalism extends the classical irreversible thermodynamics which leads to classical thermodynamics and can not describe physical phenomena…

Analysis of PDEs · Mathematics 2018-09-06 Zaibao Yang , Wen-An Yong , Yi Zhu

We discuss that the thermodynamical Legendre transform structure can be retained not only for the arbitrary entropic form but also for the arbitrary form of the energy constraints by following the discussion of Plastino and Plastino. The…

Statistical Mechanics · Physics 2009-10-31 Takuya Yamano

Local thermal equilibrium generally implies the absence of heat flux within a fluid. We find the relations between a set of thermodynamic variables of a fluid on a general spacetime and those defined on a conformally connected spacetime,…

General Relativity and Quantum Cosmology · Physics 2025-07-09 Bhera Ram , Bibhas Ranjan Majhi

For general quantum systems the power expansion of the Gibbs potential and consequently the power expansion of the self energy is derived in terms of the interaction strength. Employing a generalization of the projector technique a compact…

Statistical Mechanics · Physics 2019-07-18 T. Plefka

Starting out with an entropy identity, the entropy flux, the entropy production and the corresponding Gibbs and Gibbs-Duhem equations of general-covariant conti\-nuum thermodynamics are established. Non-dissipative materials and equilibria…

General Relativity and Quantum Cosmology · Physics 2017-03-08 Wolfgang Muschik , Horst-Heino v. Borzeszkowski

We obtain macroscopic isothermal thermodynamic transformations by space-time scalings of a microscopic Hamiltonian dynamics in contact with a heat bath. The microscopic dynamics is given by a chain of anharmonic oscillators subject to a…

Statistical Mechanics · Physics 2013-10-03 Stefano Olla

Macroscopic thermodynamics of equilibrium is constructed for systems obeying power-law canonical distributions. With this, the connection between macroscopic thermodynamics and microscopic statistical thermodynamics is generalized. This is…

Statistical Mechanics · Physics 2009-10-31 Sumiyoshi Abe , A. K. Rajagopal

In this paper a thermodynamical derivation of the quantum potential is pro- posed. Within the framework of Bohmian mechanics we show how the quantum potential can be derived, by adding an additional informational degree of freedom to the…

Quantum Physics · Physics 2019-06-04 Luca Curcuraci , Mehdi Ramezani

Although its practical efficiency is unquestionable, it is well known that thermodynamics presents conceptual difficulties from the theoretical point of view. It is shown that the problem comes from an imperfect compatibility between the…

General Physics · Physics 2007-05-23 Jean-Louis Tane

We take the perspective of open quantum systems and examine from their nonequilibrium dynamics the conditions when the physical quantities, their relations and the laws of thermodynamics become well defined and viable for quantum many body…

Quantum Physics · Physics 2018-01-30 Jen-Tsung Hsiang , C. H. Chou , Y. Subaşi , B. L. Hu

Relativistic effects in the thermodynamical properties of interacting particle systems are investigated within the framework of the relativistic direct interaction theory in various forms of dynamics. In the front form of relativistic…

High Energy Physics - Theory · Physics 2007-05-23 V. Tretyak

To describe the nonequilibrium states of the system, a new thermodynamic parameter - system lifetime - is introduced. Statistical distributions that describe the behavior of energy and lifetime are recorded. Entropy and obtained…

Statistical Mechanics · Physics 2019-10-14 V. V. Ryazanov

After reviewing some fundamental results derived from the introduction of the generalized Gibbs canonical ensemble, such as the called thermodynamic uncertainty relation, it is described a physical scenario where such a generalized ensemble…

Statistical Mechanics · Physics 2007-05-23 L. Velazquez

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

Chemical Physics · Physics 2007-05-23 Elias P. Gyftopoulos

We write explicitly the Euler identity and the Gibbs-Duhem relation for thermodynamic potentials that are not homogeneous first-order functions of their natural extensive variables. We apply the rules to the theory of geometrothermodynamics…

General Relativity and Quantum Cosmology · Physics 2014-06-26 Mustapha Azreg-Aïnou

We review the main aspects of geometrothermodynamics, a formalism that uses contact geometry and Riemannian geometry to describe the properties of thermodynamic systems. We show how to handle in a geometric way the invariance of classical…

General Relativity and Quantum Cosmology · Physics 2023-07-26 Orlando Luongo , Hernando Quevedo

The one-loop effective potential for non-relativistic bosons with a delta function repulsive potential is calculated for a given chemical potential using functional methods. After renormalization and at zero temperature it reproduces the…

Statistical Mechanics · Physics 2009-10-30 T. Haugset , H. Haugerud , F. Ravndal