Related papers: Thermodynamic potentials and Thermodynamic Relatio…
In recent papers, several authors have claimed that a definition of the thermodynamic entropy in terms of the logarithm of a volume in phase space, originally suggested by Gibbs, is the only valid definition. Arguing from the Gibbs entropy,…
Macroscopic nonextensive thermodynamics is studied without recourse to microscopic statistical mechanics. It is shown that if entropy is nonextensive, the concept of physical temperature introduced through the generalized zeroth law of…
Classical gravitation is treated from the point of view of non-equilibrium thermodynamics. Gravitational potential is a thermodynamic state variable in a weakly nonlocal treatment. Entropy production is calculated and the simplest solution…
Based on the Tsallis entropy, the nonextensive thermodynamic properties are studied as a q-deformation of classical statistical results using only probabilistic methods and straightforward calculations. It is shown that the constant in the…
Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…
'Relativistic thermodynamics' should be understood not as a generalization of a non-relativistic theory but as an application of a general thermodynamic framework, neutral as to spacetime setting and allowing arbitrary conserved quantities,…
The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this letter, we…
Thermodynamic relations are derived from first principles of mechanics for non-equilibrium processes. Since the key role herein is played by the law of increase of entropy, the latter is analyzed at first. It is shown that its derivation…
Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…
Relativistic thermodynamics is treated from the point of view of kinetic theory. It is shown that the generalized J\"uttner distribution suggested in [1] is compatible with kinetic equilibrium. The requirement of compatibility of kinetic…
During the past dozen years there have been numerous articles on a relation between entropy and probability which is non-additive and has a parameter $q$ that depends on the nature of the thermodynamic system under consideration. For $q=1$…
The role of thermodynamics in continuum mechanics and the derivation of the proper constitutive relations is a discussed subject of Rational Mechanics. The classical literature did not use the accumulated knowledge of thermostatics and was…
A generally relativistic theory of thermodynamics is developed, based on four main physical principles: heat is a local form of energy, therefore described by a thermal energy tensor; conservation of mass, equivalent to conservation of…
The physical impossibility of heat transfer under isothermal conditions implies that the classical expression for the entropy of the ideal gas may not be compatible with the internal energy of the gas itself. A corrected expression of the…
The concepts of quantity of heat and work are deduced in the non-extensive statistical mechanics context, following steps in parallel to those employed in the extensive statistical mechanics.
Using the chemical potential of a solid in a dissolved state or the corresponding component of the chemical potential tensor at equilibrium with the solution, a new concept of grand thermodynamic potential for solids has been suggested.…
The equations of state for an ideal generalized gas, like an ideal quantum gas, are expressed in terms of power laws of the temperature. The reduction of an ideal generalized gas to an ideal classical case occurs when the characteristic…
Thermodynamic description of a model system with magnetoelastic coupling is presented. The elastic, vibrational, electronic and magnetic energy contributions are taken into account. The long-range RKKY interaction is considered together…
We explore thermodynamic relations in non-equilibrium steady states with numerical experiments on a driven lattice gas. After operationally defining the pressure and chemical potential in the driven lattice gas, we confirm numerically the…
The fundamental dynamic stability of heat conduction theories beyond Fourier is analyzed in the framework of nonequilibrium thermodynamics. It is shown, that the thermodynamic framework, concave entropy and nonnegative entropy production,…