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We present a first-principles investigation of ferroelectricity in layered perovskite oxide La2Ti2O7 (LTO), one of the compounds with highest Curie temperature known (1770 K). Our calculations reveal that LTO's ferroelectric transition…

Materials Science · Physics 2015-05-27 Jorge Lopez-Perez , Jorge Iniguez

The magnetic susceptibility, crystal and magnetic structures, and electronic structure of double perovskite Sr2ScOsO6 are reported. Using both neutron and x-ray powder diffraction we find that the crystal structure is monoclinic P21/n from…

Strongly Correlated Electrons · Physics 2015-04-06 A. E. Taylor , R. Morrow , D. J. Singh , S. Calder , M. D. Lumsden , P. M. Woodward , A. D. Christianson

Recently, halide perovskites have gained significant attention from the perspective of efficient spintronics owing to Rashba effect. This effect occurs as a consequence of strong spin-orbit coupling under noncentrosymmetric environment,…

Controlling grain orientations within polycrystalline all-inorganic halide perovskite solar cells can help increase conversion efficiencies toward their thermodynamic limits, however the forces governing texture formation are ambiguous.…

Recent neutron scattering and specific heat studies on the pyrochlore Yb2Ti2O7 have revealed variations in its magnetic behavior below 265mK. In the best samples, a sharp anomaly in the specific heat is observed at T=265mK. Other samples,…

Strongly Correlated Electrons · Physics 2013-02-01 K. A. Ross , Th. Proffen , H. A. Dabkowska , J. A. Quilliam , L. R. Yaraskavitch , J. B. Kycia , B. D. Gaulin

Transition-metal dichalcogenide IrTe2 has attracted attention because of striped lattice, charge ordering and superconductivity. We have investigated the surface structure of IrTe2, using low energy electron diffraction (LEED) and scanning…

Materials Science · Physics 2017-04-05 Chen Chen , Jisun Kim , Yifan Yang , Guixin Cao , Rongying Jin , E. W. Plummer

PbTiO3 has the highest tetragonal distortion (c/a=1.064) and highest spontaneous polarization among perovskite titanates. But, it is hazardous and hence one needs to reduce Pb content by substituting or reducing Pb content for use in…

The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

Materials Science · Physics 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

We present a computational investigation, in conjunction with synthesis and experimental characterization, into the structural, electronic, and optical properties of layered 2D organic lead bromide perovskites. We contrast materials based…

Materials Science · Physics 2025-10-29 Md Mehdi Masud , Jarek Viera , Azza Ben-Akacha , Biwu Ma , David A. Strubbe

Although the structural phase transitions in single-crystal hybrid methyl-ammonium (MA) lead halide perovskites (MAPbX3, X = Cl, Br, I) are common phenomena, they have never been observed in the corresponding nanocrystals. Here we…

Applied Physics · Physics 2020-04-08 Yuri D. Glinka , Rui Cai , Xian Gao , Dan Wu , Rui Chen , Xiao Wei Sun

We present the crystal growth as well as the structural, chemical and physical chracterization of SmRh$_2$Si$_2$ single crystals. Their ground state is antiferromagnetic, as indicated by the behaviour of the magnetic susceptibility and the…

Strongly Correlated Electrons · Physics 2019-05-03 Kristin Kliemt , Jacintha Banda , Christoph Geibel , Manuel Brando , Cornelius Krellner

The perovskite ruthenates (ARuO3, A = Ca, Ba, or Sr) exhibit unique properties owing to a subtle interplay of crystal structure and electronic-spin degrees of freedom. Here, we demonstrate an intriguing continuous tuning of crystal symmetry…

We use solid-state methods to synthesize single crystals of perovskite-phase cesium lead iodide (${\gamma}$-CsPbI3) that are kinetically stable at room temperature. Single crystal X-ray diffraction characterization shows that the compound…

Applied Physics · Physics 2019-07-10 Daniel B. Straus , Shu Guo , Robert J. Cava

The NaNO$_{2}$ nanocomposite ferroelectric material in porous glass was studied by neutron diffraction. For the first time the details of the crystal structure including positions and anisotropic thermal parameters were determined for the…

The use of oxide materials in oxide electronics requires their controlled epitaxial growth. Recently, it was shown that Reflection High Energy Electron Diffraction (RHEED) allows to monitor the growth of oxide thin films even at high oxygen…

Materials Science · Physics 2009-11-07 D. Reisinger , B. Blass , J. Klein , J. B. Philipp , M. Schonecke , A. Erb , L. Alff , R. Gross

A powder X-ray diffraction study, combined with the magnetic susceptibility and electric transport measurements, was performed on a series of LnCoO3 perovskites (Ln = Y, Dy, Gd, Sm, Nd, Pr and La) over a temperature range 100 - 1000 K. A…

Materials Science · Physics 2010-07-30 K. Knizek , Z. Jirak , J. Hejtmanek , M. Veverka , M. Marysko , G. Maris , T. T. M. Palstra

Single crystals of Cs2BiAgBr6 lead-free perovskite were grown by crystallization from supersaturated solution. According to characterization by XRD and EBSD methods the double perovskite single crystal are of the cubic Fm-3m symmetry with…

Angle-resolved photoemission spectroscopy is performed on single crystals of the single-layer high-Tc superconductor Bi(2)Sr(2-x)La(x)CuO(6+d) at optimal doping (x=0.4) in order to study in great detail the Zhang-Rice (ZR) singlet band at…

Superconductivity · Physics 2009-10-31 R. Manzke , R. Mueller , C. Janowitz , M. Schneider , A. Krapf , H. Dwelk

Single crystals of the Bi-Ca-Co-O system have been grown using the flux method with cooling from 900$\celsius$ and 950$\celsius$, respectively. The single crystals are characterized by transmission electron microscopy and X-ray diffraction.…

Materials Science · Physics 2009-11-13 X. G. Luo , Y. C. Jing , H. Chen , X. H. Chen

Inorganic lead-free double perovskites represent particular interest as non-toxic and stable material platform for optoelectronic applications. Here, we employ Brillouin light scattering spectroscopy to investigate the elastic properties…