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Among polycyclic aromatic hydrocarbons, pyrene is widely used as an optical probe thanks to peculiar ultraviolet absorption and infrared emission features. Interestingly, this molecule is also an abundant component of the interstellar…

Chemical Physics · Physics 2021-11-19 Katherine R. Herperger , Jannis Krumland , Caterina Cocchi

We investigate full quantum mechanical evolution of two electrons nonlinearly coupled to quantum phonons and simulate the dynamical response of the system subject to a short spatially uniform optical pulse that couples to dipole-active…

Statistical Mechanics · Physics 2025-03-06 K. Kovač , D. Golež , M. Mierzejewski , J. Bonča

We describe a method to probe the spectral fluctuations of a transition over broad ranges of frequencies and timescales with the high spectral resolution of Fourier spectroscopy, and a temporal resolution as high as the excited state…

Vibrationally resolved electronic absorption spectra including the effect of vibrational pre-excitation are computed in order to interpret and predict vibronic transitions that are probed in the Vibrationally Promoted Electronic Resonance…

Broadband laser ultrasonics and two dimensional Fourier transformation are used to characterize the properties of varieties of foils and plates. Laser ultrasonics generation is achieved by use of a pulsed laser which deposits pulsed laser…

Materials Science · Physics 2009-11-10 Xinya Zhang , Emmanuel Lafond , Ted Jackson

Nonlinear spectroscopic techniques using entangled photon pairs can provide an opportunity to exploit non-classical correlations encoded in two-photon wavefunctions to manipulate two-exciton wavefunctions. We propose an entangled photon…

Quantum Physics · Physics 2026-04-10 Arunangshu Debnath , Shaul Mukamel

An electromagnetic wave-packet propagating in a linear, homogeneous, and isotropic medium changes shape while its envelope travels with different velocities at different points in spacetime. In general, a wave-packet can be described as a…

Optics · Physics 2020-08-26 Masud Mansuripur

Coherent phonons can greatly vary light-matter interaction in semiconductor nanostructures placed inside an optical resonator on an ultrafast time scale. For an ensemble of quantum dots as active laser medium phonons are able to induce a…

Mesoscale and Nanoscale Physics · Physics 2018-09-27 D. Wigger , T. Czerniuk , D. E. Reiter , M. Bayer , T. Kuhn

We present a rapid-scanning approach to fluorescence-detected two-dimensional electronic spectroscopy that combines acousto-optic phase-modulation with digital lock-in detection. The approach shifts the signal detection window to suppress…

Representation of molecular vibrational degrees of freedom by independent harmonic oscillators, when describing electronic spectra or electronic excitation energy transport, raises unfavourable effects as vibrational energy relaxation…

Chemical Physics · Physics 2018-07-26 Mantas Jakučionis , Vladimir Chorošajev , Darius Abramavičius

How atoms and electrons in a molecule move during a chemical reaction and how rapidly energy is transferred to or from the surroundings can be studied with flashes of laser light. However, despite prolonged efforts to develop various…

Chemical Physics · Physics 2022-01-05 JunWoo Kim , Jonggu Jeon , Tai Hyun Yoon , Minhaeng Cho

The influence of an electron-vibrational coupling on the laser control of electron transport through a molecular wire that is attached to several electronic leads is investigated. These molecular vibrational modes induce an effective…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Jörg Lehmann , Sigmund Kohler , Volkhard May , Peter Hänggi

Processes involving ultrafast laser driven electron-phonon dynamics play a fundamental role in the response of quantum systems in a growing number of situations of interest, as evidenced by phenomena such as strongly driven phase…

Materials Science · Physics 2024-03-01 Kevin Lively , Shunsuke A. Sato , Guillermo Albareda , Angel Rubio , Aaron Kelly

Recent interest in the role of quantum mechanics in the primary events of photosynthetic energy transfer has led to a convergence of nonlinear optical spectroscopy and quantum optics on the topic of energy-transfer dynamics in…

Quantum Physics · Physics 2014-01-23 Agata M. Branczyk , Daniel B. Turner , Gregory D. Scholes

The correlated behavior of electrons determines the structure and optical properties of molecules, semiconductor and other systems. Valuable information on these correlations is provided by measuring the response to femtosecond laser…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Shaul Mukamel , Rafal Oszwaldowski , Lijun Yang

Two-dimensional electronic spectroscopy provides information on coupling and energy transfer between excited states on ultrafast timescales. Only recently, incoherent fluorescence detection has made it possible to combine this method with…

Optics · Physics 2025-05-14 Sanchayeeta Jana , Simon Durst , Lucas Ludwig , Markus Lippitz

Excited-state vibrational dynamics in molecules can be studied by an electronically off-resonant Raman process induced by a probe pulse with variable delay with respect to an actinic pulse. We establish the connection between several…

Chemical Physics · Physics 2013-09-27 Konstantin E. Dorfman , Benjamin P. Fingerhut , Shaul Mukamel

Electron energy loss spectroscopy is consolidating as a powerful tool to explore electronic (as well as vibrational) excitations of matter, including molecules. Performed in a scanning transmission electron microscope, this technique is…

Chemical Physics · Physics 2021-03-05 Ciro A. Guido , Enzo Rotunno , Matteo Zanfrognini , Stefano Corni , Vincenzo Grillo

Experiments studying phonon mediated drag in the double layer two dimensional electron gas system are reported. Detailed measurements of the dependence of drag on temperature, layer spacing, density ratio, and matched density are discussed.…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 H. Noh , S. Zelakiewicz , T. J. Gramila , L. N. Pfeiffer , K. W. West

Recently, nuclear vibrational contribution signatures in 2D electronic spectroscopy have attracted considerable interest, in particular as regards interpretation of the oscillatory transients observed in light-harvesting complexes. These…

Chemical Physics · Physics 2015-06-04 Yuta Fujihashi , Graham R. Fleming , Akihito Ishizaki