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The controlled functionalization of graphene is critical for tuning and enhancing its properties, thereby expanding its potential applications. Covalent functionalization offers a deeper tuning of the geometric and electronic structure of…

Materials Science · Physics 2025-05-07 Ylea Vlamidis , Carmela Marinelli , Aldo Moscardini , Paolo Faraci , Stefan Heun , Stefano Veronesi

Synthesis of graphene with reduced use of chemical reagents is essential for manufacturing scale-up and to control its structure and properties. In this paper, we report on a novel chemical-free mechanism of graphene exfoliation from…

Owing to wide variety of applications of graphene, high-quality and economical way of synthesizing graphene is highly desirable. In this study, we report a cost effective and simple approach to production of high-quality graphene. Here the…

Materials Science · Physics 2013-10-29 Prashant Tripathi , Ch. Ravi Prakash Patel , M. A. Shaz , O. N. Srivastava

Electronic properties of surface areas decoupled from graphite are studied using scanning tunnelling microscopy and spectroscopy. We show that it is possible to identify decoupled graphene monolayer, Bernal bilayer, and Bernal trilayer on…

Mesoscale and Nanoscale Physics · Physics 2015-03-06 Long-Jing Yin , Si-Yu Li , Jia-Bin Qiao , Jia-Cai Nie , Lin He

We show that strong coupling between graphene and the substrate is mitigated when 0.8 monolayer of Na is adsorbed and consolidated on top graphene-on-Ni(111). Specifically, the {\pi} state is partially restored near the K-point and the…

Single-layer graphene exhibits exceptional mechanical properties attractive for optomechanics: it combines low mass density, large tensile modulus, and low bending stiffness. However, at visible wavelengths, graphene absorbs weakly and…

Optics · Physics 2014-06-10 S. Hossein Mousavi , Peter T. Rakich , Zheng Wang

Using in situ low-energy electron microscopy and density functional theory, we studied the growth structure and work function of bilayer graphene on Pd(111). Low-energy electron diffraction analysis established that the two graphene layers…

Materials Science · Physics 2013-03-29 Y. Murata , S. Nie , A. Ebnonnasir , E. Starodub , B. B. Kappes , K. F. McCarty , C. V. Ciobanu , S. Kodambaka

We report experimentally and theoretically the behavior of freestanding graphene subject to bombardment of energetic ions, investigating the ability of large-scale patterning of freestanding graphene with nanometer sized features by focused…

Mesoscale and Nanoscale Physics · Physics 2016-05-04 Jakob Buchheim , Roman M. Wyss , Ivan Shorubalko , Hyung Gyu Park

Using the first principles calculations, we show that mechanically tunable electronic energy gap is realizable in bilayer graphene if different homogeneous strains are applied to the two layers. It is shown that the size of energy gap can…

Mesoscale and Nanoscale Physics · Physics 2010-09-13 Seon-Myeong Choi , Seung-Hoon Jhi , Young-Woo Son

We present a comparative study of high carrier density transport in mono-, bi-, and trilayer graphene using electric-double-layer transistors to continuously tune the carrier density up to values exceeding 10^{14} cm^{-2}. Whereas in…

Mesoscale and Nanoscale Physics · Physics 2016-07-13 J. T. Ye , M. F. Craciun , M. Koshino , S. Russo , S. Inoue , H. T. Yuan , H. Shimotani , A. F. Morpurgo , Y. Iwasa

Understanding the coupling of graphene with its local environment is critical to be able to integrate it in tomorrow's electronic devices. Here we show how the presence of a metallic substrate affects the properties of an atomically…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 M. M. Ugeda , D. Fernández-Torre , I. Brihuega , P. Pou , A. J. Martínez-Galera , R. Pérez , J. M. Gómez-Rodríguez

We consider the low energy effective field model of graphene monolayer. Coulomb interactions are taken into account. The model is simulated numerically using the lattice discretization with staggered fermions. The two point fermionic Green…

High Energy Physics - Lattice · Physics 2013-03-04 M. V. Ulybyshev , M. A. Zubkov

We report on the synthesis and characterization of the epoxy-based composites with the few-layer graphene fillers, which are capable of the duel functional applications. It was found that composites with the certain types of few-layer…

In this article, based on first-principles calculations, we systematically study functionalization induced diamonization of graphene bilayer and graphene-BN hybrid bilayer. With single-side functionalization, the diamondized structures are…

Materials Science · Physics 2011-12-22 Long Yuan , Zhenyu Li , Jinlong Yang , Jian Guo Hou

Organic functionalization of graphene is successfully performed via 1,3-dipolar cycloaddition of azomethine ylide in the liquid phase. The comparison between 1-methyl-2-pyrrolidinone and N,N-dimethylformamide as dispersant solvents, and…

We calculate the energy bands for graphene monolayers when electrons move through a periodic electrostatic potential in the presence of a uniform perpendicular magnetic field. We clearly demonstrate the quantum fractal nature of the energy…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 Godfrey Gumbs , Andrii Iurov , Danhong Huang , Liubov Zhemchuzhna

Self-heating is a severe problem for high-power microelectronic devices. Graphene and few-layer graphene have attracted tremendous attention for heat removal thanks to their extraordinarily high in-plane thermal conductivity. However, this…

We show that by using an original method, bulk graphite can be bonded onto borosilicate glass or potentially any insulating substrate with ionic conductivity and then cleaved off to leave single or few layer graphene on the substrate,…

Materials Science · Physics 2009-04-06 Abhay Shukla , Rakesh Kumar , Javed Mazher , Adrian Balan

High mobility single and few-layer graphene sheets are in many ways attractive as nanoelectronic circuit hosts but lack energy gaps, which are essential to the operation of field-effect transistors. One of the methods used to create gaps in…

Mesoscale and Nanoscale Physics · Physics 2018-12-26 Hakseong Kim , Nicolas Leconte , Bheema L. Chittari , Kenji Watanabe , Takashi Taniguchi , Allan H. MacDonald , Jeil Jung , Suyong Jung

We investigated theoretically the effect of covalent edge functionalization, with organic functional groups, on the electronic properties of graphene nanostructures and nano-junctions. Our analysis shows that functionalization can be…

Materials Science · Physics 2012-03-30 Caterina Cocchi , Alice Ruini , Deborah Prezzi , Marilia J. Caldas , Elisa Molinari