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Nonadiabatic dynamical processes are one of the most important quantum mechanical phenomena in chemical, materials, biological, and environmental molecular systems, where the coupling between different electronic states is either inherent…

Chemical Physics · Physics 2022-05-24 Jian Liu , Xin He , Baihua Wu

We study quantum dynamics of Grover's adiabatic search algorithm with the equivalent two-level system. Its adiabatic and non-adiabatic evolutions are visualized as trajectories of Bloch vectors on a Bloch sphere. We find the change in the…

Quantum Physics · Physics 2020-05-28 Sangchul Oh , Sabre Kais

Theoretical approaches to nonequilibrium many-body dynamics generally rest upon an adiabatic assumption, whereby the true dynamics is represented as a sequence of equilibrium states. Going beyond this simple approximation is a notoriously…

Soft Condensed Matter · Physics 2014-10-15 Andrea Fortini , Daniel de las Heras , Joseph M. Brader , Matthias Schmidt

We investigate a stochastic approach to non-equilibrium quantum spin systems based on recent insights linking quantum and classical dynamics. Exploiting a sequence of exact transformations, quantum expectation values can be recast as…

Statistical Mechanics · Physics 2019-01-31 S. De Nicola , B. Doyon , M. J. Bhaseen

We describe a numerical method which allows us to go beyond the classical approximation for the real-time dynamics of many-body systems by approximating the many-body Wigner function by the most general Gaussian function with time-dependent…

High Energy Physics - Theory · Physics 2018-03-29 Pavel Buividovich , Masanori Hanada , Andreas Schäfer

In a time-orbiting-potential magnetic trap the neutral atoms are confined by means of an inhomogeneous magnetic field superimposed to an uniform rotating one. We perform an analytic study of the atomic motion by taking into account the…

Soft Condensed Matter · Physics 2009-11-10 Roberto Franzosi , Andrea Spinelli , Bruno Zambon , Ennio Arimondo

The crossover from nonadiabatic to adiabatic electron transfer has been theoretically studied under a spin-boson model (dissipative two-state system) description. We present numerically exact data for the thermal transfer rate and the…

Condensed Matter · Physics 2009-11-07 L. Muehlbacher , R. Egger

The spin-boson model is a simplified Hamiltonian often used to study non-adiabatic dynamics in large condensed phase systems, even though it has not been solved in a fully analytic fashion. Herein, we present an exact analytic expression…

Chemical Physics · Physics 2017-07-10 Diptarka Hait , Michael G. Mavros , Troy Van Voorhis

With extensive variational simulations, dissipative quantum phase transitions in the sub-Ohmic spin-boson model are numerically studied in a dense limit of environmental modes. By employing a generalized trial wave function composed of…

Statistical Mechanics · Physics 2023-09-06 Yulong Shen , Nengji Zhou

An approach to non-adiabatic dynamics of atoms in molecular and condensed matter systems under general non-equilibrium conditions is proposed. In this method interaction between nuclei and electrons is considered explicitly up to the second…

Materials Science · Physics 2018-08-01 L. Kantorovich

Based on recently derived exact stochastic Liouville-von Neumann equations, several strategies for the efficient simulation of open quantum systems are developed and tested on the spin-boson model. The accuracy and efficiency of these…

Condensed Matter · Physics 2007-05-23 J. T. Stockburger

We present an approximate semiclassical (SC) framework for mixed quantized dynamics in Wigner phase space in a two-part series. In the first article, we introduced the Adiabatic Hybrid Wigner Dynamics (AHWD) method that allows for a few…

Chemical Physics · Physics 2024-09-06 Shreyas Malpathak , Nandini Ananth

We investigate non-equilibrium quantum spin systems via an exact mapping to stochastic differential equations. This description is invariant under a shift in the mean of the Gaussian noise. We show that one can extend the simulation time…

Strongly Correlated Electrons · Physics 2021-12-28 S. E. Begg , A. G. Green , M. J. Bhaseen

We consider the nonadiabatic energy fluctuations of a many-body system in a time-dependent harmonic trap. In the presence of scale-invariance, the dynamics becomes self-similar and the nondiabatic energy fluctuations can be found in terms…

Quantum Physics · Physics 2020-05-05 Mathieu Beau , Adolfo del Campo

We propose a novel method to describe realistically ionization processes with absorbing boundary conditions in basis expansion within the formalism of the so-called Non-Adiabatic Quantum Molecular Dynamics. This theory couples…

Quantum Physics · Physics 2015-06-26 Mathias Uhlmann , Thomas Kunert , Ruediger Schmidt

The study of many-body quantum dynamics in strongly-correlated systems is extremely challenging. To date few numerical methods exist which are capable of simulating the non-equilibrium dynamics of two-dimensional quantum systems, in part…

Quantum Physics · Physics 2024-09-17 S. J. Thomson , J. Eisert

Non-adiabatic transitions are studied in a spin-boson model with multiple scattering points. In order to generalize the Landau-Zener formula, which describes the case of a single scattering point, we define an ``effective gap'' for a set of…

Statistical Mechanics · Physics 2015-06-25 Hiroto Kobayashi , Naomichi Hatano , Seiji Miyashita

We present a method to simulate the dynamics of large driven-dissipative many-body open quantum systems using a variational encoding of the Wigner or Husimi-Q quasi-probability distributions. The method relies on Monte-Carlo sampling to…

Quantum Physics · Physics 2023-07-17 Debbie Eeltink , Filippo Vicentini , Vincenzo Savona

There are a number of tasks in quantum information science that exploit non-transitional adiabatic dynamics. Such a dynamics is bounded by the adiabatic theorem, which naturally imposes a speed limit in the evolution of quantum systems.…

Quantum Physics · Physics 2014-03-04 Marcela Herrera , Marcelo S. Sarandy , Eduardo I. Duzzioni , Roberto M. Serra

Every physical regime is some sort of approximation of reality. One lesser-known realm that is the semiquantal regime, which may be used to describe systems with both classical and quantum subcomponents. In the present review, we discuss…

Chaotic Dynamics · Physics 2009-11-07 Mason A. Porter