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We consider two ultracold particles confined in spherically symmetric harmonic trap and interacting via isotropic potential with absorbing boundary conditions at short range that models reactive scattering. First, we apply the contact…

Quantum Physics · Physics 2016-06-01 Joanna Jankowska , Zbigniew Idziaszek

We present a unified formalism for describing chemical reaction rates of trapped, ultracold molecules. This formalism reduces the scattering to its essential features, namely, a propagation of the reactant molecules through a gauntlet of…

Quantum Physics · Physics 2015-05-19 Zbigniew Idziaszek , Goulven Quéméner , John L. Bohn , Paul S. Julienne

Magnetically tunable scattering resonances have been used with great success for precise control of s-wave scattering lengths in ultracold atomic collisions. We describe relatively simple yet quite powerful analytic treatments of such…

Atomic Physics · Physics 2009-11-13 Paul S. Julienne , Bo Gao

Ultracold collisions of cold atoms or molecules make the bound states of the collision complex formed from the two colliding species accessible for control and manipulation of the cold species or the complex. Such resonances are best…

Atomic Physics · Physics 2015-05-13 Paul S. Julienne

We investigate collisions of polar molecules in quasi-2D traps in the presence of an external electric field perpendicular to the collision plane. We use the quantum-defect model characterized by two dimensionless parameters: $y$ and $s$.…

Quantum Physics · Physics 2015-08-17 M. Krych , Z. Idziaszek

How does a chemical reaction proceed at ultralow temperatures? Can simple quantum mechanical rules such as quantum statistics, single scattering partial waves, and quantum threshold laws provide a clear understanding for the molecular…

Ultracold polar molecules offer the possibility of exploring quantum gases with interparticle interactions that are strong, long-range, and spatially anisotropic. This is in stark contrast to the dilute gases of ultracold atoms, which have…

Atomic Physics · Physics 2015-05-18 K. -K. Ni , S. Ospelkaus , D. Wang , G. Quemener , B. Neyenhuis , M. H. G. de Miranda , J. L. Bohn , J. Ye , D. S. Jin

Analytic expressions describe universal elastic and reactive rates of quasi-two-dimensional and quasi-one-dimensional collisions of highly reactive ultracold molecules interacting by a van der Waals potential. Exact and approximate…

This paper deals with the theory of collisions between two ultracold particles with a special focus on molecules. It describes the general features of the scattering theory of two particles with internal structure, using a time-independent…

Atomic Physics · Physics 2017-03-28 Goulven Quéméner

We discuss laser dressed dipolar and Van der Waals interactions between atoms and polar molecules, so that a cold atomic gas with laser admixed Rydberg levels acts as a designed reservoir for both elastic and inelastic collisional…

Atomic Physics · Physics 2012-05-15 Bo Zhao , Alexander Glätzle , Guido Pupillo , Peter Zoller

We computed the long-range interactions between two identical polar bialkali molecules in their rovibronic ground level, for all ten species involving Li, Na, K, Rb and Cs, using accurate quantum chemistry results combined with available…

Atomic Physics · Physics 2017-04-11 Maxence Lepers , Romain Vexiau , Mireille Aymar , Nadia Bouloufa-Maafa , Olivier Dulieu

Scattering resonances due to the dipole-dipole interaction between ultracold molecules, induced by static or microwave fields, are studied theoretically. We develop a method for coupled-channel calculations that can efficiently impose many…

Quantum Gases · Physics 2023-07-11 Tijs Karman

We show that ultracold chemical reactions can be manipulated and controlled by using Rydberg-dressed interactions. Scattering in the ultracold regime is sensitive to long-range interactions, especially when weakly bound (or quasi-bound)…

Atomic Physics · Physics 2015-06-19 Jia Wang , Jason N. Byrd , Ion Simbotin , R. Côté

Compared to purely atomic collisions, ultracold molecular collisions potentially support a much larger number of Fano-Feshbach resonances due to the enormous number of ro-vibrational states available. In fact, for alkali-metal dimers we…

Atomic Physics · Physics 2012-10-19 Michael Mayle , Goulven Quéméner , Brandon P. Ruzic , John L. Bohn

We show that reactive molecules with a unit probability of reaction naturally provide a simulator of some intriguing black hole physics. The unit reaction at the short distance acts as an event horizon and delivers a one-way traffic for…

Quantum Gases · Physics 2023-05-24 Ren Zhang , Chenwei Lv , Qi Zhou

We investigate the properties of two interacting ultracold polar molecules described as distinguishable quantum rigid rotors, trapped in a one-dimensional harmonic potential. The molecules interact via a multichannel two-body contact…

Atomic Physics · Physics 2018-07-03 Anna Dawid , Maciej Lewenstein , Michał Tomza

Ultracold collisions of polar OH molecules are considered in the presence of an electrostatic field. The field exerts a strong influence on both elastic and state-changing inelastic collision rate constants, leading to clear experimental…

Atomic Physics · Physics 2009-11-07 Alexandr V. Avdeenkov , John L. Bohn

Quantum scattering calculations are reported for the H+HCl(v,j=0) and H+DCl(v,j=0) collisions for vibrational levels v=0-2 of the diatoms. Calculations were performed for incident kinetic energies in the range 10-7 to 10-1 eV, for total…

Chemical Physics · Physics 2009-11-10 P. F. Weck , N. Balakrishnan

Using the multipolar expansion of electrostatic and magnetostatic potential energies, we characterize the long-range interactions between two weakly-bound diatomic molecules, taking as an example the paramagnetic Er$_2$ Feshbach molecules…

Atomic Physics · Physics 2017-04-11 Maxence Lepers , Goulven Quéméner , Eliane Luc-Koenig , Olivier Dulieu

An ion and a polar molecule interact by an anisotropic ion-dipole potential scaling as $- \alpha \cos (\theta)/r^2$ at large distances. Due to its long-range character, it modifies the properties of angular wave functions, which are no…

Atomic Physics · Physics 2021-03-03 Tomasz Wasak , Zbigniew Idziaszek
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