Related papers: Reactions of ultracold alkali metal dimers
A universal dimer is subject to secondary collisions with atoms when formed in a cloud of ultracold atoms via three-body recombination. We show that in a collisionally opaque medium, the value of the scattering length that results in the…
We discuss the collisional formation of Efimov trimers via ultracold four-body recombination. In particular, we consider the reaction A+A+A+B->A3+B with A and B ultracold atoms. We obtain expressions for the four-body recombination rate and…
We calculate the universal spectrum of trimer and tetramer states in heteronuclear mixtures of ultracold atoms with different masses in the vicinity of the heavy-light dimer threshold. To extract the energies, we solve the three- and…
We investigate the hyperfine energy levels and Zeeman splittings for homonuclear alkali-metal dimers in low-lying rotational and vibrational states, which are important for experiments designed to produce quantum gases of deeply bound…
The formation and interaction of ultracold polar molecules is a topic of active research. Understanding possible reaction paths and molecular combinations requires accurate studies of the fragment and product energetics. We have calculated…
We study cold heteronuclear atom ion collisions by immersing a trapped single ion into an ultracold atomic cloud. Using ultracold atoms as reaction targets, our measurement is sensitive to elastic collisions with extremely small energy…
We predict that pairs of polar molecules can be weakly bound together in an ultracold environment, provided that a dc electric field is present. The field that links the molecules together also strongly influences the basic properties of…
We demonstrate that it is possible to efficiently control ultracold chemical reactions of alkali-metal atoms colliding with open-shell alkali-metal dimers in their metastable triplet states by choosing the internal hyperfine and…
We report the observation of coherent oscillations in conversion efficiency of weakly-bound dimers formed from a thermal gas of ultracold atoms. Finite thermal energy of the gas causes loss of coherence when a broad continuum is resonantly…
We investigate the potential energy surfaces and activation energies for reactions between methyl halide molecules CH$_{3}X$ ($X$ = F, Cl, Br, I) and alkali-metal atoms $A$ ($A$ = Li, Na, K, Rb) using high-level {\it ab initio}…
We discuss consequences of Fermi exchange symmetry on collisions of polar molecules at low temperatures (below 1 K), considering the OD radical as a prototype. At low fields and low temperatures, Fermi statistics can stabilize a gas of OD…
Homonuclear spin-polarized alkali-metal trimers in their lowest-lying electronic state are investigated theoretically. Their equilibrium geometries and binding energies are determined with the state-of-the-art quantum chemical methods at…
We consider a heteronuclear fermionic mixture on the molecular side of an interspecies Feshbach resonance and discuss atom-dimer scattering properties in uniform space and in the presence of an external confining potential, restricting the…
The Efimov effect, with its ladder of weakly bound three-atomic molecules, poses intriguing questions in the theoretically controversial and experimentally demanding regime of merging of the first excited Efimov energy level with the…
We find that energy surfaces of more than two atoms or molecules interacting via dipole-dipole po- tentials generically possess conical intersections (CIs). Typically only few atoms participate strongly in such an intersection. For the…
The general formalism of the multipolar expansion of electrostatic interactions is applied to the calculation the potential energy between an excited atom (without fine structure) and a ground state diatomic molecule at large separations.…
We investigate the energetics of the atom exchange reaction in the SrF+alkali-metal atom and CaF+alkali-metal atom systems. Such reactions are possible only for collisions of SrF and CaF with the lithium atoms, while they are energetically…
This paper reports results from an experimental investigation of the dissociative recombination (DR) of the helium dimer ions at the heavy-ion Test Storage Ring (TSR) in Heidelberg, observing neutral products from electron-ion collisions in…
Ultrafast laser excitation can induce fast increases of the electronic subsystem temperature. The subsequent electronic evolutions in terms of band structure and energy distribution can determine the change of several thermodynamic…
The behaviour of a di-nuclear system in the regime of strong pairing correlations is studied with the methods of statistical mechanics. It is shown that the thermal averaging is strong enough to assure the application of thermodynamical…