Related papers: Deuterium Fractionation as an Evolutionary Probe i…
Although ammonia is an abundant molecule commonly observed towards the dense interstellar medium, it has not yet been established whether its main formation route is from gas-phase ion-molecule reactions or grain-surface hydrogen additions…
Aims: We aim to investigate the abundances of light deuterium-bearing species such as HD, H2D+ and D2H+ in a gas-grain chemical model including an extensive description of deuterium and spin state chemistry, in physical conditions…
We present the modeling results of deuterium fractionation of water ice, H2, and the primary deuterium isotopologues of H3+ adopting physical conditions associated with the star and planet formation process. We calculated the deuterium…
[abridged] The enhanced degrees of deuterium fractionation observed in envelopes around protostars demonstrate the importance of chemistry at low temperatures, relevant in pre- and protostellar cores. formaldehyde is an important species in…
The initial stage of star formation is a complex area study because of its high density and low temperature. Under such conditions, many molecules become depleted from the gas phase by freezing out onto dust grains. However, the deuterated…
Infrared-dark high-mass clumps are among the most promising objects to study the initial conditions of the formation process of high-mass stars and rich stellar clusters. In this work, we have observed the (3-2) rotational transition of…
We observed the pre-stellar core L1521F in dust emission at 1.2mm and in two transitions each of N2H+, N2D+, C18O, and C17O in order to increase the sample of well studied centrally concentrated and chemically evolved starless cores, likely…
We examine the physical properties and evolutionary stages of a sample of 17 clumps within 8 Infrared Dark Clouds (IRDCs) by combining existing infrared, millimeter, and radio data with new Bolocam Galactic Plane Survey (BGPS) 1.1 mm data,…
The physical and chemical properties of cold and dense molecular clouds are key to understanding how stars form. Using the IRAM 30 m and NRO 45 m telescopes, we carried out a Multiwavelength line-Imaging survey of the 70 $\mu$m dark and…
Deuterium fractionation is dependent on various physical and chemical parameters. Thus, the formation location and thermal history of material in the solar system is often studied by measuring its D/H ratio. This requires knowledge about…
From mapping observations of H2CO, HDCO, and D2CO, we have determined how the degree of deuterium fractionation changes over the central 3'x3' region of rho Oph A. The multi-transition data of the various H2CO isotopologues, as well as from…
The presence of H2D+ in dense cloud cores underlies ion-molecule reactions that strongly enhance the deuterium fractionation of many molecular species. We determine the H2D+ abundance in one starless core, Barnard 68, that has a…
High degrees of deuterium fractionation are commonly found in cold prestellar cores and in the envelopes around young protostars. As it brings strong constraints to chemical models, deuterium chemistry is often used to infer core history or…
We present a survey of the ortho-H2D+(1_{1,0}-1_{1,1}) line toward a sample of 10 starless cores and 6 protostellar cores, carried out at the Caltech Submillimeter Observatory. The high diagnostic power of this line is revealed for the…
Context : Dynamical studies of prestellar cores search for small velocity differences between different tracers. The highest radiation frequency precision is therefore required for each of these species. Aims : We want to adjust the…
Recent advances in identifying giant molecular filaments in galactic surveys allow us to study the interstellar material and its dense, potentially star forming phase on scales comparable to resolved extragalactic clouds. Two large…
We report new calculations of interstellar 15N fractionation. Previously, we have shown that large enhancements of 15N/14N can occur in cold, dense gas where CO is frozen out, but that the existence of an NH + N channel in the dissociative…
The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is…
We aim at investigating with high angular resolution the NH3/N2H+ ratio toward the high-mass star-forming region AFGL 5142 in order to study whether this ratio behaves similarly to the low-mass case, for which the ratio decreases from…
The formation of singly and doubly deuterated isotopomers of formaldehyde and of singly, doubly, and multiply deuterated isotopomers of methanol on interstellar grain surfaces has been studied with a semi-empirical modified rate approach…