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We report on the first experimental results for microwave spectroscopy of the hyperfine structure of antiprotonic He-3. Due to the helium nuclear spin, antiprotonic He-3 has a more complex hyperfine structure than antiprotonic He-4 which…

Evolutionary algorithms for molecular design require computationally efficient yet accurate fitness functions. We systematically benchmark Hartree-Fock and density functional theory for predicting molecular first hyperpolarizability…

Chemical Physics · Physics 2026-04-24 Dominic Mashak , S. A. Alexander

We experimentally study the breakdown of hyperfine coupling for an atom in a deep optical-dipole trap. One-color laser spectroscopy is performed at the resonance lines of a single $^{87}$Rb atom for a trap wavelength of 1064 nm. Evidence of…

Atomic Physics · Physics 2015-11-20 Andreas Neuzner , Matthias Körber , Stephan Dürr , Gerhard Rempe , Stephan Ritter

We present a first-principles study of the structural, electronic, and optical properties of hydrogenated amorphous silicon (a-Si:H). To this end, atomic configurations of a-Si:H with 72 and 576 atoms respectively are generated using…

Materials Science · Physics 2017-03-31 Philippe Czaja , Urs Aeberhard , Massimo Celino , Simone Giusepponi , Michele Gusso

We report on the improved measurement of the hyperfine structure of $4f^{12}(^3 H_6)5d_{5/2}6s^2$ $(J=9/2)$ excited state in Tm-169 which is involved in the second-stage laser cooling of Tm. To measure the absolute value of the hyperfine…

Nuclear structure of 7Be, 8B and 7,8Li is studied within the ab initio no-core shell model (NCSM). Starting from the high-precision CD-Bonn 2000 nucleon-nucleon (NN) interaction, wave functions of 7Be and 8B bound states are obtained in…

Nuclear Theory · Physics 2009-11-11 P. Navratil , C. A. Bertulani , E. Caurier

The ab initio linear muffin-tin-orbital (LMTO) formalism and the semi-empirical method of the Intermediate Neglect of the Differential Overlap (INDO) based on the Hartree-Fock formalism are combined for the study of the hole polarons (a…

Materials Science · Physics 2009-10-31 E. A. Kotomin , R. I. Eglitis , A. V. Postnikov , G. Borstel , N. E. Christensen

We derive expressions for cluster overlap integrals or channel cluster form factors for ab initio no-core shell model (NCSM) wave functions. These are used to obtain the spectroscopic factors and can serve as a starting point for the…

Nuclear Theory · Physics 2009-11-10 Petr Navratil

The Z-vector method in the relativistic coupled-cluster framework is used to calculate magnetic hyperfine structure constant ($A_J$) of alkali metals and singly charged alkaline earth metals in their ground state electronic configuration.…

Atomic Physics · Physics 2017-07-18 Sudip Sasmal

The usefulness of study of hyperfine splitting in the hydrogen atom is limited on a level of 10 ppm by our knowledge of the proton structure. One way to go beyond 10 ppm is to study a specific difference of the hyperfine structure intervals…

Atomic Physics · Physics 2007-05-23 Savely G. Karshenboim

We study (inverse) photoemission from systems with strong coupling of doped carriers to phonons. Using an adiabatic approximation, we develop a method for calculating spectra. This method is particularly simple for systems where the…

Strongly Correlated Electrons · Physics 2007-05-23 O. Rösch , O. Gunnarsson

A comprehensive angle resolved photoemission spectroscopy study of the band structure in single layer cuprates is presented with the aim of uncovering universal trends across different materials. Five different hole- and electron-doped…

A new ATSP2K module is presented for evaluating the electron density function of any multiconfiguration Hartree-Fock or configuration interaction wave function in the non relativistic or relativistic Breit-Pauli approximation. It is first…

Atomic Physics · Physics 2015-05-13 A. Borgoo , O. Scharf , G. Gaigalas , M. Godefroid

We formulate an ab initio downfolding scheme for electron-phonon coupled systems. In this scheme, we calculate partially renormalized phonon frequencies and electron-phonon coupling, which include the screening effects of high-energy…

Strongly Correlated Electrons · Physics 2015-12-10 Yusuke Nomura , Ryotaro Arita

We measure the hyperfine structure of the $5p^65d$ ${}^2D_{3/2}$, $5p^65d$ ${}^2D_{5/2}$, $5p^64f$ ${}^2F^o_{5/2}$, and $5p^64f$ ${}^2F^o_{7/2}$ levels in doubly-ionized lanthanum (La III; La$^{2+}$) in a hollow cathode lamp using…

Atomic Physics · Physics 2018-04-13 S. Olmschenk , P. R. Banner , J. Hankes , A. M. Nelson

Using the Gaussian-03 for ab initio calculations, interactions of various acid molecules with a single water molecule were studied. The molecular and supermolecular optimized structures were found with the Becke-3-Lee-Yang-Parr…

Chemical Physics · Physics 2018-04-17 Aleksey Anatolievich Zakharenko

Relativistic corrections to the hyperfine splitting are calculated for the triplet $2^3S_1$ state of the helium isotope He$^3$. High precision variational wave functions are employed, where the electron-electron correlations are well…

Atomic Physics · Physics 2009-11-07 Krzysztof Pachucki

A simple approximation within the framework of the hybrid methods for the calculation of the electronic structure of solids is presented. By considering only the diagonal elements of the perturbation operator (Hartree-Fock exchange minus…

Materials Science · Physics 2012-01-31 Fabien Tran

The hyperfine structure splittings are determined for the lowest bound state in the positron-helium ion $e^{+}[^3$He$(2^3S)]$ and $e^{+}[^4$He$(2^3S)]$. In particular, we have fond that for the $e^{+}[{}^3$He$(2^3S)]$ ion one can observe…

Atomic Physics · Physics 2012-12-21 Alexei M. Frolov
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