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We show that combining vibrational spectroscopy with signal processing can result in a scheme for ultrasensitive detection of molecules. We consider the vibrational spectrum as a signal on the energy axis and apply a matched filter on that…

Computational Physics · Physics 2018-12-10 Tay Yong Boon , Ian Tay Rongde , Loy Liang Yi , Aw Ke Fun , Ong Zhi Li , Sergei Manzhos

Multi-molecular excited states accompanied by an intra- and inter-molecular geometric relaxation are commonly encountered in optical and electrooptical studies and applications of organic semiconductors as, for example excimers or charge…

Materials Science · Physics 2022-11-14 Sebastian Hammer , Theresa Linderl , Kristofer Tvingstedt , Wolfgang Brütting , Jens Pflaum

Two recent experimental (Li, J.~\emphj{et al}, \emph{Proc.\ Natl.\ Acad.\ Sci.\ U.~S.~A.} {\bf 2014}, 111, 1282-1287) and theoretical studies (B\^aldea, I, \emph{Phys.\ Chem.\ Chem.\ Phys.}\ {\bf 2014}, 16, 25942-25949) have addressed the…

Chemical Physics · Physics 2015-09-21 Ioan Baldea

The quantum entanglement phenomenon was demonstrated to operate on a bipartite entangled system composed of two single layers of graphene embedded in an electrolytic medium (which did not permit the transport of electrons) and subjected to…

General Physics · Physics 2024-10-17 David A. Miranda , Edgar F. Pinzón , Paulo R. Bueno

Photoemission and tunneling spectroscopies measure the energies at which single electrons can be added to or removed from an electronic system. Features observed in such spectra have revealed electrons coupling to vibrational modes of ions…

Strongly Correlated Electrons · Physics 2017-05-09 Joonho Jang , Benjamin Hunt , Loren N. Pfeiffer , Kenneth W. West , Raymond C. Ashoori

Vibronic effects in resonant electron transport through single-molecule junctions are analyzed. The study is based on generic models for molecular junctions, which include electronic states on the molecular bridge that are vibrationally…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 R. Härtle , M. Thoss

We study the electronic properties of an array of small metallic grains connected by tunnel junctions. Such an array serves as a model for a granular metal. Previous theoretical studies of junction arrays were based on models of quantum…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 I. S. Beloborodov , K. B. Efetov , Alexander Altland , F. W. J. Hekking

We analyze various limits of vibrationally coupled resonant electron transport in single-molecule junctions. Based on a master equation approach, we discuss analytic and numerical results for junctions under a high bias voltage or weak…

Mesoscale and Nanoscale Physics · Physics 2015-03-18 R. Härtle , M. Thoss

Electronic conduction through single molecules is affected by the molecular electronic structure as well as by other information that is extremely difficult to assess, such as bonding geometry and chemical environment. The lack of an…

Mesoscale and Nanoscale Physics · Physics 2009-05-21 Daniel R. Ward , Naomi J. Halas , Jacob W. Ciszek , James M. Tour , Yanpeng Wu , Peter Nordlander , Douglas Natelson

We discuss the luminescence spectra of coupled light-matter systems realized with semiconductor heterostructures in microcavities in the presence of a continuous, incoherent pumping, when the matter field is Fermionic. The linear…

Mesoscale and Nanoscale Physics · Physics 2009-07-09 Elena del Valle , Fabrice P. Laussy , Carlos Tejedor

The advent of single molecule optics has had a profound impact in fields ranging from biophysics to material science, photophysics, and quantum optics. However, all existing room-temperature single molecule methods have been based on…

Mesoscale and Nanoscale Physics · Physics 2010-07-22 Michele Celebrano , Philipp Kukura , Alois Renn , Vahid Sandoghdar

Weak measurement is a new technique which allows one to describe the evolution of postselected quantum systems. It appears to be useful for resolving a variety of thorny quantum paradoxes, particularly when used to study properties of pairs…

Quantum Physics · Physics 2009-11-10 K. J. Resch , A. M. Steinberg

Tip-enhanced photoluminescence (TEPL) measurements are performed with sub-nanometer spatial resolution on individual molecules decoupled from a metallic substrate by a thin NaCl layer. TEPL spectra reveal progressive fluorescence quenching…

Mesoscale and Nanoscale Physics · Physics 2024-03-18 Katharina Kaiser , Michelangelo Romeo , Fabrice Scheurer , Guillaume Schull , Anna Rosławska

We study the quantum mechanical behavior of a macroscopic, three-body, superconducting circuit. Microwave spectroscopy on our system, a resonator coupling two large Josephson junctions, produced complex energy spectra well explained by…

Vibrationally inelastic electron transport through a flexible molecular junction is investigated. The study is based on a mechanistic model for a biphenyl molecule between two metal electrodes. Employing methods from electron-molecule…

Mesoscale and Nanoscale Physics · Physics 2023-07-26 Martin Cizek , Michael Thoss , Wolfgang Domcke

Modulated electroreflectance spectroscopy $\Delta R/R$ of semiconductor self-assembled quantum dots is investigated. The structure is modeled as dots with lens shape geometry and circular cross section. A microscopic description of the…

Materials Science · Physics 2016-08-16 A. H. Rodríguez , C. Trallero-Giner , Martín Muñoz , María C. Tamargo

Vibrational modes of molecules are fundamental properties determined by intramolecular bonding, atomic masses, and molecular geometry, and often serve as important channels for dissipation in nanoscale processes. Although single-molecule…

Mesoscale and Nanoscale Physics · Physics 2014-03-06 Y. Li , P. Doak , L. Kronik , J. B. Neaton , D. Natelson

Strong confinement of charges in few electron systems such as in atoms, molecules and quantum dots leads to a spectrum of discrete energy levels that are often shared by several degenerate quantum states. Since the electronic structure is…

Single-molecule electronics has been envisioned as the ultimate goal in the miniaturisation of electronic circuits. While the aim of incorporating single-molecule junctions into modern technology still proves elusive, recent developments in…

Mesoscale and Nanoscale Physics · Physics 2017-11-22 Jakub K. Sowa , Jan A. Mol , G. Andrew D. Briggs , Erik M. Gauger

Manifestations of quantum coherence in the electronic conductance through nearly closed quantum dots in the Coulomb blockade regime are addressed. We show that quantum coherent tunneling processes explain some puzzling statistical features…

Mesoscale and Nanoscale Physics · Physics 2015-05-26 L. E. F. Foa Torres , C. H. Lewenkopf , H. M. Pastawski
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