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We show that classical molecular density functional theory (MDFT), here in the homogeneous reference fluid approximation in which the functional is inferred from the properties of the bulk solvent, is a powerful new tool to study, at a…

The amplitude expansion for a magnetic phase-field-crystal (magnetic APFC) model enables a convenient coarse-grained description of crystalline structures under the influence of magnetic fields. Considering higher-order magnetic coupling…

Materials Science · Physics 2022-11-01 Rainer Backofen , Marco Salvalaglio , Axel Voigt

We investigate the possibility to control the symmetry of ordered states in phase-field crystal models by tuning nonlinear resonances. In two dimensions, we find that a state of square symmetry as well as coexistence between squares and…

Materials Science · Physics 2015-05-19 Kuo-An Wu , Mathis Plapp , Peter W Voorhees

Based on static and dynamical density functional theory, a phase-field-crystal model is derived which involves both the translational density and the orientational degree of ordering as well as a local director field. The model exhibits…

Soft Condensed Matter · Physics 2015-05-19 Hartmut Löwen

Density functional theory (DFT) became a universal approach to compute ground-state and excited configurations of many-electron systems held together by an external one-body potential in condensed-matter, atomic, and molecular physics. At…

Nuclear Theory · Physics 2011-09-30 J. Dobaczewski

The interfacial free energy between a crystal and a fluid, {\gamma} cf, is a highly relevant parameter in phenomena such as wetting or crystal nucleation and growth. Due to the difficulty of measuring {\gamma} cf experimentally, computer…

Statistical Mechanics · Physics 2015-06-23 J. R. Espinosa , C. Vega , E. Sanz

Quantum embedding methods have recently developed significantly to model large molecular structures. This work proposes a novel wave function theory in density functional theory (WTF-in-DFT) embedding scheme based on pair-coupled cluster…

Chemical Physics · Physics 2024-01-10 Rahul Chakraborty , Katharina Boguslawski , Paweł Tecmer

We present a mesoscale description of deformations and defects in thin, flexible sheets with crystalline order, tackling the interplay between in-plane elasticity, out-of-plane deformation, as well as dislocation nucleation and motion. Our…

Materials Science · Physics 2025-02-26 Lucas Benoit--Maréchal , Ingo Nitschke , Axel Voigt , Marco Salvalaglio

In this paper, we study the phase field models with fractional-order in time. The phase field models have been widely used to study coarsening dynamics of material systems with microstructures. It is known that phase field models are…

Numerical Analysis · Mathematics 2018-03-15 Lizhen Chen , Jia Zhao , Hong Wang

The phase diagram of numerous materials of technological importance features high-symmetry high-temperature phases that exhibit phonon instabilities. Leading examples include shape-memory alloys, as well as ferroelectric, refractory, and…

Materials Science · Physics 2017-02-06 Sara Kadkhodaei , Qi-Jun Hong , Axel van de Walle

We use an accurate implementation of density functional theory (DFT) to calculate the zero-temperature generalized phase diagram of the 4$d$ series of transition metals from Y to Pd as a function of pressure $P$ and atomic number $Z$. The…

Materials Science · Physics 2009-11-13 C. Cazorla , D. Alf`e , M. J. Gillan

We report a systematic and accurate approach for deriving the bulk free energy surface (FES), a function of temperature, polarization, and strain, from the first-principles density functional theory (DFT) of proper ferroelectrics. The core…

Materials Science · Physics 2026-02-10 Pinchen Xie , Yixiao Chen , Xinyu Xu , Zhi Yao , Weinan E , Roberto Car

Experiments of the recrystallization processes in two-dimensional complex plasmas are analyzed in order to rigorously test a recently developed scale-free phase transition theory. The "Fractal-Domain-Structure" (FDS) theory is based on the…

Soft Condensed Matter · Physics 2018-05-23 A. Böbel , C. A. Knapek , C. Räth

The dynamics of glass formation in monatomic and binary liquids are studied numerically using a microscopic field theory for the evolution of the time-averaged atomic number density. A stochastic framework combining phase field crystal free…

Materials Science · Physics 2015-05-27 Joel Berry , Martin Grant

Colloidal systems offer unique opportunities for the study of phase formation and structure since their characteristic length scales are accessible to visible light. As a model system the two dimensional assembly of colloidal magnetic and…

Soft Condensed Matter · Physics 2018-11-12 Hauke Carstensen , Vassilios Kapaklis , Max Wolff

We consider a realistic model, i.e., ultracold atoms in a driven optical lattice, to realize phase space crystals [Phys. Rev. Lett. 111, 205303 (2013)]. The corresponding lattice structure in phase space is more complex and contains rich…

Quantum Gases · Physics 2016-02-02 Lingzhen Guo , Michael Marthaler

A simplified density functional theory (DFT) method for charged adsorbates on an ultrathin, insulating film supported by a metal substrate is developed and presented. This new method is based on a previous DFT development that uses a…

Materials Science · Physics 2017-03-27 Ivan Scivetti , Mats Persson

By using modular functions on the upper complex half-plane, we study a class of strain energies for crystalline materials whose global invariance originates from the full symmetry group of the underlying lattice. This follows Ericksen's…

Materials Science · Physics 2022-11-29 Edoardo Arbib , Paolo Biscari , Clara Patriarca , Giovanni Zanzotto

Phase-field approaches to fracture based on energy minimization principles have been rapidly gaining popularity in recent years, and are particularly well-suited for simulating crack initiation and growth in complex fracture networks. In…

Materials Science · Physics 2018-03-14 Juan Michael Sargado , Eirik Keilegavlen , Inga Berre , Jan Martin Nordbotten

We describe a general method to model multicomponent ordered crystals using the phase-field crystal (PFC) formalism. As a test case, a generic B2 compound is investigated. We are able to produce a line of either first-order or second-order…

Materials Science · Physics 2017-02-15 Eli Alster , K. R. Elder , Jeffrey J. Hoyt , Peter W. Voorhees
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