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We present a theory for the ab-initio computation of NMR chemical shifts (sigma) in condensed matter systems, using periodic boundary conditions. Our approach can be applied to periodic systems such as crystals, surfaces, or polymers and,…

Materials Science · Physics 2009-10-28 Francesco Mauri , Bernd G. Pfrommer , Steven G. Louie

A junction between an n- and p-type semiconductor results in the creation of a depletion region whose properties are at the basis of nowadays electronics. If realized using topological insulators as constituent materials, p-n junctions are…

Mesoscale and Nanoscale Physics · Physics 2016-04-14 T. Bathon , S. Achilli , P. Sessi , V. A. Golyashov , K. A. Kokh , O. E. Tereshchenko , M. Bode

The microstructure of the Ti-Al binary system is an area of great interest as it affects material properties and plasticity. Phase transformations induce microstructural changes; therefore, accurately modeling the phase transformations of…

Materials Science · Physics 2024-11-13 Micah Nichols , Christopher D. Barrett , Doyl E. Dickel , Mashroor S. Nitol , Saryu J. Fensin

We describe and test an implicit solvent all-atom potential for simulations of protein folding and aggregation. The potential is developed through studies of structural and thermodynamic properties of 17 peptides with diverse secondary…

Biomolecules · Quantitative Biology 2009-04-09 Anders Irbäck , Simon Mitternacht , Sandipan Mohanty

We present a general method of constructing \textit{in-situ} pseodopotentials from first principles, all-electron, full-potential electronic structure calculations of a solid. The method is applied to bcc Na, at equilibrium volume. The…

Materials Science · Physics 2021-02-10 K. Björnson , J. M. Wills , M. Alouani , O. Grånäs , P. Thunström , Chin Shen Ong , O. Eriksson

The ground-state properties of spin polarized hydrogen H$\downarrow$ are obtained by means of diffusion Monte Carlo calculations. Using the most accurate to date ab initio H$\downarrow$-H$\downarrow$ interatomic potential we have studied…

Other Condensed Matter · Physics 2007-05-23 L. Vranjes Markic , J. Boronat , J. Casulleras

The phase diagram of water harbours many mysteries: some of the phase boundaries are fuzzy, and the set of known stable phases may not be complete. Starting from liquid water and a comprehensive set of 50 ice structures, we compute the…

Statistical Mechanics · Physics 2021-01-27 Aleks Reinhardt , Bingqing Cheng

Calculations of transition intensities for small molecules like H$_2$O, CO, CO$_2$ based on s high-quality potential energy surface (PES) and dipole moment surface (DMS) can nowadays reach sub-percent accuracy. An extension of this…

The energy landscape of helium-nitrogen mixtures is explored by ab initio evolutionary searches, which predicted several stable helium-nitrogen compounds in the pressure range from 25 to 100 GPa. In particular, the monoclinic structure of…

Understanding and prediction of the chemical reactions are fundamental demanding in the study of many complex chemical systems. Reactive molecular dynamics (MD) simulation has been widely used for this purpose as it can offer atomic details…

Chemical Physics · Physics 2020-11-12 Jinzhe Zeng , Liqun Cao , Mingyuan Xu , Tong Zhu , John ZH Zhang

We develop an electronic-temperature dependent interatomic potential $\Phi (T_\text{e})$ for unexcited and laser-excited silicon. The potential is designed to reproduce ab initio molecular dynamics simulations by requiring force- and energy…

Materials Science · Physics 2020-03-04 Bernd Bauerhenne , Vladimir P. Lipp , Tobias Zier , Eeuwe S. Zijlstra , Martin E. Garcia

Constructing accurate interatomic potential and overcoming the exponential growth of structural equilibration time are challenges to the atomistic investigations of the composition-dependent structure and dynamics during the vitrification…

Materials Science · Physics 2023-02-14 Rui Su , Jieyi Yu , Pengfei Guan , Weihua Wang

Knowledge of the behavior of hydrogen in metal hydrides is the key for understanding their electronic properties. So far, no experimental methods exist to access these properties beyond 100 GPa, where high-Tc superconductivity emerges.…

Based on an analysis of the short range chemical environment of each atom in a system, standard machine learning based approaches to the construction of interatomic potentials aim at determining directly the central quantity which is the…

Materials Science · Physics 2015-08-05 S. Alireza Ghasemi , Albert Hofstetter , Santanu Saha , Stefan Goedecker

Sintering of alumina nanoparticles is of interest both from the view of fundamental research as well as for industrial applications. Atomistic simulations are tailor-made for understanding and predicting the time- and temperature-dependent…

Materials Science · Physics 2022-08-31 Shyamal Roy , Arun Prakash , Stefan Sandfeld

We present the development and applications of a quadratic Spectral Neighbor Analysis Potential (q-SNAP) for ferromagnetic cobalt. Trained on Density Functional Theory calculations using the Perdew-Burke-Ernzerhof (DFT-PBE) functional, this…

Materials Science · Physics 2024-11-05 Marthe Bideault , Jérôme Creuze , Ryoji Asahi , Erich Wimmer

Equilibration dynamics of hot oxygen atoms following O2 dissociation on Pd(100) and Pd(111) surfaces are investigated by molecular dynamics simulations based on a scalable neural network potential enabling first-principles description of O2…

Materials Science · Physics 2023-04-24 Qidong Lin , Bin Jiang

Choice of appropriate force field is one of the main concerns of any atomistic simulation that needs to be seriously considered in order to yield reliable results. Since, investigations on mechanical behavior of materials at micro/nanoscale…

Computational Physics · Physics 2016-07-12 Seyed Moein Rassoulinejad-Mousavi , Yijin Mao , Yuwen Zhang

We present a multiscale simulation approach for hydroxide transport in aqueous solutions of potassium hydroxide, combining ab initio molecular dynamics (AIMD) simulations with force field ensemble averaging and lattice Monte Carlo…

Computational Physics · Physics 2025-04-09 Jonas Hänseroth , Daniel Sebastiani , Jakob Scholl , Karl Skadell , Christian Dreßler

Accurate prediction of thermodynamic properties requires an extremely accurate representation of the free energy surface. Requirements are twofold -- first, the inclusion of the relevant finite-temperature mechanisms, and second, a dense…

Materials Science · Physics 2023-01-11 Jong Hyun Jung , Prashanth Srinivasan , Axel Forslund , Blazej Grabowski
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