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We generalize the methods used in the theory of correlation dynamics and establish a set of equations of motion for many-body correlation green's functions in the non-relativistic case. These non-linear and coupled equations of motion…

Nuclear Theory · Physics 2015-06-26 Shun-Jin Wang , Wei Zuo , Wolfgang Cassing

Employing a local formula for the electron-electron interaction energy, we derive a self-consistent approximation for the total energy of a general $N$-electron system. Our scheme works as a local variant of the Thomas-Fermi approximation…

Chemical Physics · Physics 2013-10-31 E. Rasanen , A. Odriazola , I. Makkonen , A. Harju

In this work, we consider the particle-hole random phase approximation (phRPA), an approximation to the correlation energy in electronic structure, and show that the phRPA energy of the H2 molecule correctly dissociates. That is, as the…

Analysis of PDEs · Mathematics 2022-10-11 Mi-Song Dupuy , Kyle Thicke

Hedin's $GW$ approximation to the electronic self-energy has been impressively successful to calculate quasiparticle energies, such as ionization potentials, electron affinities, or electronic band structures. The success of this fairly…

Chemical Physics · Physics 2024-10-31 Arno Förster , Fabien Bruneval

Based on the Korringa-Kohn-Rostoker Green's function technique we present a computational scheme for calculating the electronic structure of layered systems with homogeneous spin-spiral magnetic state. From the self-consistent…

Materials Science · Physics 2019-10-30 Eszter Simon , Laszlo Szunyogh

The self-consistent theory of the correlation effects in Highly Correlated Systems(HCS) is presented. The novel Irreducible Green's Functions(IGF) method is discused in detail for the Hubbard model and random Hubbard model. The…

Strongly Correlated Electrons · Physics 2008-02-03 A. L. Kuzemsky

Including finite-temperature effects from the electronic degrees of freedom in electronic structure calculations of semiconductors and metals is desired; however, in practice it remains exceedingly difficult when using zero-temperature…

Chemical Physics · Physics 2016-11-24 Alicia Rae Welden , Alexander A. Rusakov , Dominika Zgid

We present a detailed account of the GW space-time method. The method increases the size of systems whose electronic structure can be studied with a computational implementation of Hedin's GW approximation. At the heart of the method is a…

Condensed Matter · Physics 2009-10-31 M. M. Rieger , L. Steinbeck , I. D. White , H. N. Rojas , R. W. Godby

We compute the energy functional of a three-level Lipkin model via a Legrendre transform and compare exact numerical results with analytical solutions obtained from the random phase approximation (RPA). Except for the region of the phase…

Nuclear Theory · Physics 2008-12-24 Michael G. Bertolli , Thomas Papenbrock

We study the uniform electron gas with a gap model in the context of density functional theory. Based on this analysis, we construct two local gap models that realize generalized gradient approximation (GGA) correlation functionals…

Other Condensed Matter · Physics 2015-01-22 E. Fabiano , P. E. Trevisanutto , A. Terentjevs , L. A. Constantin

We present the multi-channel Dyson equation that combines two or more many-body Green's functions to describe the electronic structure of materials. In this work we use it to model photoemission spectra by coupling the one-body Green's…

Strongly Correlated Electrons · Physics 2023-10-03 Gabriele Riva , Pina Romaniello , J. Arjan Berger

The $GW$ method for calculating quasi-particle energies of solids commonly begin from a DFT Hamiltonian and Kohn-Sham orbitals in a plane wave basis. Screening of the coulomb interaction is implemented using the inverse dielectric function…

Materials Science · Physics 2026-05-20 Charles H. Patterson

The ultimate goal of electronic structure calculations is to make the left and right hand sides of the titled ``equation'' as close as possible. This requires high-precision treatment of relativistic, correlation, and quantum…

Chemical Physics · Physics 2022-10-10 Wenjian Liu

Green's function methods within many-body perturbation theory provide a general framework for treating electronic correlations in excited states. Here we investigate the cumulant form of the one-electron Green's function based on the…

Chemical Physics · Physics 2021-04-23 F. D. Vila , J. J. Rehr , J. J. Kas , K. Kowalski , B. Peng

A simple formula for correlation energy $E_c$ of the $\pi$ electron systems is obtained under an approximation for the electron-electron interactions. This formula is related directly to square of the bond order matrix and the…

Other Condensed Matter · Physics 2007-05-23 Hua Zhao

We present results for the electronic structure of plutonium by using a recently developed quasiparticle self-consistent $GW$ method (\qsgw). We consider a paramagnetic solution without spin-orbit interaction as a function of volume for the…

Strongly Correlated Electrons · Physics 2009-07-23 A. N. Chantis , R. C. Albers , A. Svane , N. E. Christensen

We present a new all-electron, augmented-wave implementation of the GW approximation using eigenfunctions generated by a recent variant of the full-potential LMTO method. The dynamically screened Coulomb interaction W is expanded in a mixed…

Materials Science · Physics 2009-11-07 Takao Kotani , Mark van Schilfgaarde

Using the adiabatic connection, we formulate the free energy in terms of the correlation function of a fictitious system, $h_{\lambda}({\bf r},{\bf r}')$, where $\lambda$ determines the interaction strength. To obtain $h_{\lambda}({\bf…

Statistical Mechanics · Physics 2016-06-15 Derek Frydel , Manman Ma

We report an implementation of self-consistent Green's function many-body theory within a second-order approximation (GF2) for application with molecular systems. This is done by iterative solution of the Dyson equation expressed in matrix…

Chemical Physics · Physics 2016-11-15 Jordan J. Phillips , Dominika Zgid

The good performance of the GW approximation for band-structure calculations in solids was long taken as a sign that the sum of self-energy diagrams is converged and that all omitted terms are small. However, with modern computational…

Materials Science · Physics 2007-05-23 Arno Schindlmayr