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Two non-equidistant grid implementations of infinite range exterior complex scaling are introduced that allow for perfect absorption in the time dependent Schr\"odinger equation. Finite element discrete variables grid discretizations…

Computational Physics · Physics 2015-09-17 Markus Weinmüller , Michael Weinmüller , Jonathan Rohland , Armin Scrinzi

We study the suppression of reflections in the numerical simulation of the time-dependent Schr\"odinger equation for strong-field problems on a grid using exterior complex scaling (ECS) as absorbing boundary condition. It is shown that the…

Atomic Physics · Physics 2007-05-23 F. He , C. Ruiz , A. Becker

We perform a short review of the history of quantum mechanics, with a focus on the historical problems with describing ionization theoretically in the context of quantum mechanics. The essentials of the theory of resonances are presented.…

Quantum Physics · Physics 2021-03-10 Patrik Pirkola

Theoretical treatments of strong-field physics have long relied on the numerical solution of the time-dependent Schr\"odinger equation. The most effective such treatments utilize a discrete spatial representation---a grid. Since most…

Computational Physics · Physics 2018-05-09 Youliang Yu , B. D. Esry

We present an ab initio approach to solve the time-dependent Schr\"odinger equation to treat electron and photon impact multiple ionization of atoms or molecules. It combines the already known time scaled coordinate method with a new high…

A global solution of the Schr\"odinger equation for explicitly time-dependent Hamiltonians is derived by integrating the non-linear differential equation associated with the time-dependent wave operator. A fast iterative solution method is…

Quantum Physics · Physics 2015-05-18 Arnaud Leclerc , Georges Jolicard

A method is proposed for extracting ionization amplitudes from the solution of the time-dependent Schr\"odinger equation (TDSE) describing a system in a time-dependent external field. The method is a hybrid of two earlier developed methods,…

Atomic Physics · Physics 2013-10-30 Vladislav V. Serov , Tatyana A. Sergeeva , Sergue I. Vinitsky

Based on the work of Nuttall and Cohen [Phys. Rev. {\bf 188} (1969) 1542] and Resigno et al{} [Phys. Rev. A {\bf 55} (1997) 4253] we present a rigorous formalism for solving the scattering problem for long-range interactions without using…

Atomic Physics · Physics 2015-05-27 M. V. Volkov , N. Elander , E. Yarevsky , S. L. Yakovlev

The Schroedinger equation with an energy-dependent complex absorbing potential, associated with a scattering system, can be reduced for a special choice of the energy-dependence to a harmonic inversion problem of a discrete pseudo-time…

Chemical Physics · Physics 2009-11-07 A. Neumaier , V. A. Mandelshtam

We present a very efficient technique for solving the three-dimensional time-dependent Schrodinger equation. Our method is applicable to a wide range of problems where a fullly three-dimensional solution is required, i.e., to cases where no…

Atomic Physics · Physics 2009-11-13 T. K. Kjeldsen , L. A. A. Nikolopoulos , L. B. Madsen

A method of solving the time-dependent Schr\"odinger equation is presented, in which a finite region of space is treated explicitly, with the boundary conditions for matching the wave-functions on to the rest of the system replaced by an…

Materials Science · Physics 2009-11-13 J. E. Inglesfield

Absorbing boundaries are frequently employed in real-time propagation of the Schr\"odinger equation to remove spurious reflections and efficiently emulate outgoing boundary conditions. These conditions are a fundamental ingredient for an…

Computational Physics · Physics 2015-02-09 Umberto De Giovannini , Ask Hjorth Larsen , Angel Rubio

Absorbing boundary conditions are presented for three-dimensional time-dependent Schr\"odinger-type of equations as a means to reduce the cost of the quantum-mechanical calculations. The boundary condition is first derived from a…

Numerical Analysis · Mathematics 2020-01-15 Xiaojie Wu , Xiaotao Li

We explore the applicability of splitting methods involving complex coefficients to solve numerically the time-dependent Schr\"odinger equation. We prove that a particular class of integrators are conjugate to unitary methods for…

Numerical Analysis · Mathematics 2021-09-16 S. Blanes , F. Casas , A. Escorihuela-Tomàs

The perfectly matched layers (PML) and exterior complex scaling (ECS) methods for absorbing boundary conditions are analyzed using spectral decomposition. Both methods are derived through analytical continuations from unitary to contractive…

Computational Physics · Physics 2015-06-16 A. Scrinzi , H. P. Stimming , N. J . Mauser

The split-operator pseudo-spectral method based on the fast Fourier transform (SO-FFT) is a fast and accurate method for the numerical solution of the time-dependent Schr\"odinger-like equations (TDSE). As well as other grid-based…

Atomic Physics · Physics 2015-09-02 Vladislav V. Serov , Tatiana A. Sergeeva

In this work we propose a high-order structure-preserving discretization of the cold plasma model which describes the propagation of electromagnetic waves in magnetized plasmas. By utilizing B-Splines Finite Elements Exterior Calculus, we…

Numerical Analysis · Mathematics 2025-01-29 Elena Moral Sánchez , Martin Campos Pinto , Yaman Güçlü , Omar Maj

We present a numerical implementation of the infinite-range exterior complex scaling (irECS) [Phys. Rev. A 81, 053845 (2010)] as an efficient absorbing boundary to the time-dependent complete-active-space self-consistent field (TD-CASSCF)…

Atomic Physics · Physics 2018-03-07 Yuki Orimo , Takeshi Sato , Armin Scrinzi , Kenichi L. Ishikawa

An efficient method is proposed for numerical solutions of nonlinear Schr\"{o}dinger equations in an unbounded domain. Through approximating the kinetic energy term by a one-way equation and uniting it with the potential energy equation,…

Numerical Analysis · Mathematics 2009-11-13 Jiwei Zhang , Zhenli Xu , Xiaonan Wu

The Schr\"odinger equation in the presence of an external electromagnetic field is an important problem in computational quantum mechanics. It also provides a nice example of a differential equation whose flow can be split with benefit into…

Numerical Analysis · Mathematics 2016-04-28 Marco Caliari , Alexander Ostermann , Chiara Piazzola
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