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We consider a microscopic model of a polymer blend that is prone to phase separation. Permanent crosslinks are introduced between randomly chosen pairs of monomers, drawn from the Deam-Edwards distribution. Thereby, not only density but…

Soft Condensed Matter · Physics 2009-11-11 Christian Wald , Paul M. Goldbart , Annette Zippelius

We carry out Monte Carlo simulations to investigate the effect of molecular shape on liquid-crystal order. In our approach, each model mesogen consists of several soft spheres bonded rigidly together. The arrangement of the spheres may be…

Soft Condensed Matter · Physics 2009-11-07 J. Xu , R. L. B. Selinger , J. V. Selinger , R. Shashidhar

We explore the coupling between the helix-coil and coil-globule transitions of a helical polymer using Monte Carlo simulations. A very rich state diagram is found. Each state is characterized by a specific configuration of the chain which…

Soft Condensed Matter · Physics 2007-05-23 Vikas Varshney , Gustavo A. Carri

We study the interplay between the fluid-crystal transition and the glass transition of elastic sphere system with polydispersity using nonequilibrium molecular dynamics simulations. It is found that the end point of the crystal-fluid…

Statistical Mechanics · Physics 2010-09-29 Tomoaki Nogawa , Nobuyasu Ito , Hiroshi Watanabe

This paper reviews recent Monte Carlo simulation studies of the glassy behavior in thin polymer films. The simulations employ a version of the bond-fluctuation lattice model, in which the glass transition is driven by the competition…

Soft Condensed Matter · Physics 2007-05-23 C. Mischler , J. Baschnagel , K. Binder

We review recent simulation studies of interfaces between immiscible homopolymer phases. Special emphasis is given to the presentation of efficient simulation techniques and powerful methods of data analysis, such as the analysis of…

Soft Condensed Matter · Physics 2016-11-03 M. Mueller , F. Schmid

As a model for a suspension of hard-sphere like colloidal particles where small nonadsorbing dissolved polymers create a depletion attraction, we introduce an effective colloid-colloid potential closely related to the Asakura-Oosawa model…

Soft Condensed Matter · Physics 2015-10-28 Antonia Statt , Peter Virnau , Kurt Binder

We use computer simulations to investigate how a catalytic reaction in a polymer sol can induce the formation of a polymer gel. To this aim we consider a solution of homopolymers in which freely-diffusing catalysts convert the originally…

Soft Condensed Matter · Physics 2017-11-10 Virginie Hugouvieux , Walter Kob

The structure of a polystyrene matrix filled with tightly cross-linked polystyrene nanoparticles, forming an athermal nanocomposite system, is investigated by means of a Monte Carlo sampling formalism. The polymer chains are represented as…

Soft Condensed Matter · Physics 2014-01-17 Georgios G. Vogiatzis , Evangelos Voyiatzis , Doros N. Theodorou

We simulate structural phase behavior of polymer-grafted colloidal particles by molecular Monte Carlo technique. Interparticle potential, which has a finite repulsive square-step outside a rigid core of the colloid, was previously confirmed…

Soft Condensed Matter · Physics 2015-03-19 Yuki Norizoe , Toshihiro Kawakatsu

Finite-size and surface effects in fine particle systems are investigated by Monte Carlo simulation of a model of a $\gamma$-Fe$_2$O$_3$ (maghemite) single particle. Periodic boundary conditions have been used to simulate the bulk…

Materials Science · Physics 2007-05-23 Oscar Iglesias , Amilcar Labarta

We study the temperature dependence of static and dynamic responses of Coulomb interacting particles in two-dimensional traps across the thermal crossover from an amorphous solid- to liquid-like behaviors. While static correlations, that…

Disordered Systems and Neural Networks · Physics 2017-10-11 Biswarup Ash , J. Chakrabarti , Amit Ghosal

Hybrid molecular dynamics/Monte Carlo simulations used to study melts of unentangled, thermoreversibly associating supramolecular polymers. In this first of a series of papers, we describe and validate a model that is effective in…

Soft Condensed Matter · Physics 2015-05-13 Robert S. Hoy , Glenn H. Fredrickson

We model polydomain liquid-crystal elastomers by extending the neo-classical soft and semi-soft free energies used successfully to describe monodomain samples. We show that there is a significant difference between polydomains cross-linked…

Soft Condensed Matter · Physics 2014-07-09 J. S. Biggins , M. Warner , K. Bhattacharya

Liquid crystal elastomers (LCEs) are rubber-like solids that incorporate nematic mesogens (stiff rod-like molecules) as a part of their polymer chains. In recent years, isotropic-genesis, polydomain liquid crystal elastomers (I-PLCEs) has…

Soft Condensed Matter · Physics 2023-08-09 Victoria Lee , Adeline Wihardja , Kaushik Bhattacharya

The effect of different Monte Carlo move sets on the the folding kinetics of lattice polymer chains is studied from the geometry of the conformation-network. The networks have the characteristics of small- world. The Monte Carlo move, rigid…

Statistical Mechanics · Physics 2009-11-11 Yu-Pin Luo , Hung-Yeh Lin , Ming-Chang Huang , Tsong-Ming Liaw

We present Monte Carlo simulation results for square-well homopolymers at a series of bond lengths. Although the model contains only isotropic pairwise interactions, under appropriate conditions this system shows spontaneous chiral symmetry…

Soft Condensed Matter · Physics 2009-11-11 James E. Magee , Victor R. Vasquez , Leo Lue

The work is devoted to particles dynamics simulation in a colloidal drop, when it dries on a substrate and the triple-phase boundary is fixed. Experimental observations [Deegan R. D. et. al., 2000] show a ring deposition on a solid…

Soft Condensed Matter · Physics 2019-03-28 K. S. Kolegov

The finite-size effects prominent in zero-range processes exhibiting a condensation transition are studied by using continuous-time Monte Carlo simulations. We observe that, well above the thermodynamic critical point, both static and…

Statistical Mechanics · Physics 2010-09-21 Janne Juntunen , Otto Pulkkinen , Juha Merikoski

Many soft-matter and biophysical systems are composed of monomers which reversibly assemble into rod-like aggregates. The aggregates can then order into liquid-crystal phases if the density is high enough, and liquid-crystal ordering…

Soft Condensed Matter · Physics 2010-07-27 Tatiana Kuriabova , M. D. Betterton , Matthew A. Glaser
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