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The rotational spectrum of the molecular ion HCNH+ is revisited using double-resonance spectroscopy in an ion trap apparatus, with six transitions measured between 74 and 445 GHz. Due to the cryogenic temperature of the trap, the hyperfine…

Chemical Physics · Physics 2024-04-09 Weslley G. D. P. Silva , Luis Bonah , Philipp C. Schmid , Stephan Schlemmer , Oskar Asvany

Energy levels and radiative rates (A-values) for four types of transitions (E1, E2, M1, and M2) are reported for an astrophysically important Mg-like ion Si~III, whose emission lines have been observed in a variety of plasmas. For the…

Atomic Physics · Physics 2016-11-16 K M Aggarwal

The rotational sublevels of the key (000) and (010) vibrational states of the H2S molecule were modeled with an accuracy close to experimental uncertainty using the generating function and Euler approaches. The predictive ability of the…

Chemical Physics · Physics 2021-01-14 O. V. Naumenko , E. R. Polovtseva , A. D. Bykov

Molecular line-transition lists are an essential ingredient for radiative-transfer calculations. With recent databases now surpassing the billion-lines mark, handling them has become computationally prohibitive, due to both the required…

Earth and Planetary Astrophysics · Physics 2017-11-29 Patricio Cubillos

In this paper, energy levels, radiative rates and lifetimes are reported for 11 F-like ions with 12 $\le$ Z $\le$ 23. Up to 198 levels (depending on the ion) have been considered which include 113 of the 2s$^2$2p$^5$, 2s2p$^6$,…

Atomic Physics · Physics 2019-01-16 K M Aggarwal

The wavelength and Einstein A coefficient are calculated for all rotation-vibration transitions of $^4$He$^1$H$^+$, $^3$He$^1$H$^+$, $^4$He$^2$H$^+$ and $^3$He$^2$H$^+$, giving a complete line list and the partition function for $^4$HeH$^+$…

Astrophysics · Physics 2009-11-10 Elodie A. Engel , Natasha Doss , Gregory J. Harris , Jonathan Tennyson

We conducted observations of multiple HC3N (J = 10-9, 12-11, and 16-15) lines and the N2H+ (J = 1-0) line toward a large sample of 61 ultracompact (UC) H II regions, through the Institutde Radioastronomie Millmetrique 30 m and the Arizona…

Astrophysics of Galaxies · Physics 2023-02-21 Y. X. Wang , J. S. Zhang , H. Z. Yu , Y. Wang , Y. T. Yan , J. L. Chen , J. Y. Zhao , Y. P. Zou

Electron-impact cross sections for the dissociation process of vibrationally excited He2+ molecular ion, as a function of the incident electron energy are calculated for the dissociative transition X2\Sigma+u \to A2\Sigma+g by using the…

Plasma Physics · Physics 2015-06-29 R. Celiberto , K. L. Baluja , R. K. Janev , V. Laporta

We aim to study the excitation conditions of the molecular gas in the rotating disk of the Red Rectangle, the only post-Asymptotic-Giant-Branch object in which the existence of an equatorial rotating disk has been demonstrated. For this…

Astrophysics of Galaxies · Physics 2015-06-15 V. Bujarrabal , J. Alcolea

We investigate the molecular gas properties of the deeply obscured luminous infrared galaxy NGC 4418. We address the excitation of the complex molecule HC3N to determine whether its unusually luminous emission is related to the nature of…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-18 F. Costagliola , S. Aalto

Rotationally resolved spectra of the HNC$^+$ and HCN$^+$ molecular ions have been recorded in the spectral range between 6200 and 6800 \rcm\ using a cryogenic ion trap instrument. The rovibrational transitions were probed using two…

Solar and Stellar Astrophysics · Physics 2025-12-16 Miguel Jiménez-Redondo , Chiara Schleif , Julianna Palotás , János Sarka , Hayley Bunn , Petr Dohnal , Paola Caselli , Pavol Jusko

Rotational excitation of isotopologues of HCN and HNC by thermal electron-impact is studied using the molecular {\bf R}-matrix method combined with the adiabatic-nuclei-rotation (ANR) approximation. Rate coefficients are obtained for…

Astrophysics · Physics 2009-11-13 A. Faure , H. N. Varambhia , T. Stoecklin , J. Tennyson

A new line list for H$_2$$^{16}$O is presented. This line list, which is called POKAZATEL, includes transitions between rotation-vibrational energy levels up to 41000 cm$^{-1}$ in energy and is the most complete to date. The potential…

Earth and Planetary Astrophysics · Physics 2018-08-21 Oleg L. Polyansky , Aleksandra A. Kyuberis , Nikolai F. Zobov , Jonathan Tennyson , Sergei N. Yurchenko , Lorenzo Lodi

Any future detection of the calcium monohydroxide radical (CaOH) in stellar and exoplanetary atmospheres will rely on accurate molecular opacity data. Here, we present the first comprehensive molecular line list of CaOH covering the \A--\X\…

Earth and Planetary Astrophysics · Physics 2022-10-25 Alec Owens , Alexander Mitrushchenkov , Sergei N. Yurchenko , Jonathan Tennyson

Sulphur trioxide (SO$_3$) is a trace species in the atmospheres of the Earth and Venus, as well as well as being an industrial product and an environmental pollutant. A variational line list for $^{32}$S$^{16}$O$_{3}$, named UYT2, is…

Earth and Planetary Astrophysics · Physics 2016-09-21 Daniel S. Underwood , Sergei N. Yurchenko , Jonathan Tennyson , Ahmed F. Al-Refaie , Sønnik Clausen , Alexander Fateev

The collision-energy resolved rate coefficient for dissociative recombination of HD+ ions in the vibrational ground state is measured using the photocathode electron target at the heavy-ion storage ring TSR. Rydberg resonances associated…

We present calculated rate coefficients for ro-vibrational transitions of CO in collisions with H atoms for a gas temperature range of 10 K $\leq T \leq$ 3000 K, based on the recent three-dimensional ab initio H-CO interaction potential of…

Astrophysics of Galaxies · Physics 2015-11-23 L. Song , N. Balakrishnan , K. M. Walker , P. C. Stancil , W. F. Thi , I. Kamp , A. van der Avoird , G. C. Groenenboom

Rates for rotational excitation of HC3N by collisions with He atoms and H2 molecules are computed for kinetic temperatures in the range 5-20K and 5-100K, respectively. These rates are obtained from extensive quantum and quasi-classical…

Chemical Physics · Physics 2009-11-13 Michael Wernli , Laurent Wiesenfeld , Alexandre Faure , Pierre Valiron

A rovibronic line list for the ground ($X$ $^3\Sigma^-$) and first excited ($a$ $^1\Delta$) states of phosphinidene, $^{31}$PH, is computed. The line list is designed for studies of exoplanetary and cool stellar atmospheres with…

Earth and Planetary Astrophysics · Physics 2019-07-17 Jonathan Langleben , Jonathan Tennyson , Sergei N. Yurchenko , Peter Bernath

Energies of ns[1/2] (n= 6-9), np[j] (n = 6-8), nd[j] (n= 6-7), and 5f[j] states in neutral Au and Au-like ions with nuclear charges Z = 80 - 83 are calculated using relativistic many-body perturbation theory. Reduced matrix elements,…

Atomic Physics · Physics 2009-11-10 U. I. Safronova , W. R. Johnson
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