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A balanced description of ground and excited states is essential for the description of many chemical processes. However, few methods can handle cases where static correlation is present, and often these scale very unfavourably with system…

Chemical Physics · Physics 2019-05-08 Hugh G. A. Burton , Alex J. W. Thom

High throughput screening of materials for technologically relevant areas, like identification of better catalysts, electronic materials, ceramics for high temperature applications and drug discovery, is an emerging topic of research. To…

Chemical Physics · Physics 2020-05-04 Edgar Josué Landinez Borda , Amit Samanta

We present two improvements to the tight-binding approximation of time-dependent density functional theory (TD-DFTB): Firstly, we add an exact Hartree-Fock exchange term, which is switched on at large distances, to the ground state…

Chemical Physics · Physics 2015-10-28 Alexander Humeniuk , Roland Mitric

Numerical simulations of quantum spin models are crucial for a profound understanding of many-body phenomena in a variety of research areas in physics. An outstanding problem is the availability of methods to tackle systems that violate…

Quantum Physics · Physics 2023-05-31 Fabian Köhler , Rick Mukherjee , Peter Schmelcher

We investigate the multielectron effects on high-harmonic generation from solid-state materials using the time-dependent Hartree-Fock theory. We find qualitative change in harmonic spectra, in particular, multiple-plateau formation at…

Given a time-independent Hamiltonian $\widetilde H$, one can construct a time-dependent Hamiltonian $H_t$ by means of the gauge transformation $H_t=U_t \widetilde H \, U^\dagger_t-i\, U_t\, \partial_t U_t^\dagger$. Here $U_t$ is the unitary…

Quantum Physics · Physics 2021-08-04 Oleksandr Gamayun , Oleg Lychkovskiy

The method of choice for describing attractive quantum systems is Hartree-Fock-Bogoliubov (HFB) theory. This is a nonlinear model which allows for the description of pairing effects, the main explanation for the superconductivity of certain…

Numerical Analysis · Mathematics 2013-11-08 Mathieu Lewin , Séverine Paul

This paper concerns with the large time behavior of solutions to a diffusion approximation radiation hydrodynamics model when the initial data is a small perturbation around an equilibrium state. The global-in-time well-posedness of…

Analysis of PDEs · Mathematics 2022-05-04 Wenjun Wang , Feng Xie , Xiongfeng Yang

We apply in a schematic model a theory beyond mean-field, namely Stochastic Time-Dependent Hartree-Fock (STDHF), which includes dynamical electron-electron collisions on top of an incoherent ensemble of mean-field states by occasional…

Atomic and Molecular Clusters · Physics 2016-10-12 Lionel Lacombe , Paul-Gerhard Reinhard , Eric Suraud , Phuong Mai Dinh

We describe the time-dependent restricted-active-space self-consistent-field (TD-RASSCF) method for a system of interacting bosons. We provide the theory of the method and discuss its numerical implementation. The method provides a general…

Quantum Physics · Physics 2017-04-28 Camille Lévêque , Lars Bojer Madsen

We present a time-dependent extension of logarithmic perturbation theory for nonrelativistic quantum dynamics governed by the Schr\"odinger equation, in which the logarithm of the wave function is expanded in powers of a coupling constant.…

Quantum Physics · Physics 2026-04-17 Juan Carlos del Valle , Paul Bergold , Karolina Kropielnicka

Many-electron systems at substantial finite temperatures and densities present a major challenge to density functional theory. Very little is known about the free-energy behavior over the temperature range of interest, for example, in the…

Materials Science · Physics 2012-01-25 Travis Sjostrom , Frank E. Harris , S. B. Trickey

We review some results of our paper arXiv:1602.05171v2 on the "nonlinear quasifree approximation" to the many-body Schr\"odinger dynamics of Bose gases. In that paper, we derive, with the help of this approximation, the time-dependent…

Mathematical Physics · Physics 2018-05-15 Volker Bach , Sébastien Breteaux , Thomas Chen , Jürg Fröhlich , Israel Michael Sigal

Numerical results for ground state and excited state properties (energies, double occupancies, and Matsubara-axis self energies) of the single-orbital Hubbard model on a two-dimensional square lattice are presented, in order to provide an…

We consider the inhomogeneous biharmonic nonlinear Schr\"odinger equation $$ i u_t +\Delta^2 u+\lambda|x|^{-b}|u|^\alpha u = 0, $$ where $\lambda=\pm 1$ and $\alpha$, $b>0$. In the subctritical case, we improve the global well-posedness…

Analysis of PDEs · Mathematics 2021-05-05 Carlos M. Guzmán , Ademir Pastor

We propose a time-dependent many-body approach to study the short-time dynamics of correlated electrons in quantum transport through nanoscale systems contacted to metallic leads. This approach is based on the time-propagation of the…

Mesoscale and Nanoscale Physics · Physics 2011-11-28 Petri Myohanen , Adrian Stan , Gianluca Stefanucci , Robert van Leeuwen

A self-contained pedagogical introduction to the functional Schr\"{o}dinger picture method of many-body theory is given at a level suitable for graduate students and also for many-body physicists who have not been exposed to the functional…

Strongly Correlated Electrons · Physics 2007-05-23 Chul Koo Kim , Sang Koo You

Various auxiliary-particle approaches to treat electron correlations in many-electron models are analyzed. Applications to copper-oxide layered systems are discussed. The ground-state magnetic phase diagrams are considered within the…

Strongly Correlated Electrons · Physics 2019-02-21 V. Yu. Irkhin , P. A. Igoshev

A many-body wave function is approximated by a product of two functions: the wave function $\phi$ depending on the particle coordinates and the function $\chi$ depending only on the value of interparticle interaction potential. For the…

Quantum Physics · Physics 2008-09-10 V. M. Tapilin

We derive an exact single-body decomposition of the time-dependent Schroedinger equation for N pairwise-interacting fermions. Each fermion obeys a stochastic time-dependent norm-preserving wave equation. As a first test of the method we…

Quantum Physics · Physics 2009-11-10 L. Tessieri , J. Wilkie , M. Cetinbas
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