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We develop an analytic model of vector correlations in rotationally inelastic atom-diatom collisions and test it against the much examined Ar--NO ($\mathbf X^2 \Pi$) system. Based on the Fraunhofer scattering of matter waves, the model…

Chemical Physics · Physics 2017-03-15 Mikhail Lemeshko , Bretislav Friedrich

Stereodynamics of cold collisions has become a fertile ground for quantized studies of molecular collisions and control of the collision outcome. A benchmark process for stereodynamic control is rotational transition in He+HD collisions.…

Chemical Physics · Physics 2020-09-04 Masato Morita , Naduvalath Balakrishnan

Quantum control of molecular collision dynamics is an exciting emerging area of cold collisions. Co-expansion of collision partners in a supersonic molecular beam combined with precise control of their quantum states and…

Chemical Physics · Physics 2021-09-29 Pablo G. Jambrina , James F. E. Croft , Naduvalath Balakrishnan , F. Javier Aoiz

We use numerically exact quantum dynamics calculations to demonstrate universal stereoselectivity of cold collisions of $^2\Pi$ molecules with $^1$S-state atoms in an external electric field. We show that cold collisions of OH molecules in…

Atomic Physics · Physics 2021-06-29 Timur V. Tscherbul , Jacek Kłos

We present an analytic model of thermal state-to-state rotationally inelastic collisions of polar molecules in electric fields. The model is based on the Fraunhofer scattering of matter waves and requires Legendre moments characterizing the…

Chemical Physics · Physics 2008-07-09 Mikhail Lemeshko , Bretislav Friedrich

Stereodynamic control of resonant molecular collisions has emerged as a new frontier in cold molecule research. Recent experimental studies have focused on weakly interacting molecular systems such as HD collisions with H$_2$, D$_2$ and He.…

Chemical Physics · Physics 2020-07-22 Masato Morita , Qian Yao , Changjian Xie , Hua Guo , Naduvalath Balakrishnan

When hydrogen molecules collide with a surface, they can either scatter away from the surface or stick to the surface through a dissociation reaction which leaves two H atoms adsorbed on the surface. The relative probabilities of these two…

Chemical Physics · Physics 2024-10-03 H. Chadwick , G. Zhang , C. J. Baker , P. L. Smith , G. Alexandrowicz

We develop an analytic model of thermal state-to-state rotationally inelastic collisions of asymmetric-top molecules with closed-shell atoms in electric fields, and apply it to the Ar--H$_2$O collision system. The predicted cross sections…

Chemical Physics · Physics 2010-01-05 Mikhail Lemeshko , Bretislav Friedrich

The diffraction of fast atoms at crystal surfaces is ideal for a detailed investigation of the surface electronic density. However, instead of sharp diffraction spots, most experiments show elongated streaks characteristic of inelastic…

Atomic Physics · Physics 2017-08-02 Philippe Roncin , Maxime Debiossac

In molecular collisions, resonances occur at specific energies where the colliding particles temporarily form quasi-bound complexes, resulting in rapid variations in the energy dependence of scattering cross sections. Experimentally, it has…

We study the breakdown of diffusive hydrodynamics in holographic systems dual to neutral dilatonic black holes with extremal near horizon geometries conformal to AdS$_2\times\,$R$^2$. We find that at low temperatures by tuning the effective…

High Energy Physics - Theory · Physics 2022-01-28 Yan Liu , Xin-Meng Wu

Ultracold collisions of polar OH molecules are considered in the presence of an electrostatic field. The field exerts a strong influence on both elastic and state-changing inelastic collision rate constants, leading to clear experimental…

Atomic Physics · Physics 2009-11-07 Alexandr V. Avdeenkov , John L. Bohn

Inelastic low-energy (0--1 eV) collisions of electrons with HeH$^+$ cations are treated theoretically, with a focus on the rovibrational excitation and dissociative recombination (DR) channels. In an application of {\it ab initio}…

Chemical Physics · Physics 2017-10-30 Roman Čurík , Chris H. Greene

Whereas collisions between atoms and molecules are largely understood, collisions between two molecules have proven much harder to study. In both experiment and theory, our ability to determine quantum state-resolved bimolecular cross…

We investigate the effects of a magnetic field on the dynamics of rotationally inelastic collisions of open-shell molecules ($^2\Sigma$, $^3\Sigma$, and $^2\Pi$) with closed-shell atoms. Our treatment makes use of the Fraunhofer model of…

Atomic Physics · Physics 2009-02-02 Mikhail Lemeshko , Bretislav Friedrich

The model of nonlinear interaction of proper waves of photonic crystal with plane acoustic wave was developed. The formulation of the model is reduced to the eigenvalue problem, which can be solved by computer simulations. By means of the…

Optics · Physics 2010-01-12 Z. A. Pyatakova

Scattering and ionizing cross sections and rates are calculated for ultracold collisions between metastable helium atoms using a fully quantum-mechanical close-coupled formalism. Homonuclear collisions of the bosonic ${}^{4}$He$^{*}…

Atomic Physics · Physics 2019-07-03 D. G. Cocks , I. B. Whittingham , G. Peach

The inelastic scattering of fast electrons by metastable hydrogen atoms in the presence of a linearly polarized laser field is theoretically studied in the domain of moderate field intensities. The interaction of the hydrogen atom with the…

Atomic Physics · Physics 2023-06-19 Gabriela Buica

Two different ab initio potential energy surfaces are employed to investigate the efficiency of the rotational excitation channels for the polar molecular ion HeH$^+$ interacting with He atoms. We further use them to investigate the quantum…

We theoretically study the influence of laser polarization in inelastic scattering of electrons by hydrogen atoms in the presence of a circularly polarized laser field in the domain of field strengths below $10^{7}$ V/cm and high projectile…

Atomic Physics · Physics 2023-06-16 Gabriela Buică
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