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We have developed a method based on the embedded Kadanoff-Baym equations to study the time evolution of open and inhomogeneous systems. The equation of motion for the Green's function on the Keldysh contour is solved using different…

Mesoscale and Nanoscale Physics · Physics 2011-11-28 Petri Myöhänen , Adrian Stan , Gianluca Stefanucci , Robert van Leeuwen

Electronic conductance through a single molecule is sensitive towards its structural orientation between two electrodes, owing to the distribution of molecular orbitals and their coupling to the electrode levels, that are governed by…

Mesoscale and Nanoscale Physics · Physics 2023-08-11 Koushik R. Das , Sudipta Dutta

In this work we theoretically study steady state thermoelectric transport through a single-molecule junction with a long chain-like bridge. Electron transmission through the system is computed using a tight-binding model for the bridge. We…

Mesoscale and Nanoscale Physics · Physics 2018-03-02 Natalya A. Zimbovskaya , Abraham Nitzan

Combining density functional theory calculations for molecular electronic structure with a Green function method for electron transport, we calculate from first principles the molecular conductance of benzene connected to two Au leads…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 San-Huang Ke , Harold U. Baranger , Weitao Yang

We consider a model of a molecular junction made of BDT (benzene dithiol) molecule trapped between two Au(100) leads. Using the ab initio approach implemented in the SIESTA package we look for the optimal configuration of the molecule as a…

Materials Science · Physics 2015-06-25 Victor M. Garcia-Suarez , Tomasz Kostyrko , Steven Bailey , Colin Lambert , Bogdan R. Bulka

We present a systematic ab-initio study of the length dependence of the thermopower in molecular junctions. The systems under consideration are small saturated and conjugated molecular chains of varying length attached to gold electrodes…

Mesoscale and Nanoscale Physics · Physics 2015-12-15 Falco Hüser , Gemma C. Solomon

Devices made of few molecules constitute the miniaturization limit that both inorganic and organic-based electronics aspire to reach. However, integration of millions of molecular junctions with less than 100 molecules each has been a long…

Mesoscale and Nanoscale Physics · Physics 2013-02-11 Kacem Smaali , Nicolas Clement , Gilles Patriarche , Dominique Vuillaume

Temperature ($T$) dependent conductance $G = G(T)$ data measured in molecular junctions are routinely taken as evidence for a two-step hopping mechanism. The present paper emphasizes that this is not necessarily the case. A curve of $\ln G$…

Mesoscale and Nanoscale Physics · Physics 2022-12-01 Ioan Baldea

The wide-band limit is a commonly used approximation to analyze transport through nanoscale devices. In this work we investigate its applicability to the study of charge and heat transport through molecular break junctions exposed to…

Mesoscale and Nanoscale Physics · Physics 2018-05-15 F. Covito , F. G. Eich , R. Tuovinen , M. A. Sentef , A. Rubio

The conductance of a single metal-molecule-metal junction depends critically on the conformations of the molecule. In the simple case of a biphenyl, two phenyl rings linked together by a single C-C bond, the conductance is expected to…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Latha Venkataraman , Jennifer E. Klare , Colin Nuckolls , Mark S. Hybertsen , Michael L. Steigerwald

The electron tunneling through a molecular junction modeled by a single site weakly coupled to two leads is studied in the presence of a time-dependent external field using a master equation approach. In the case of small bias voltages and…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Guangqi Li , Michael Schreiber , Ulrich Kleinekathoefer

We investigate the conformation-dependent electron transfer in a biphenyl molecule within a simple tight-binding framework. The overall junction current and circular currents in two benzene rings driven by applied bias voltage are…

Mesoscale and Nanoscale Physics · Physics 2013-07-02 Santanu K. Maiti

We study charge and energy transfer in two-site molecular electronic junctions in which electron transport is assisted by a vibrational mode. To understand the role of mode harmonicity/anharmonicity on transport behavior, we consider two…

Mesoscale and Nanoscale Physics · Physics 2015-09-01 Bijay Kumar Agarwalla , Jian-Hua Jiang , Dvira Segal

We present a microscopic model for calculating the AC conductivity of a finite length line junction made up of two counter or co-propagating single mode quantum Hall edges with possibly different filling fractions. The effect of…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Amit Agarwal , Diptiman Sen

We study the model of a molecular switch comprised of a molecule with a soft vibrational degree of freedom coupled to metallic leads. In the presence of strong electron-ion interaction, different charge states of the molecule correspond to…

Mesoscale and Nanoscale Physics · Physics 2008-12-18 Fabio Pistolesi , Yaroslav M. Blanter , Ivar Martin

A time-dependent approach is used to explore inelastic effects during electron transport through few-level systems. We study a tight-binding chain with one and two sites connected to vibrations. This simple but transparent model gives…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 S. Monturet , N. Lorente

We present a theoretical study of the electronic transport through a many-level quantum dot driven by time-dependent signals applied at the contacts to the leads. If the barriers oscillate out of phase the system operates like a turnstile…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Valeriu Moldoveanu , Vidar Gudmundsson , Andrei Manolescu

A minimal model for coherent transport through a donor/acceptor molecular junction is presented. The two donor and acceptor sites are described by single levels energetically separated by an intramolecular tunnel barrier. In the limit of…

Disordered Systems and Neural Networks · Physics 2009-11-11 Florian Pump , Gianaurelio Cuniberti

Quantum transport through single molecules is very sensitive to the strength of the molecule-electrode contact. Here, we investigate the behavior of a model molecular junction weakly coupled to external electrodes in the case where charging…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Bo Song , Dmitry A. Ryndyk , Gianaurelio Cuniberti

We present a fully nonequilibrium calculation of the low-temperature transport properties of a single molecular quantum dot coupled to local phonon mode when an ac field is applied to the gate. The resonant behavior is shown in the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Rong Lu