Related papers: Constraining the Environment of CH+ Formation with…
We used the Plateau de Bure Interferometer to search for $\lambda$3mm absorption lines of HOC+ from local diffuse and translucent clouds occulting compact extragalactic mm-wave continuum sources. We detected HOC+ in three directions with…
Complex organic molecules (COMs) are often observed toward embedded Class 0 and I protostars. However, not all Class 0 and I protostars exhibit COMs emission. In this work, variations in methanol (CH$_3$OH) emission are studied to test if…
We have performed a theoretical investigation of the S$^+$($^4$S) + SiH$_{2}$($^1$A$_1$) reaction, a possible formation route of the HSiS$^+$ and SiSH$^+$ cations that are alleged to be precursors of interstellar silicon sulfide, SiS.…
Star-forming regions host a large and evolving suite of molecular species. Molecular transition lines, particularly of complex molecules, can reveal the physical and dynamical environment of star formation. We aim to study the large-scale…
The C$^{+}$ ion is an important coolant of interstellar gas, and so the [CII] fine structure line is frequently observed in the interstellar medium. However, the physical and chemical properties of the [CII]-emitting gas are still unclear.…
Most stars in the Galaxy, including the Sun, were born in high-mass star-forming regions. It is hence important to study the chemical processes in these regions to better understand the chemical heritage of both the Solar System and most…
We analyze mutual relations between interstellar extinction E(B-V) and column densities of diatomic molecules such as CN, CH and CH cation observed along translucent sightlines. Observational material acquired using five echelle…
New insights into the formation of interstellar formamide, a species of great relevance in prebiotic chemistry, are provided by electronic structure and kinetic calculations for the reaction NH2 + H2CO -> NH2CHO + H. Contrarily to what…
CH2D+, the singly deuterated counterpart of CH3+, offers an alternative way to mediate formation of deuterated species at temperatures of several tens of K, as compared to the release of deuterated species from grains. We report a…
The H3+ ion plays a key role in the chemistry of dense interstellar gas clouds where stars and planets are forming. The low temperatures and high extinctions of such clouds make direct observations of H3+ impossible, but lead to large…
Rate constants have been measured for the C(3P) + CH3CN reaction between 50 K and 296 K using a continuous-flow supersonic reactor. C(3P) atoms were created by the in-situ pulsed laser photolysis of CBr4 at 266 nm, while the kinetics of…
Forty years ago it was proposed that gas phase organic chemistry in the interstellar medium was initiated by the methyl cation CH3+, but hitherto it has not been observed outside the Solar System. Alternative routes involving processes on…
We explore the energetics of the titular reaction, which current astrochemical databases consider open at typical dense molecular (i.e., dark) cloud conditions. As is common for reactions involving the transfer of light particles, we assume…
We investigate the role of carbon monoxide ice in the chemical evolution of prestellar cores using astrochemical rate equation models. We constrain the ratios of the binding energies on CO ice and H$_{2}$O ice for a series of adsorbates…
Methanol (CH3OH) is thought to form on interstellar ice dust via successive hydrogenation reactions. The reaction between CH3 and OH radicals could also conceivably generate methanol at temperatures above approximately 20 K, at which…
Pre-stellar cores represent the earliest stage of the star- and planet-formation process. By characterizing the physical and chemical structure of these cores we can establish the initial conditions for star and planet formation and…
We report the detection in TMC-1 of the protonated form of C3S. The discovery of the cation HC3S+ was carried through the observation of four harmonically related lines in the Q band using the Yebes 40m radiotelescope, and is supported by…
Solid-phase photo-processes involving icy dust grains greatly affect the chemical evolution of the interstellar medium by leading to the formation of complex organic molecules and by inducing photodesorption. So far, the focus of laboratory…
We survey the current situation regarding chemical modelling of the synthesis of molecules in the interstellar medium. The present state of knowledge concerning the rate coefficients and their uncertainties for the major gas-phase processes…
Shocks, modelled over a broad range of parameters, are used to construct a new tool to deduce the mechanical energy and physical conditions from observed atomic or molecular emission lines. We compute magnetised, molecular shock models with…