Related papers: Constraining the Environment of CH+ Formation with…

Atomic carbon in its ground electronic state, C(3P), is expected to be present at high abundances during the evolution of dense molecular clouds. Consequently, its reactions with other interstellar species could have a strong influence on…

Mono-deuterated methanol is thought to form during the prestellar core stage of star formation. Observed variations in the CH2DOH/CH3OD ratio suggest that its formation is strongly dependent on the surrounding cloud conditions. Thus, it is…

Interstellar amides have attracted significant attentions as they are potential precursors for a wide variety of organics essential to life. However, our current understanding of their formation in space is heavily based on observations in…

We aim at studying the cluster environment surrounding the UCHII region in IRAS 20293+3952, a region in the first stages of formation of a cluster around a high-mass star. BIMA and VLA were used to observe the 3 mm continuum, N2H+(1-0),…

(Abridged) Gas-phase complex organic molecules are commonly detected in the warm inner regions of protostellar envelopes. Recent models show that photochemistry in ices followed by desorption may explain the observed abundances. This study…

We investigate the formation and evolution of interstellar dust-grain ices under dark-cloud conditions, with a particular emphasis on CO2. We use a three-phase model (gas/surface/mantle) to simulate the coupled gas--grain chemistry,…

The cosmic abundance of hydrides depends critically on high-energy UV, X-ray, and particle irradiation. Here we study hydrides in star-forming regions where irradiation by the young stellar object can be substantial, and density and…

In the cold neutral medium, high out-of-equilibrium temperatures are created by intermittent dissipation processes, including shocks, viscous heating, and ambipolar diffusion. The high-temperature excursions are thought to explain the…

We report on a search for Interstellar CH2D+. Four transitions occur in easily accessible portions of the spectrum; we report on emission at the frequencies of these transitions toward high column density star-forming regions. While the…

Among all closed-shell species observed in molecular clouds, molecules with C$_{3v}$ symmetry play a crucial role, as their rotational spectroscopy allows them to behave as a gas thermometer. In the interstellar medium, methyl cyanide…

Iram 30-m Observations towards eight protostellar outflow sources were taken in the 96-\SI{176}{\giga\hertz} range. Transitions of CH$_3$OH and CH$_3$CHO were detected in seven of them. The integrated emission of the transitions of each…

We discuss the first astronomical detection of the CF+ (fluoromethylidynium) ion, obtained by observations of the J=1-0 (102.6 GHz), J=2-1 (205.2 GHz) and J=3-2 (307.7 GHz) rotational transitions toward the Orion Bar region. Our search for…

Observations with the Short Wavelength Spectrometer (SWS) onboard the {\it Infrared Space Observatory} (ISO) have led to the first detection of the methyl radical ${\rm CH_3}$ in the interstellar medium. The $\nu_2$ $Q-$branch at 16.5…

Many chemical models of dense interstellar clouds predict that the majority of gas-phase elemental nitrogen should be present as N2, with an abundance approximately five orders of magnitude less than that of hydrogen. As a homonuclear…

The CH$_3$O and CH$_2$OH radicals can be important precursors of complex organic molecules (COMs) in interstellar dust. The COMs presumably originating from these radicals were abundantly found in various astronomical objects. Because each…

The abundance of CH+ and OH and excitation are predicted to be enhanced by the presence of vibrationally excited H2 or hot gas (~500-1000 K) in PDRs with high incident FUV radiation field. The excitation may also originate in dense gas…

Formic acid (HCOOH) and carbon dioxide (CO2) are simple species that have been detected in the interstellar medium. The solid-state formation pathways of these species under experimental conditions relevant to prestellar cores are primarily…

We investigate chemistry in the compression layer behind the interstellar shock waves, where molecular cloud formation starts. We perform three-dimensional magnetohydrodynamics simulations of converging flows of atomic gas with shock…

Nitrogen-bearing molecules are more difficult to observe than oxygen-bearing ones, mainly due to the lower abundance of nitrogen in the interstellar medium. Therefore, the formation pathways of many of these species is still under debate.…

The rate constants required to model the OH$^+$ observations in different regions of the interstellar medium have been determined using state of the art quantum methods. First, state-to-state rate constants for the H$_2(v=0,J=0,1)$+…