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SrTiO$_3$ is a model perovskite compound with unique properties and technological relevance. At 105 K it undergoes a transition from a cubic to a tetragonal phase with characteristic antiferrodistortive rotations of the TiO$_6$ octahedra.…

Strongly Correlated Electrons · Physics 2019-06-07 Vijaya Begum , Markus Ernst Gruner , Rossitza Pentcheva

We investigate the evolution of the electronic structure in SrRu_(1-x)Ti_xO_3 as a function of x using high resolution photoemission spectroscopy, where SrRuO3 is a weakly correlated metal and SrTiO3 is a band insulator. The surface spectra…

Strongly Correlated Electrons · Physics 2009-11-13 Kalobaran Maiti , Ravi Shankar Singh , V. R. R. Medicherla

We have studied the cubic to tetragonal phase transition in epitaxial SrTiO$_3$ films under various biaxial strain conditions using synchrotron X-ray diffraction. Measuring the superlattice peak associated with TiO$_6$ octahedra rotation in…

Condensed Matter · Physics 2007-05-23 Feizhou He , B. O. Wells , S. M. Shapiro , M. v. Zimmermann , A. Clark , X. X. Xi

We investigated with synchrotron x-ray diffraction and reflectometry the formation of structural domains in the near-surface region of single crystalline SrTiO3 (001) substrates with Y0.6Pr0.4Ba2Cu3O7 / La2/3Ca1/3MnO3 superlattices grown on…

The quasi-two-dimensional electronic gas at the (111) SrTiO$_3$-based heterostructure interfaces is described by a multi-band tight-binding model providing electronic bands in agreement at low energies with photoemission experiments. We…

Materials Science · Physics 2022-02-14 Mattia Trama , Carmine Antonio Perroni , Vittorio Cataudella

We present x-ray reflectivity, x-ray diffraction and atomic force microscopy measurements of single crystal SrTiO3 taken as a function of temperature. We found a rumpling transformation of the SrTiO3 surface after cooling the sample below…

Materials Science · Physics 2014-11-18 S. Singh , Te-Yu Chien , J. R. Guest , M. R. Fitzsimmons

The dynamic structures of the cubic and tetragonal phase in BaTiO3 and its dielectric response above the cubic-to-tetragonal phase transition temperature (Tp) are studied by first-principles molecular dynamics (MD) simulation. It's shown…

Materials Science · Physics 2015-05-20 L. Xie , Y. L. Li , R. Yu , J. Zhu

The structural and magnetic properties of the hexagonal four-layer form of SrMnO$_3$ have been investigated by combining magnetization measurements, electron diffraction and high-resolution synchrotron X-ray and neutron powder diffraction.…

Strongly Correlated Electrons · Physics 2007-05-23 A. Daoud-Aladine , C. Martin , L. C. Chapon , M. Hervieu , K. S. Knight , M. Brunelli , P. G. Radaelli

Using angle-resolved photoemission spectroscopy, we show that the recently-discovered surface state on SrTiO$_{3}$ consists of non-degenerate $t_{2g}$ states with different dimensional characters. While the $d_{xy}$ bands have quasi-2D…

Charge redistribution across heterojunctions has long been utilized to induce functional response in materials systems. Here we examine how the composition of the terminating surface affects charge transfer across a heterojunction…

Materials Science · Physics 2023-03-28 M. Chrysler , J. Gabel , T. -L. Lee , Z. Zhu , T. C. Kaspar , P. V. Sushko , S. A. Chambers , J. H. Ngai

We have studied the transport properties of LaTiO3/SrTiO3 (LTO/STO) heterostructures. In spite of 2D growth observed in reflection high energy electron diffraction, Transmission Electron Microscopy images revealed that the samples tend to…

Mesoscale and Nanoscale Physics · Physics 2020-12-30 N. Lebedev , M. Stehno , A. Rana , N. Gauquelin , J. Verbeeck , A. Brinkman , J. Aarts

We have recently predicted and subsequently verified experimentally by specific heat measurements that EuTiO3 undergoes a structural phase transition at elevated temperature TS = 282 K. The origin of the phase transition has been attributed…

Materials Science · Physics 2012-05-25 J. Köhler , R. Dinnebier , A. Bussmann-Holder

We present a Coherent X-ray Diffraction study of the antiferrodistortive displacive transition of SrTiO$_3$, a prototypical example of a phase transition for which the critical fluctuations exhibit two length scales and two time scales.…

Materials Science · Physics 2015-06-25 S. Ravy , D. Le Bolloc'h , R. Currat , A. Fluerasu , C. Mocuta , B. Dkhil

The phase purity and crystal structure of PLTA samples (synthesized via sol-gel process) were confirmed using synchrotron x-ray powder diffraction (wavelength, lmbda= 0.44573 A. Rietveld analyses of powder x-ray diffraction data confirmed…

The structural flexibility at three substitution sites in LaFeAsO enabled investigation of the relation between superconductivity and structural parameters over a wide range of crystal compositions. Substitutions of Nd for La, Sb or P for…

Superconductivity · Physics 2021-06-09 T. Kawashima , S. Miyasaka , H. Tsuji , T. Yamamoto , M. Uekubo , A. Takemori , K. T. Lai , S. Tajima

We used x-ray absorption spectroscopy to study the orbital symmetry and the energy band splitting of (111) LaAlO${_3}$/SrTiO${_3}$ and LaAlO${_3}$/EuTiO${_3}$/SrTiO${_3}$ heterostructures, hosting a quasi two-dimensional electron system…

We demonstrate that zero-field $\beta$-detected nuclear quadrupole resonance and spin relaxation of low energy $^8$Li can be used as a sensitive local probe of structural phase transitions near a surface. We find that the transition near…

EuTiO_{3} undergoes a structural phase transition from cubic to tetragonal at T_S = 282 K which is not accompanied by any long range magnetic order. However, it is related to the oxygen ocathedra rotation driven by a zone boundary acoustic…

Materials Science · Physics 2013-01-28 Z. Guguchia , H. Keller , J. Kohler , A. Bussmann-Holder

Strontium titanate SrTiO$_3$ is one of the most studied and paradigmatic transition metal oxides. Recently, a breakthrough has been achieved with the fabrication of freestanding SrTiO$_3$ ultrathin films down to the monolayer limit.…

Materials Science · Physics 2023-03-28 Lorenzo Varrassi , Peitao Liu , Cesare Franchini

Understanding charge transfer at oxide interfaces is crucial for designing materials with emergent electronic and magnetic properties, especially in systems where strong electron correlations and spin-orbit coupling coexist.…

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