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Spin-density-functional calculations of tip-suspended gold chains, with molecular oxygen, or dissociated oxygen atoms, incorporated in them, reveal structural transitions for varying lengths. The nanowires exhibit enhanced strength for both…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Chun Zhang , R. N. Barnett , Uzi Landman

Carbene-metal-amides (CMAs) are a promising family of donor-bridge-acceptor molecular charge-transfer emitters for organic light-emitting diodes (OLEDs). Here a universal approach is introduced to tune the energy of their charge-transfer…

Excitation energy transfer (EET) in an organic/inorganic nanohybrid system, composed of a single \textit{para}-sexiphenyl (6P) molecule physisorbed on a finite-sized MoS$_2$ nanoflake, is investigated theoretically. % The electronic…

Mesoscale and Nanoscale Physics · Physics 2026-01-22 Yan Meng , Kainan Chang , Luxia Wang

The concept of alloy engineering has emerged as a viable technique towards tuning the bandgap as well as engineering the defect levels in two-dimensional transition metal dichalcognides (TMDC). Possibility to synthesize these ultrathin TMDC…

Materials Science · Physics 2022-07-01 Shubhrasish Mukherjee , Didhiti Bhattacharya , Samit Kumar Ray , Atindra Nath Pal

Phosphorene is a promising single elemental two-dimensional layered semiconductor with huge potential for future nanoelectronics and spintronics applications. In this work, we investigated the effect of an organic molecule (benzene) in the…

Mesoscale and Nanoscale Physics · Physics 2019-07-09 A. Chaudhury , S. Majumder , S. J. Ray

We have fabricated suspended few layer (1-3 layers) graphene nanoribbon field effect transistors from unzipped multiwall carbon nanotubes. Electrical transport measurements show that current-annealing effectively removes the impurities on…

The electronic properties of interfaces between two different solids can differ strikingly from those of the constituent materials. For instance, metallic conductivity, and even superconductivity, have been recently discovered at interfaces…

Materials Science · Physics 2009-11-13 H. Dias Alves , A. S. Molinari , H. Xie , A. F. Morpurgo

We reveal the role of aurophilic interactions in the formation and conductance of gold cyanide molecular wires of variable length-to-width ratios assembled at the tip of an STM break junction in ambient conditions. Specifically, we identify…

Mesoscale and Nanoscale Physics · Physics 2025-08-05 Sigifredo Luna , Hannah E Skipper , Brent Lawson , Eric S Cueny , Maria Kamenetska

The band offsets between crystalline and hydrogenated amorphous silicon (a-Si:H) are key parameters governing the charge transport in modern silicon hetrojunction solar cells. They are an important input for macroscopic simulators that are…

Materials Science · Physics 2017-08-02 K. Jarolimek , E. Hazrati , R. A. de Groot , G. A. de Wijs

We validate that off-resonant electron transport across {\it ultra-short} oligomer molecular junctions is characterised by a conductance which decays exponentially with length, and we discuss a method to determine the damping factor via the…

Materials Science · Physics 2007-05-23 Giorgos Fagas , Agapi Kambili , Marcus Elstner

We report a detailed comparison on the role of a self-assembled monolayer (SAM) of dipolar molecules on the threshold voltage and charge carrier mobility of organic field-effect transistor (OFET) made of both amorphous and polycrystalline…

Materials Science · Physics 2014-02-05 C. Celle , C. Suspene , M. Ternisien , S. Lenfant , D. Guerin , K. Smaali , K. Lmimouni , J. P. Simonato , D. Vuillaume

A common issue in low temperature measurements of enhancement-mode metal-oxide-semiconductor (MOS) field-effect transistors (FETs) in the low electron density regime is the high contact resistance dominating the device impedance. In that…

Mesoscale and Nanoscale Physics · Physics 2011-10-10 Laurens H. Willems Van Beveren , Kuan Y. Tan , Nai-Shyan Lai , Oleh Klochan , Andrew S. Dzurak , Alex R. Hamilton

We review theories of phosphorescence in cyclometalated complexes. We focus primarily on pseudooctahedrally coordinated $t_{2g}^6$ metals (e.g., [Os(II)(bpy)$_3$]$^{2+}$, Ir(III)(ppy)$_3$ and Ir(III)(ptz)$_3$) as, for reasons that are…

Chemical Physics · Physics 2015-04-02 B. J. Powell

Designing molecular organic semiconductors with distinct frontier orbitals is key for the development of devices with desirable properties. Generating defined organic nanostructures with atomic precision can be accomplished by on-surface…

Atomic-sized junctions of iron, created by controlled rupture, present unusually high values of conductance compared to other metals. This result is counter-intuitive since, at the nanoscale, body-centered cubic metals are expected to…

Mesoscale and Nanoscale Physics · Physics 2020-04-29 W. Dednam , C. Sabater , M. R. Calvo , C. Untiedt , J. J. Palacios , A. E. Botha , M. J. Caturla

The transport properties of nanostructured systems are deeply affected by the geometry of the effective connections to metallic leads. In this work we derive a conductance expression for interacting systems whose connectivity geometries do…

Mesoscale and Nanoscale Physics · Physics 2017-09-15 Luis G. G. V. Dias da Silva , Caio H. Lewenkopf , Edson Vernek , Gerson J. Ferreira , Sergio E. Ulloa

Here we report further investigation on the thermodynamic, and transport properties, and the first assessment of theoretical calculations for the BiS2-layered Bi3O2S3 superconductor. The polycrystalline sample is synthesized with the…

Superconductivity · Physics 2015-06-23 L. Li , D. Parker , P. Babkevich , L. Yang , H. M. Ronnow , A. S. Sefat

We report here the reversibility and bistability of the switching behavior in an azobenzene derivative induced by the bias applied by a Scanning-Tunneling Microscopy (STM) tip, at low temperature and in ultra-high vacuum environment. This…

Materials Science · Physics 2025-01-08 Sylvie Godey , Hugo Therssen , David Guérin , Thierry Melin , Stéphane Lenfant

The switching behaviour of stilbene molecular system (SMS) device is investigated with the help of non-equilibrium Green's function (NEGF) approach using first principles calculation. The transmission spectrum of cis-isomers confirmed that…

Mesoscale and Nanoscale Physics · Physics 2018-12-21 V. Nagarajan , R. Chandiramouli

Strongly differing static dipole moments of the trans and cis isomers of photochromic azobenzene allow for optical switching the work function of azobenzene-functionalized self-assembled monolayers (SAMs). We apply these properties in a…

Mesoscale and Nanoscale Physics · Physics 2024-02-26 Jan Böhnke , Beatrice Andres , Larissa Boie , Angela Richter , Cornelius Gahl , Martin Weinelt , Wibke Bronsch
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