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Related papers: Modeling of Nucleation Processes

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The nucleation of crystals in liquids is one of nature's most ubiquitous phenomena, playing an important role in areas such as climate change and the production of drugs. As the early stages of nucleation involve exceedingly small time and…

Systems with long-range interactions when quenced into a metastable state near the pseudo-spinodal exhibit nucleation processes that are quite different from the classical nucleation seen near the coexistence curve. In systems with…

Materials Science · Physics 2009-11-07 W. Klein , T. Lookman , A. Saxena , D. Hatch

An analytical description of nucleation stage in a supersaturated vapor with instantly created supersaturation is given with taking into account the vapor concentration inhomogeneities arising as a result of depletion due to non-stationary…

Chemical Physics · Physics 2014-04-25 Anatoly Kuchma , Maxim Markov , Alexander Shchekin

Classical nucleation theory (CNT), linking rare nucleation events to the free energy landscape of a growing nucleus, is central to understanding phase-change kinetics in passive fluids. Nucleation in non-equilibrium systems is much harder…

Soft Condensed Matter · Physics 2023-03-15 M. E. Cates , C. Nardini

A phase transformation in a metastable phase can be affected when it is subjected to a high intensity ultrasound wave. In this study we determined the effect of oscillation in pressure and temperature on a phase transformation using the…

Statistical Mechanics · Physics 2016-08-17 S. R. Haqshenas , I. J. Ford , N. Saffari

We discuss the structure of the equation of motion that governs nucleation processes at first order phase transitions. From the underlying microscopic dynamics of a nucleating system, we derive by means of a non-equilibrium projection…

Statistical Mechanics · Physics 2019-12-04 Anja Kuhnhold , Hugues Meyer , Graziano Amati , Philipp Pelagejcev , Tanja Schilling

Corrections to a mean number of droplets appeared in the process of nucleation have been analyzed. The two stage model with a fixed boundary can not lead to a write result. The multi stage generalization of this model also can not give…

Statistical Mechanics · Physics 2007-05-23 Victor Kurasov

Classical nucleation theory offers a good framework for understanding the common features of new phase formation processes in metastable homogeneous media at rest. However, nucleation processes in liquids are ubiquitously affected by…

Soft Condensed Matter · Physics 2016-04-18 F. Mura , A. Zaccone

The basic physics of nucleation in solid \hl{single-crystal} nanoparticles is revealed by a phase-field theory that includes surface energy, chemical reactions and coherency strain. In contrast to binary fluids, which form arbitrary contact…

Materials Science · Physics 2014-09-17 Daniel A. Cogswell , Martin Z. Bazant

Nucleation is an out-of-equilibrium process, which can be strongly affected by the presence of external fields. In this letter, we report a simple extension of classical nucleation theory to systems submitted to an homogeneous shear flow.…

Statistical Mechanics · Physics 2013-06-17 Anatolii V. Mokshin , Bulat N. Galimzyanov , Jean-Louis Barrat

Macroscopic theories of nucleation such as classical nucleation theory envision that clusters of the bulk stable phase form inside the bulk metastable phase. Molecular dynamics simulations are often used to elucidate nucleation mechanisms,…

Materials Science · Physics 2017-09-06 Bingqing Cheng , Michele Ceriotti

We use a simplified model which is based on the same physics as inherent in most statistical models for nuclear multifragmentation. The simplified model allows exact calculations for thermodynamic properties of systems of large number of…

Nuclear Theory · Physics 2008-11-26 S. Das Gupta , A. Z. Mekjian

We consider a system of clusters made of elementary building blocks, monomers, and evolving via collisions between diffusing monomers and immobile composite clusters. In our model, the cluster-monomer collision can lead to the attachment of…

Statistical Mechanics · Physics 2017-10-25 P. L. Krapivsky , W. Otieno , N. V. Brilliantov

Crystallization of supersaturated liquids usually starts by heterogeneous nucleation. Mounting evidence shows that even homogeneous nucleation in simple liquids takes place in two steps; first a dense amorphous precursor forms, and the…

Materials Science · Physics 2014-07-15 László Gránásy , Frigyes Podmaniczky , Gyula I. Tóth , György Tegze , Tamás Pusztai

The microscopic model in which nodes interacting with each other are statistical systems is introduced. The nodes conditions are connected with a string of distinct microscopic configurations and depend on external parameters (pressure and…

Statistical Mechanics · Physics 2007-05-23 V. Stepanov

Phase transformations such as freezing typically start with heterogeneous nucleation. Heterogeneous nucleation near a wetting transition, of a crystalline phase is studied. The wetting transition occurs at or near a vapour-liquid transition…

Statistical Mechanics · Physics 2009-11-07 Richard P. Sear

Nucleation phenomena commonly observed in our every day life are of fundamental, technological and societal importance in many areas, but some of their most intimate mechanisms remain however to be unravelled. Crystal nucleation, the early…

Disordered Systems and Neural Networks · Physics 2021-09-17 Sébastien Becker , Emilie Devijver , Rémi Molinier , Noël Jakse

We study the nucleation of crystalline cluster phases in the generalized exponential model with exponent n=4. Due to the finite value of this pair potential for zero separation, at high densities the system forms cluster crystals with…

Soft Condensed Matter · Physics 2016-09-01 Christian Leitold , Christoph Dellago

During the processes of nucleation and growth of a precipitate cluster from a supersaturated solution, the diffusion flux between the cluster and the solution changes the solute concentration near the cluster-solution interface from its…

Chemical Physics · Physics 2016-06-08 Alexander Borisenko

The foundation for any discussion of first-order phse transitions is Classical Nucleation Theory(CNT). CNT, developed in the first half of the twentieth century, is based on a number of heuristically plausible assumtptions and the majority…

Chemical Physics · Physics 2018-11-14 James F. Lutsko