English
Related papers

Related papers: Fully selfconsistent GW calculations for molecules

200 papers

We present a new, all-electron implementation of the GW approximation and apply it to wurtzite ZnO. Eigenfunctions computed in the local-density approximation (LDA) by the full-potential linearized augmented-plane-wave (LAPW) or the…

Materials Science · Physics 2009-11-07 Manabu Usuda , Noriaki Hamada , Takao Kotani , Mark van Schilfgaarde

We present an energy-specific Bethe-Salpeter equation (BSE) implementation for efficient core and valence optical spectrum calculations. In energy-specific BSE, high-lying excitation energies are obtained by constructing trial vectors and…

Materials Science · Physics 2025-01-29 Christopher Hillenbrand , Jiachen Li , Tianyu Zhu

We present a machine learning (ML) framework that predicts $G_0W_0$ quasiparticle energies across molecular dynamics (MD) trajectories with high accuracy and efficiency. Using only DFT-derived mean-field eigenvalues and exchange-correlation…

Materials Science · Physics 2025-05-06 Ragab. A. Abdelghany , Chih-En Hsu , Hung-Chung Hsueh , Yuan-Hong Tsai , Ming-Chiang Chung

We present an extension of the quasiparticle self-consistent $GW$ approximation (QS$GW$) [Phys. Rev. B, 76 165106 (2007)] to include vertex corrections in the screened Coulomb interaction $W$. This is achieved by solving the Bethe-Salpeter…

Materials Science · Physics 2023-10-11 Brian Cunningham , Myrta Grüning , Dimitar Pashov , Mark van Schilfgaarde

The fully self-consistent GW approximation is an established method for electronic structure calculations. Its most serious deficiency is known to be an incorrect prediction of the dielectric response. In this work we examine the GW…

Strongly Correlated Electrons · Physics 2017-05-24 Kris Van Houcke , Igor S. Tupitsyn , Andrey S. Mishchenko , Nikolay V. Prokof'ev

We present a comprehensive investigation of electron capture (EC) ratios spanning a broad range of atomic numbers. The study employs a self-consistent computational method that incorporates electron screening, electron correlations, overlap…

Nuclear Theory · Physics 2023-07-26 V. A. Sevestrean , O. Niţescu , S. Ghinescu , S. Stoica

We apply the renormalized singles (RS) Green's function in the Bethe-Salpeter equation (BSE)/$GW$ approach to predict accurate neutral excitation energies of molecular systems. The BSE calculations are performed on top of the…

Chemical Physics · Physics 2022-10-26 Jiachen Li , Dorothea Golze , Weitao Yang

Gross-Oliveira-Kohn density-functional theory (GOK-DFT) for ensembles is the DFT analog of state-averaged wavefunction-based (SA-WF) methods. In GOK-DFT, the state-averaged (so-called ensemble) exchange-correlation (xc) energy is described…

Chemical Physics · Physics 2019-03-07 Killian Deur , Emmanuel Fromager

Despite of its huge successes in vast amount of applications, the Kohn-Sham scheme of density functional theory (DFT-Kohn-Sham) has not been able to get reliable ionization potentials (IP) for semiconductors, due to self-interaction error…

Materials Science · Physics 2016-04-07 Lin-Hui Ye

We present algorithmic and implementation details for the fully self-consistent finite-temperature $GW$ method in Gaussian Bloch orbitals for solids. Our implementation is based on the finite-temperature Green's function formalism in which…

Materials Science · Physics 2022-12-14 Chia-Nan Yeh , Sergei Iskakov , Dominika Zgid , Emanuel Gull

Upcoming gravitational wave (GW) detectors might detect a stochastic background of GWs potentially arising from many possible sources, including bubble collisions from a strongly first-order electroweak phase transition. We investigate…

High Energy Physics - Phenomenology · Physics 2014-11-20 John Kehayias , Stefano Profumo

We present an approach to calculate the optical absorption spectra that combines the quasiparticle self-consistent GW method [Phys. Rev. B, 76 165106 (2007)] for the electronic structure with the solution of the ladder approximation to the…

Materials Science · Physics 2018-03-21 Brian Cunningham , Pooya Azarhoosh , Dimitar Pashov , Myrta Gruening , Mark van Schilfgaarde

Gas phase C$_{70}$ molecules have been ionized with single photons of energies between 16 eV and 70 eV and the electron spectra measured with velocity map imaging in coincidence with the ions. The doubly ionized and unfragmented species was…

Within the framework of the full potential projector-augmented wave methodology, we present a promising low-scaling $GW$ implementation. It allows for quasiparticle calculations with a scaling that is cubic in the system size and linear in…

Materials Science · Physics 2016-10-12 Peitao Liu , Merzuk Kaltak , Jiří Klimeš , Georg Kresse

We present a protocol for computing core-ionisation energies for molecules, which is essential for reproducing X-Ray photoelectron spectroscopy experiments. The electronic structure of both the ground state and the core-ionised states are…

Chemical Physics · Physics 2025-04-18 Niklas Göllmann , Matthew R. Ludwig , Peter Wind , Laura Ratcliff , Luca Frediani

We present a nontrivial model system of interacting electrons that can be solved analytically in the GW approximation. We obtain the particle number from the GW Green's function strictly analytically, and prove that there is a genuine…

Materials Science · Physics 2008-02-03 Arno Schindlmayr

Experimental data for pion photoproduction including differential cross sections and various polarization observables from four reaction channels, $\gamma p \to \pi^0 p$, $\gamma p \to \pi^+n$, $\gamma n \to \pi^- p$ and $\gamma n \to \pi^0…

Molecule-metal interfaces have a broad range of applications in nanoscale materials science. Accurate characterization of their electronic structures from first-principles is key in understanding material and device properties. The GW…

Materials Science · Physics 2020-02-05 Zhenfei Liu

Parameter estimation (PE) for compact binary coalescence (CBC) events observed by gravitational wave (GW) laser interferometers is a core task in GW astrophysics. We present a method to compute the posterior distribution efficiently without…

General Relativity and Quantum Cosmology · Physics 2025-09-09 Jonathan Mushkin , Javier Roulet , Barak Zackay , Tejaswi Venumadhav , Oryna Ivashtenko , Digvijay Wadekar , Ajit Kumar Mehta , Matias Zaldarriaga

In this work we present a new method for basis set generation for electronic structure calculations of crystalline solids. This procedure is aimed at applications to Density Functional Theory (DFT). In this construction, Energy Window…

Materials Science · Physics 2025-07-16 Garry Goldstein