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Quantum simulation offers a route to study open-system molecular dynamics in non-perturbative regimes by programming the interactions among electronic, vibrational, and environmental degrees of freedom on similar energy scales. Trapped-ion…

The preceding paper describes a strategy for externally influencing the course of short-time electronic excitation transfer (EET) in molecular dimers and observing the process by nonlinear wave-packet interferometry (nl-WPI). Within a…

Quantum Physics · Physics 2015-05-14 Jason D. Biggs , Jeffrey A. Cina

We present a quantum framework based on a density matrix of a dimer system to investigate the quantum dynamics of excitation energy transfer (EET) in the presence of the evanescent field from the metal and the phonon bath. Due to the…

Quantum Physics · Physics 2017-08-02 Amrit Poudel , Xin Chen , Mark A. Ratner

Photo-induced excited-state energy transfer (EET) processes play an important role in the solar energy conversions. The phenylene ethynylene (PE) dendrimers display great potential in improving the efficiency of solar cells, because of…

Chemical Physics · Physics 2024-01-17 Sisi Liu , Jiawei Peng , Peng Bao , Qiang Shi , Zhenggang Lan

Semiclassical electrodynamics is an appealing approach for studying light-matter interactions, especially for realistic molecular systems. However, there is no unique semiclassical scheme. On the one hand, intermolecular interactions can be…

Chemical Physics · Physics 2019-12-16 Tao E. Li , Hsing-Ta Chen , Abraham Nitzan , Joseph E. Subotnik

We explore the behavior in time of the energy exchange between a system of interest and its environment, together with its relationship to the non-Markovianity of the system dynamics. In order to evaluate the energy exchange we rely on the…

Quantum Physics · Physics 2016-01-26 Giacomo Guarnieri , Chikako Uchiyama , Bassano Vacchini

The theoretical and experimental study of energy transfer in photosynthesis has revealed an interesting transport regime, which lies at the borderline between classical transport dynamics and quantum-mechanical interference effects.…

Biological Physics · Physics 2014-02-13 Tobias Kramer , Christoph Kreisbeck

Non-Markovian effects in the evolution of open quantum systems have recently attracted widespread interest, particularly in the context of assessing the efficiency of energy and charge transfer in nanoscale biomolecular networks and quantum…

Chemical Physics · Physics 2016-02-10 S. Oviedo-Casado , J. Prior , A. W. Chin , R. Rosenbach , S. F. Huelga , M. B. Plenio

We study the evolution of quantum entanglement during exciton energy transfer (EET) in a network model of the Fenna-Matthews-Olson (FMO) complex, a biological pigment-protein complex involved in the early steps of photosynthesis in sulphur…

Quantum Physics · Physics 2010-06-29 Filippo Caruso , Alex W. Chin , Animesh Datta , Susana F. Huelga , Martin B. Plenio

We show that the use of a recently proposed iterative collision model with inter-environment swaps displays a signature of strongly non-Markovian dynamics that is highly dependent on the establishment of system-environment correlations. Two…

Quantum Physics · Physics 2014-05-27 Ruari McCloskey , Mauro Paternostro

We consider the dynamics of a collisional model in which both the system and environment are embodied by spin-$1/2$ particles. In order to include non-Markovian features in our model we introduce interactions among the environmental qubits…

Quantum Physics · Physics 2017-08-15 B. Çakmak , M. Pezzutto , M. Paternostro , Ö. E. Müstecaplıoğlu

We analyze the role of coherent, non-perturbative system-bath interactions in a photosynthetic heat engine. Using the reaction-coordinate formalism to describe the vibrational phonon-environment in the engine, we analyze the efficiency…

Chemical Physics · Physics 2018-09-19 Melina Wertnik , Alex Chin , Franco Nori , Neill Lambert

We show that non-Markovian effects of the reservoirs can be used as a resource to extract work from an Otto cycle. The state transformation under non-Markovian dynamics is achieved via a two-step process, namely an isothermal process using…

Quantum Physics · Physics 2018-06-07 George Thomas , Nana Siddharth , Subhashish Banerjee , Sibasish Ghosh

We study the Markovian process of a multi-mode open system connecting with a non-equilibrium environment, which consists of several heat baths with different temperatures. As an illustration, we study the steady state of three linearly…

Quantum Physics · Physics 2014-03-12 Sheng-Wen Li , Li-Ping Yang , C. P. Sun

The simulation of non-Markovian quantum dynamics plays an important role in the understanding of charge and exciton dynamics in the condensed phase environment, and yet it remains computationally expensive on classical computers. We have…

Quantum Physics · Physics 2024-12-03 Peter L. Walters , Mohammad U. Sherazi , Fei Wang

Dissipative phase transitions in quantum systems have been largely studied under the so-called Markovian approximation, where the environments to which the systems are coupled are memoryless. Here, we present a generalization of the…

Quantum Physics · Physics 2024-10-28 Baptiste Debecker , John Martin , François Damanet

Strong coupling between molecular excitations and quantized electromagnetic fields in optical cavities provides a powerful means to control the physical and chemical properties of molecular systems. Here, we study electron transfer (ET)…

Chemical Physics · Physics 2026-03-02 Takumi Hidaka , Tomohiro Fukushima , Nguyen Thanh Phuc

The developing field of stochastic thermodynamics extends concepts of macroscopic thermodynamics such as entropy production and work to the microscopic level of individual trajectories taken by a system through phase space. The scheme…

Statistical Mechanics · Physics 2022-06-30 Cillian Cockrell , Ian J Ford

Excited-state intramolecular proton transfer (ESIPT) is a fundamental photochemical process in which photoexcitation induces proton transfer within a molecule, leading to the formation of a tautomeric excited state. It was observed…

Chemical Physics · Physics 2026-03-03 Alessandro Nicola Nardi , Morgane Vacher

We investigate the smallest set of requirements for inducing non-Markovian dynamics in a collisional model of open quantum systems. This is done by introducing correlations in the state of the environment and analyzing the divisibility of…

Quantum Physics · Physics 2014-09-24 N. K. Bernardes , A. R. R. Carvalho , C. H. Monken , M. F. Santos
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