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We develop a detailed theoretical model of photo-induced proton-coupled electron transfer (PPCET) processes, which are at the basis of solar energy harvesting in biological systems and photovoltaic materials. Our model enables to analyze…

Chemical Physics · Physics 2021-04-13 Jiaji Zhang , Raffaele Borrelli , Yoshitaka Tanimura

We provide physically intuitive mechanisms for the effect of noise on excitation energy transfer (EET) in networks. Using these mechanisms of dephasing-assisted transport (DAT) in a hybrid basis of both excitons and sites, we develop a…

Quantum Physics · Physics 2015-05-14 Alex W. Chin , Animesh Datta , Filippo Caruso , Susana F. Huelga , Martin B. Plenio

Excitation energy transfer (EET) in an organic/inorganic nanohybrid system, composed of a single \textit{para}-sexiphenyl (6P) molecule physisorbed on a finite-sized MoS$_2$ nanoflake, is investigated theoretically. % The electronic…

Mesoscale and Nanoscale Physics · Physics 2026-01-22 Yan Meng , Kainan Chang , Luxia Wang

Constructing models to discover physics underlying magnanimous data is a traditional strategy in data mining which has been proved to be powerful and successful. In this work, a multi-optimized recurrent neural network (MRNN) is utilized to…

Applied Physics · Physics 2024-12-31 Shun-Cai Zhao , Yi-Meng Huang , Zi-Ran Zhao

The non-Markovianity of the electron transfer in an oligothiophene-fullerene heterojunction described by a spin-boson model is analyzed using the time dependent decoherence canonical rates and the volume of accessible states in the Bloch…

Chemical Physics · Physics 2017-09-13 Etienne Mangaud , Christoph Meier , Michèle Desouter-Lecomte

In this paper, we study the role of collective vibrational motion in the phenomenon of electronic energy transfer (EET) along a chain of coupled electronic dipoles with varying excitation frequencies. Previous experimental work on EET in…

Quantum Physics · Physics 2015-03-13 F. L. Semião , K. Furuya , G. J. Milburn

Electron Transfer (ET) reactions are modeled by the dynamics of a quantum two-level system (representing the electronic state) coupled to a thermalized bath of classical harmonic oscillators (representing the nuclei degrees of freedom).…

Chemical Physics · Physics 2014-11-24 Serge Aubry

A master equation, derived from the non-Markovian quantum state diffusion (NMQSD), is used to calculate excitation energy transfer in the photosynthetic Fenna-Matthews-Olson (FMO) pigment-protein complex at various temperatures. This…

Quantum Physics · Physics 2012-02-07 G. Ritschel , J. Roden , W. T. Strunz , A. Eisfeld

We consider a microscopic collision model, i.e., a quantum system interacts with a hierarchical environment consisting of an auxiliary system and a reservoir. We show how the non-Markovian character of the system is influenced by the…

Quantum Physics · Physics 2020-10-27 Yong-Wei Li , Lei Li

Using large-scale, real-time quantum dynamics calculations, we present a detailed analysis of electronic excitation transfer (EET) mechanisms in a multi-particle plasmonic nanoantenna system. Specifically, we utilize real-time,…

Mesoscale and Nanoscale Physics · Physics 2018-03-06 Niranjan V. Ilawe , M. Belén Oviedo , Bryan M. Wong

We theoretically analyze the excitation energy transfer between two closely spaced linear molecular J-aggregates, whose excited states are Frenkel excitons. The aggregate with the higher (lower) exciton band edge energy is considered as the…

Disordered Systems and Neural Networks · Physics 2007-05-23 C. Didraga , V. A. Malyshev , J. Knoester

A direct numerical algorithm for solving the time-nonlocal non-Markovian master equation in the second Born approximation is introduced and the range of utility of this approximation, and of the Markov approximation, is analyzed for the…

Chemical Physics · Physics 2011-06-30 Navinder Singh , Paul Brumer

We study qubit-mediated energy transfer between two electron reservoirs by adopting a numerically-exact influence functional path-integral method. This non-perturbative technique allows us to study the system's dynamics beyond the weak…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 D. Segal

We simulate the long-range inter-complex electronic energy transfer in Photosystem II -- from the antenna complex, via a core complex, to the reaction center -- using a non-Markovian (ZOFE) quantum master equation description that allows us…

Chemical Physics · Physics 2016-07-27 Jan J. J. Roden , Doran I. G. Bennett , K. Birgitta Whaley

Outer sphere electron transfer rates can be calculated from simulation data by sampling the equilibrium statistics of the canonical reaction coordinate -- the vertical energy gap. For these calculations, electron transfer is typically…

Chemical Physics · Physics 2025-09-23 Yoonjae Park , Adam P. Willard

The high energy transfer efficiency of photosynthetic complexes has been a topic of research across many disciplines. Several attempts have been made in order to explain this energy transfer enhancement in terms of quantum mechanical…

Quantum Physics · Physics 2022-09-02 Ali Pedram , Barış Çakmak , Özgür E. Müstecaplıoğlu

Intramolecular energy transfer driven by near-field effects plays an important role in applications ranging from biophysics and chemistry to nano-optics and quantum communications. Advances in strong light-matter coupling in molecular…

Mesoscale and Nanoscale Physics · Physics 2025-07-14 Kristin B. Arnardottir , Piper Fowler-Wright , Christos Tserkezis , Brendon W. Lovett , Jonathan Keeling

Rate processes with dynamical disorder are investigated within a simple framework provided by unidirectional electron transfer (ET) with fluctuating transfer rate. The rate fluctuations are assumed to be described by a non-Markovian…

Statistical Mechanics · Physics 2007-05-23 Igor Goychuk

We derive a many-site version of the non-Markovian time-convolutionless polaron master equation [S. Jang et al., J. Chem Phys. 129, 101104 (2008)] to describe electronic excitation dynamics in multichromophoric systems. By treating…

Quantum Physics · Physics 2015-05-28 Avinash Kolli , Ahsan Nazir , Alexandra Olaya-Castro

We discuss a failure of the wide-spread method of images solution to describe the time evolution of probability distribution in diffusive processes with memory. For a path that touches a target during stochastic evolution, we define its…

Statistical Mechanics · Physics 2025-12-02 Takuya Saito , Yuta Sakamoto , Takahiro Sakaue