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We present a formulation of excited state mean-field theory in which the derivatives with respect to the wave function parameters needed for wave function optimization (not to be confused with nuclear derivatives) are expressed analytically…

Chemical Physics · Physics 2020-06-24 Luning Zhao , Eric Neuscamman

We present a novel joint time-dependent density-functional theory for the description of solute-solvent systems in time-dependent external potentials. Starting with the exact quantum-mechanical action functional for both electrons and…

Materials Science · Physics 2012-02-16 Johannes Lischner , T. A. Arias

We present a kinetic-energy density-functional theory and the corresponding kinetic-energy Kohn-Sham (keKS) scheme on a lattice and show that by including more observables explicitly in a density-functional approach already simple…

Chemical Physics · Physics 2018-07-23 Iris Theophilou , Florian Buchholz , F. G. Eich , Michael Ruggenthaler , Angel Rubio

We consider a lattice model in which phonons scatter with pairs of electrons. All eigenvalues and eigenvectors can be obtained analytically. For a suitable choice of parameters the ground state consists of a Fermi sea of non-interacting…

Strongly Correlated Electrons · Physics 2010-01-20 Jan Naudts , Tobias Verhulst

Consider the focusing 4D cubic wave equation \[ \partial_{tt}u-\Delta u-u^{3}=0,\quad \mbox{on}\ (t,x)\in [0,\infty)\times \mathbb{R}^{4}.\] The main result states the existence in energy space $\dot{H}^{1}\times L^{2}$ of multi-solitary…

Analysis of PDEs · Mathematics 2021-03-10 Xu Yuan

It has been previously proven that the Kohn-Sham kinetic energy functional scales homogeneusly under generalized coordinate scaling, in a way that is obeyed by the von Weiz\"acker functional, but seems to be in contradiction with the…

Quantum Physics · Physics 2014-10-16 Lázaro Calderín

Measurements and a theoretical interpretation of the excitation spectrum of a two-electron quantum dot fabricated on a parabolic Ga[Al]As quantum well are reported. Experimentally, excited states are found beyond the well-known lowest…

Mesoscale and Nanoscale Physics · Physics 2021-12-30 T. Ihn , C. Ellenberger , K. Ensslin , Constantine Yannouleas , Uzi Landman , D. C. Driscoll , A. C. Gossard

We present an alternative to the Kohn-Sham formulation of density functional theory for the ground-state properties of strongly interacting electronic systems. The idea is to start from the limit of zero kinetic energy and systematically…

Strongly Correlated Electrons · Physics 2015-05-13 Paola Gori-Giorgi , Michael Seidl , G. Vignale

Many recent applications of time-dependent density functional theory begin in an initially excited state, and propagate it using an adiabatic approximation for the exchange-correlation potential. This however inserts the excited-state…

Chemical Physics · Physics 2012-04-02 Peter Elliott , Neepa T. Maitra

The partition function for the random walk of an electrostatic field produced by several static parallel infinite charged planes in which the charge distribution could be either $\pm\sigma$ is obtained. We find the electrostatic energy of…

Statistical Mechanics · Physics 2016-08-09 Gabriel Gonzalez

We introduce excited binomial states and excited negative binomial states of the radiation field by repeated application of the photon creation operator on binomial states and negative binomial states. They reduce to Fock states and excited…

Quantum Physics · Physics 2008-11-26 Xiao-Guang Wang , Hong-Chen Fu

A recent work [arXiv:2401.04685] has merged $N$-centered ensembles of neutral and charged electronic ground states with ensembles of neutral ground and excited states, thus providing a general and in-principle exact (so-called extended…

Strongly Correlated Electrons · Physics 2024-05-14 Filip Cernatic , Emmanuel Fromager

We present a modification of the $\Delta$SCF method of calculating energies of excited states, in order to make it applicable to resonance calculations of molecules adsorbed on metal surfaces, where the molecular orbitals are highly…

Materials Science · Physics 2009-03-06 Jeppe Gavnholt , Thomas Olsen , Mads Engelund , Jakob Schiøtz

We investigate the excited stationary states of Bose-Einstein condensates trapped in harmonic potentials. We derive simple analytical approximations of the first few eigenstates of the associated time-independent one-dimensional…

Condensed Matter · Physics 2007-05-23 John A. Vaccaro , Ole Steuernagel , Ben Lorimer

We present an extensive numerical study of the Sherrington-Kirkpatrick model in transverse field. Recent numerical studies of quantum spin-glasses have focused on exact diagonalization of the full Hamiltonian for small systems ($\approx$ 20…

Disordered Systems and Neural Networks · Physics 2016-04-06 Yang Wei Koh

Orbital-optimized density functional theory (DFT) has emerged as an alternative to time-dependent (TD) DFT capable of describing difficult excited states with significant electron density redistribution, such as charge-transfer, Rydberg,…

Chemical Physics · Physics 2025-01-22 Hanh D. M. Pham , Rustam Z. Khaliullin

We explore the possibility of calculating electronic excited states by using perturbation theory along a range-separated adiabatic connection. Starting from the energies of a partially interacting Hamiltonian, a first-order correction is…

Chemical Physics · Physics 2014-12-15 Elisa Rebolini , Julien Toulouse , Andrew M. Teale , Trygve Helgaker , Andreas Savin

It is known that ensembles of interacting oscillators or qubits can exhibit the phenomenon of quantum synchronization. In this work we consider a set of $N$ identical two-state systems that we call ``harmonic qubits'', because the kinetic…

General Physics · Physics 2025-09-18 L. Gamberale , G. Modanese

The $\Delta$SCF DFT approach defines the system energy as a function of orbital occupancy. Inspired by Landau Fermi liquid theory, we develop an occupancy extrapolation (OE) method that captures excited-state energies via a Taylor expansion…

Chemical Physics · Physics 2026-03-30 Yichen Fan , Weitao Yang

A doubled q-Fock space is constructed by introducing an idle mode system dual to the physical one under consideration. The quantum entanglements of photons in the squeezed states and thermal states based on the doubled q-Fock space are…

Quantum Physics · Physics 2009-11-07 He-Shan Song , Dong Mi , Ling Zhou , Chong Li