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We propose and analyze a scheme for realizing the quantum reflection of single photons in a cold Rydberg atomic gas via electromagnetically induced transparency, by which a deep and tunable attractive potential well can be prepared by using…

Quantum Physics · Physics 2022-09-07 Yao Ou , Qi Zhang , Guoxiang Huang

Quantum information processing with neutral atoms relies on Rydberg excitation for entanglement generation. While the use of heavy divalent or open-shell elements, such as strontium or ytterbium, has benefits due to their optically active…

Within a dense environment ($\rho \approx 10^{14}\,$atoms/cm$^3$) at ultracold temperatures ($T < 1\,\mu{}\text{K}$), a single atom excited to a Rydberg state acts as a reaction center for surrounding neutral atoms. At these temperatures…

Atoms excited into high-lying Rydberg states and under strong dipole-dipole interactions exhibit phenomena associated with highly correlated and complex systems. We perform first principles numerical simulations on the dynamics of such…

We explore the electronic structure of ultralong-range pentaatomic Rydberg molecules from a merger of a Rydberg atom and two ground state heteronuclear diatomic molecules. Our focus is on the interaction of Rb($23s$) and Rb($n=20$, $l\ge…

We investigate the quantum dynamics of ultra-long-range trilobite molecules exposed to homogeneous electric fields. A trilobite molecule consists of a Rydberg atom and a ground-state atom, which is trapped at large internuclear distances in…

Atomic Physics · Physics 2021-02-24 Frederic Hummel , Kevin Keiler , Peter Schmelcher

H$_3^{2+}$ is a one-electron system with three positive nuclei and is known to be unstable in its electronic ground-state. We examine an analogous one-electron system composed of a $^{87}$Rb Rydberg atom interacting with a pair of cations…

Atomic Physics · Physics 2024-06-03 Daniel J. Bosworth , Matthew T. Eiles , Peter Schmelcher

We study long range interactions between two Rydberg atoms and predict the existence of ultralong range Rydberg dimers with equilibrium distances of many thousand Bohr radii. We calculate the dispersion coefficients $C_{5}$, $C_{6}$ and…

Atomic Physics · Physics 2009-11-07 Christophe Boisseau , Ionel Simbotin , Robin Cote

We consider ultralong-range polyatomic Rydberg molecules formed by combining a Rydberg cesium atom and a ground-state RbCs molecule. We explore the regime where the charge-dipole interaction due to the Rydberg electron with the diatomic…

Thin metallic films have a 1D quantum well along the surface normal direction, which yields particle-in-a-box style electronic quantum states. However the quantum well is not infinitely deep and the wavefunctions of these states penetrate…

Chemical Physics · Physics 2016-06-29 Jemma A Gibbard , Timothy P Softley

We probe resonant dipolar interactions between ultracold $^{40}$K$^{87}$Rb molecules and Rydberg $^{87}$Rb atoms in an optically trapped ensemble. Through state-selective ionization detection of the KRb molecules, we observe resonant energy…

Atomic Physics · Physics 2025-04-10 Lingbang Zhu , Jeshurun Luke , Roy Shaham , Yi-Xiang Liu , Kang-Kuen Ni

Neutral atoms excited to Rydberg states can interact with each other via dipole-dipole interaction, which results in a physical phenomenon named Rydberg blockade mechanism. The effect attracts much attention due to its potential…

Quantum Physics · Physics 2015-06-12 Huaizhi Wu , Zhen-Biao Yang , Li-Tuo Shen , Shi-Biao Zheng

We predict the existence of a class of ultracold giant molecules formed from trapped ultracold Rydberg atoms and polar molecules. The interaction which leads to the formation of such molecules is the anisotropic charge-dipole interaction…

Atomic Physics · Physics 2015-05-18 Seth T. Rittenhouse , H. R. Sadeghpour

Interaction between Rydberg atoms can significantly modify Rydberg excitation dynamics. Under a resonant driving field the Rydberg-Rydberg interaction in high-lying states can induce shifts in the atomic resonance such that a secondary…

We propose an implementation of a universal quantum gate between pairs of spatially separated atoms in a microwave cavity at finite temperature. The gate results from reversible laser excitation of Rydberg states of atoms interacting with…

Quantum Physics · Physics 2015-09-24 Lőrinc Sárkány , József Fortágh , David Petrosyan

We predict the existence of a universal class of ultralong-range Rydberg molecular states whose vibrational spectra form trimmed Rydberg series. A dressed ion-pair model captures the physical origin of these exotic molecules, accurately…

Quantum Physics · Physics 2020-09-23 P. Giannakeas , Matthew T. Eiles , F. Robicheaux , Jan-Michael Rost

The theory is developed for one and two atom interactions when the atom has a Rydberg electron attached to a hyperfine split core state. This situation is relevant for some of the rare earth and alkaline earth atoms that have been proposed…

Atomic Physics · Physics 2018-02-21 F. Robicheaux , D. W. Booth , M. Saffman

We consider the classical map proposed previously to be the exact classical analogue of Rydberg Molecules calculated with the approximations relevant to the multi-channel quantum defect theory. The resulting classical map is analyzed at…

Chaotic Dynamics · Physics 2009-10-31 F. Leyvraz , M. Lombardi , T. H. Seligman

It is common knowledge that atoms can form molecules if they attract each other. Here, we show that it is possible to create molecules where bound states of the atoms are not the result of attractive interactions but have the topological…

Quantum Physics · Physics 2022-09-05 Ali Emami Kopaei , Xuedong Tian , Krzysztof Giergiel , Krzysztof Sacha

The identification of tipping points is essential for prediction of collapses or other sudden changes in complex systems. Applications include studies of ecology, thermodynamics, climatology, and epidemiology. However, detecting early signs…