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We study the excitation dynamics of Rydberg atoms in a one-dimensional lattice with periodic boundary conditions where the atomic Rydberg states are resonantly excited from the electronic ground state. Our description of the corresponding…

Quantum Physics · Physics 2015-05-13 B. Olmos , R. González-Férez , I. Lesanovsky

We observe long-range $^{85}$Rb and $^{87}$Rb (24$D$+5$S_{1/2}$) Rydberg molecules for eight different spin couplings, with binding energies up to 440~MHz and sub-percent relative uncertainty. Isotopic effects of the molecular binding…

Atomic Physics · Physics 2020-01-15 Jamie L. MacLennan , Yun-Jhih Chen , Georg Raithel

The ability to generate and control strong long-range interactions via highly excited electronic states has been the foundation for recent breakthroughs in a host of areas, from atomic and molecular physics [1, 2] to quantum optics [3, 4]…

Mesoscale and Nanoscale Physics · Physics 2021-07-14 Julian Heckötter , Valentin Walther , Stefan Scheel , Manfred Bayer , Thomas Pohl , Marc Aßmann

We study the long-range interaction of a single ion with a highly excited ultracold Rydberg atom and report on the direct observation of ion-induced Rydberg excitation blockade mediated over tens of micrometer distances. Our hybrid ion-atom…

Atoms with a highly excited electron, called Rydberg atoms, can form unusual types of molecular bonds. The bond differs from the well known ionic and covalent bonds not only by its binding mechanism, but also by its bond length ranging up…

Atomic Physics · Physics 2022-05-20 N. Zuber , V. S. V. Anasuri , M. Berngruber , Y. -Q. Zou , F. Meinert , R. Löw , T. Pfau

Rydberg atoms are currently a very fast advancing quantum platform. For many interesting and demanding applications, including quantum computation, fast detection of a Rydberg excitation or a Rydberg qubit for information readout would be…

Quantum Physics · Physics 2025-09-30 Jinjin Du , Thibault Vogt , Ningxuan Zheng , Wenhui Li

We consider non-adiabatic coupling in the "trilobite"-like long-range Rydberg molecules created by perturbing degenerate high-$\ell$ Rydberg states with a ground-state atom. Due to the flexibility granted by the high Rydberg level density,…

Atomic Physics · Physics 2024-03-13 Matthew T. Eiles , Frederic Hummel

We present photo-excitation of ultra-long-range Rydberg molecules as a probe of spatial correlations in quantum gases. Rydberg molecules can be created with well-defined internuclear spacing, set by the radius of the outer lobe of the…

We observe that when an ultracold ground state cesium (Cs) atom becomes bound within the electronic cloud of an extended Cs electronic orbit, ultralong-range molecules with giant (kilo-Debye) permanent electric dipole moments form. Large…

Atomic Physics · Physics 2015-06-23 Donald Booth , Seth Rittenhouse , Jin Yang , Hossein Sadeghpour , James Shaffer

Networks of Rydberg atoms provide a powerful basis for quantum simulators and quantum technologies. Inspired by matter-wave atomtronics, here we engineer switches, diodes and universal logic gates. Our schemes control the Rydberg excitation…

Quantum Physics · Physics 2025-05-26 Philip Kitson , Tobias Haug , Antonino La Magna , Oliver Morsch , Luigi Amico

We investigate the non-adiabatic quantum dynamics of ultralong-range Rydberg molecules using a vibronically coupled two-channel treatment. The two channels are composed of coupled trilobite and butterfly electronic states, formed as a…

Atomic Physics · Physics 2026-03-17 Felix Giering , Rohan Srikumar , Peter Schmelcher

We report on a novel method for photo-association of strongly polar trilobite Rydberg molecules. This exotic ultralong-range dimer, consisting of a ground-state atom bound to the Rydberg electron via electron-neutral scattering, inherits…

Ultralong-range Rydberg molecules provide an exciting testbed for molecular physics at exaggerated scales. In the so-called trilobite and butterfly Rydberg molecules, the Born-Oppenheimer approximation can fail due to strong non-adiabatic…

Atomic Physics · Physics 2023-02-23 Frederic Hummel , Peter Schmelcher , Matthew T. Eiles

We investigate the electronic structure of a triatomic Rydberg molecule formed by a Rydberg atom and two neutral ground-state atoms. Taking into account the $s$-wave and $p$-wave interactions we perform electronic structure calculations and…

Atomic Physics · Physics 2016-06-22 Javier Aguilera Fernández , Peter Schmelcher , Rosario González-Férez

Out-of-equilibrium, strong correlation in a many-body system triggers emergent properties that can act in important ways to constrain the natural dissipation of energy and matter. Networks of atoms, intricately engineered to arrange…

We observe "trilobite-like" states of ultracold 85Rb2 molecules, in which a ground-state atom is bound by the electronic wavefunction of its Rydberg-atom partner. We populate these states through the ultraviolet excitation of weakly-bound…

Atomic Physics · Physics 2015-06-15 M. A. Bellos , R. Carollo , J. Banerjee , E. E. Eyler , P. L. Gould , W. C. Stwalley

When ultracold plasma is generated using photonization of laser cooled atoms, some atoms reach only upto Rydberg states. These in turn interact with the free electrons of the plasma and get ionized further. We study the interaction of…

Atomic Physics · Physics 2026-03-18 Satyam Prakash , Ashok S Vudayagiri

We observe the formation of long-range Cs$_2$ Rydberg molecules consisting of a Rydberg and a ground-state atom by photoassociation spectroscopy in an ultracold Cs gas near 6s$_{1/2}$($F$=3,4)$\rightarrow$np$_{3/2}$ resonances (n=26-34).…

Atomic Physics · Physics 2015-06-23 Heiner Saßmannshausen , Frédéric Merkt , Johannes Deiglmayr

Trilobites are exotic giant dimers with enormous dipole moments. They consist of a Rydberg atom and a distant ground-state atom bound together by short-range electron-neutral attraction. We show that highly polar, polyatomic trilobite…

Atomic Physics · Physics 2017-11-22 Perttu J. J. Luukko , Jan-Michael Rost

We have studied the behavior of cold Rydberg atoms embedded in an ultracold plasma. We demonstrate that even deeply bound Rydberg atoms are completely ionized in such an environment, due to electron collisions. Using a fast pulse extraction…

Quantum Physics · Physics 2009-11-10 Nicolas Vanhaecke , Daniel Comparat , Duncan A. Tate , Pierre Pillet