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We have measured and analyzed the dielectric constant of the dimer Mott insulator $\kappa-$(BEDT-TTF)$_2$Cu$_2$(CN)$_3$, which is known as a playground for a spin-liquid state. Most unexpectedly, this particular organic salt has nontrivial…

Strongly Correlated Electrons · Physics 2015-05-18 Majed Abdel-Jawad , Ichiro Terasaki , Takahiko Sasaki , Naoki Yoneyama , Norio Kobayashi , Yoshiaki Uesu , Chisa Hotta

The static and dynamic local spin susceptibility of the organic Mott insulator $\kappa$-(ET)$_2$Cu$_2$(CN)$_3$, a model material of the spin- 1/2 triangular lattice, is studied by $^{13}$C NMR spectroscopy from room temperature down to 20…

Strongly Correlated Electrons · Physics 2007-05-23 Yasuhiro Shimizu , Kazuya Miyagawa , Kazushi Kanoda , Maesato Mitsuhiko , Gunzi Saito

Mott insulators are commonly pictured with electrons localized on lattice sites. Their low-energy degrees of freedom involve spins only. Here we observe emerging charge degrees of freedom in a molecule-based Mott insulator…

Quantum entanglement effects between the electronic spin and charge degrees of freedom are examined in an organic molecular solid, termed a dimer-Mott insulating system, in which molecular dimers are arranged in a crystal as fundamental…

Strongly Correlated Electrons · Physics 2016-05-18 Makoto Naka , Sumio Ishihara

Quantum spin liquid states, in which spins are quantum-mechanically delocalized in direction, have been so far studied for charge-localized Mott insulators arising from strong repulsive interaction. Recently, however, it was found that the…

Strongly Correlated Electrons · Physics 2022-02-15 Hiroshi Oike , Kazuya Miyagawa , Hiromi Taniguchi , Hiroyuki Okamoto , Kazushi Kanoda

The Mott insulator \kappa-(BEDT-TTF)2Cu[N(CN)2]Cl consists of molecular dimers arranged on an anisotropic triangular lattice and develops a canted antiferromagnetic ground state. It has recently been suggested that this system features…

$^{1}$H NMR and static susceptibility measurements have been performed in an organic Mott insulator with nearly isotropic triangular lattice, $\kappa$-(BEDT-TTF)$_{2}$Cu$_{2}$(CN)$_{3}$, which is a model system of frustrated quantum spins.…

Strongly Correlated Electrons · Physics 2009-11-10 Y. Shimizu , K. Miyagawa , K. Kanoda , M. Maesato , G. Saito

We show that the anisotropy of the effective spin model for the dimer Mott insulator phase of $\kappa$-(BEDT-TTF)$_2X$ salts is dramatically different from that of the underlying tight-binding model. Intra-dimer quantum interference results…

Strongly Correlated Electrons · Physics 2018-07-11 B. J. Powell , E. P. Kenny , J. Merino

The spin dynamics of electron doped Mott insulators on a triangular lattice is studied based on the $t-J$ model. It is found that the particularly universal behaviors of integrated dynamical spin structure factor seen in the doped Mott…

Strongly Correlated Electrons · Physics 2015-06-12 Bin Liu , Ying Liang

The Mott insulator $\kappa$-(BEDT-TTF)$_2$Ag$_2$(CN)$_3$ forms a highly-frustrated triangular lattice of $S=1/2$ dimers with a possible quantum-spin-liquid state. Our experimental and numerical studies reveal the emergence of a slight…

The effects of pressure on a quantum spin liquid are investigated in an organic Mott insulator $\kappa$-(ET)$_2$Ag$_2$(CN)$_3$ with a spin-1/2 triangular lattice. The application of negative chemical pressure to…

At strong repulsion, the triangular-lattice Hubbard model is described by $s=1/2$ spins with nearest-neighbor antiferromagnetic Heisenberg interactions and exhibits conventional 120$^\circ$ order. Using the infinite density matrix…

Strongly Correlated Electrons · Physics 2021-09-07 Tessa Cookmeyer , Johannes Motruk , Joel E. Moore

In quantum magnetism spin dimers are typically associated with spin-singlet states. To date, $triplet$ $dimerization$ has not been observed in any 3D or quasi-2D material. With this in mind we here discuss the electronic structure of the…

We study the phase diagram of a one-dimensional extended Hubbard model with antiferromagnetic exchange interaction analytically and numerically. The bosonization and transfer-matrix renormalization group methods are used in the…

Strongly Correlated Electrons · Physics 2009-11-10 Jianhui Dai , Xiaoyong Feng , Tao Xiang , Yue Yu

Triangular lattice quasi-two-dimensional Mott insulators based on BEDT-TTF molecule and its analogies present a possibility to produce exotic phases by coupling charge and spin degrees of freedom. In this work we discuss magnetic properties…

The weak Mott insulating regime of the triangular lattice Hubbard model exhibits a rich magnetic phase diagram as a result of the ring exchange interaction in the spin Hamiltonian. These phases include the Kalmeyer-Laughlin type chiral spin…

Strongly Correlated Electrons · Physics 2025-12-23 Asimpunya Mitra , Daniel J. Schultz , Yong Baek Kim

A family of molecular Mott insulators on triangular lattice provided a few S=1/2 triangular quantum spin liquid candidates, with $\kappa$-(BEDT-TTF)$_2$Cu$_2$(CN)$_3$ being the most studied material of this group. The large number…

Strongly Correlated Electrons · Physics 2024-10-08 Jesse Liebman , Kazuya Miyagawa , Kazushi Kanoda , Natalia Drichko

In Mott insulators with a half-filled $t_{2g}$ shell the Hund's rule coupling induces a spin-3/2 orbital-singlet ground state. The spin-orbit interaction is not expected to qualitatively impact low-energy degrees of freedom in such systems.…

Strongly Correlated Electrons · Physics 2023-08-28 Leonid V. Pourovskii

The study of non-s-wave unconventional superconductivities in strongly correlated-electron systems has been a central issue in condensed matter physics for more than 30 years. In such unconventional superconductivities, d-wave Cooper…

Superconductivity · Physics 2022-06-14 Y. Saitou , N. Ichikawa , R. Yamamoto , D. Kitamata , M. Suzuki , Y. Yanagita , T. Namaizawa , S. Komuro , T. Furukawa , R. Kato , T. Itou

We study the problem of designing an artificial Mott insulator in a correlated oxide heterostructure. We consider the extreme limit of quantum confinement based on ionic discontinuity doping, and argue that a unique dimer Mott insulator can…

Strongly Correlated Electrons · Physics 2013-04-30 Ru Chen , SungBin Lee , Leon Balents
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