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We report a Raman study of the effect of temperature on the self-energies of optical phonons in a number of transition metals with hexagonal-close-packed structure. Anisotropic softening of phonon energies and narrowing of phonon linewidths…

Materials Science · Physics 2017-01-04 Yu. S. Ponosov , S. V. Streltsov

We report an investigation of perovskite-type LaNiO3 thin films by Raman scattering in both various scattering configurations and as a function of temperature. The room-temperature Raman spectra and the associated phonon mode assignment…

Materials Science · Physics 2010-07-30 N. Chaban , M. Weber , S. Pignard , J. Kreisel

Electronic Raman scattering and optical phonon self-energies are studied on single crystals of $LuB_{12}$ with different isotopic composition in the temperature region 10-650K and at pressures up to 10 GPa. The shape and energy position of…

Materials Science · Physics 2016-08-09 Yu. S. Ponosov , A. A. Makhnev , S. V. Streltsov , V. B. Filipov , N. Yu. Shitsevalova

Surface enhanced Raman spectra from molecules (bipyridyl ethylene) adsorbed on gold dumbells are observed to become increasingly asymmetric (Fano-like) at higher incident light intensity. The electronic temperature (inferred from the…

Mesoscale and Nanoscale Physics · Physics 2016-01-12 S. Dey , M. Banik , E. Hulkko , K. Rodriguez , V. A. Apkarian , M. Galperin , A. Nitzan

A comparative analysis of two Raman line-shape functions has been carried out to validate the true representation of experimentally observed Raman scattering data for semiconducting nanomaterials. A modified form of already existing phonon…

Temperature dependence of Fano resonance, recently discovered in infra-red (IR spectra of nanodiamonds synthesized from chloroadamantane at high static pressures, is investigated. For the first time, marked variations of the resonance…

Mesoscale and Nanoscale Physics · Physics 2022-08-10 A. A. Shiryaev , E. A. Ekimov , V. Yu. Prokof'ev , M. V. Kondrin

The effect of pressure and temperature on the Raman-active phonon mode of osmium metal has been investigated for pressures up to 20 GPa and temperatures in the range 10--300 K. Under hydrostatic conditions (He pressure medium) the phonon…

Other Condensed Matter · Physics 2009-11-11 Yu. S. Ponosov , I. Loa , V. E. Mogilenskikh , K. Syassen

Infrared reflectivity spectra of cubic SrMnO$_{3}$ ceramics reveal 18 % stiffening of the lowest-frequency phonon below the antiferromagnetic phase transition occurring at T$_{N}$ = 233 K. Such a large temperature change of the polar phonon…

Phonon-phonon anharmonic effects have a strong influence on the phonon spectrum; most prominent manifestation of these effects are the softening (shift in frequency) and broadening (change in FWHM) of the phonon modes at finite temperature.…

A Fano-like phonon resonance is observed in few-layer (~3) graphene at room temperature using infrared Fourier transform spectroscopy. This Fano resonance is the manifestation of a strong electron-phonon interaction between the discrete…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 Zhihong Liu , Xiaoxiang Lu , Peng Peng , Wei Wu , Steven Pei , Qingkai Yu , Jiming Bao

The observation of pure phonon confinement effect in germanium nanowires is limited due to the illumination sensitivity of Raman spectra. In this paper we measured Raman spectra for different size germanium nanowires with different…

Quantum Physics · Physics 2009-11-13 Xi Wang , Ali Shakouri , Bin Yu , Xuhui Sun , Meyya Meyyappan

We present a Raman study of ZrAs_{2} single crystals, a nodal line semimetal with symmetry-enforced Dirac-like band crossings. We identified the symmetry of phonon modes by polarized light measurements and comparison with calculated phonon…

Materials Science · Physics 2024-05-16 R. Bacewicz , C. Jastrzębski , K. Zberecki , A. S. Wadge , D. Jastrzębski , A. Wiśniewski

Crystalline Silicon-on-Sapphire (SOS) films were implanted with boron (B$^+$) and phosphorous (P$^+$) ions. Different samples, prepared by varying the ion dose in the range $10^{14}$ to 5 x $10^{15}$ and ion energy in the range 150-350 keV,…

Mesoscale and Nanoscale Physics · Physics 2014-03-26 Rajesh Kumar , H. S. Mavi , A. K. Shukla

Despite the widespread use of silicon in modern technology, its peculiar thermal expansion is not well-understood. Adapting harmonic phonons to the specific volume at temperature, the quasiharmonic approximation, has become accepted for…

A comparison of experimentally observed Raman scattering data with Raman line-shapes, generated theoretically using phonon confinement model, has been carried out to understand the sensitivity of different Raman spectral parameters on…

Mesoscale and Nanoscale Physics · Physics 2020-03-20 Neeshu K. M. , Chanchal Rani , Ritika Kaushik , Manushree Tanwar , Ashisha Kumar , Rajesh Kumar

We report Raman spectra measurements on a MoS2 monolayer supported on SiO2 as a function of temperature. Unlike in previous studies, the positions of the two main Raman modes, E2g1 and A1g exhibited nonlinear temperature dependence.…

Mesoscale and Nanoscale Physics · Physics 2014-06-13 Andrzej Taube , Jarosław Judek , Cezariusz Jastrzębski , Anna Duzynska , Krzysztof Świtkowski , Mariusz Zdrojek

Spatially-resolved Raman spectra of individual pristine suspended carbon nanotubes are observed under electrical heating. The Raman G+ and G- bands show unequal temperature profiles. The preferential heating is more pronounced in short…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Vikram V. Deshpande , Scott Hsieh , Adam W. Bushmaker , Marc Bockrath , Stephen B. Cronin

Raman studies of nanocomposite SiCN thin film by sputtering showed that with an increase of substrate temperature from room temperature to 500oC, a transition from mostly sp2 graphitic phase to sp3 carbon took place which was observed from…

Materials Science · Physics 2016-11-24 A. S. Bhattacharyya , S. K. Mishra

Theoretical Raman line shape functions have been studied to take care of quantum confinement effect and Fano effect individually and jointly. The characteristics of various Raman line shapes have been studied in terms of the broadening and…

Boundary scattering in hierarchically disordered nanomaterials is an effective way to reduce the thermal conductivity of thermoelectric materials and increase their performance. In this work we investigate thermal transport in silicon based…

Materials Science · Physics 2019-02-27 Dhritiman Chakraborty , Laura de Sousa Oliveira , Neophytos Neophytou
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