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We present temperature-, magnetic-field-, and pressure-dependent Raman scattering studies of single crystal Mn3O4, combined with temperature- and field-dependent x-ray diffraction studies, revealing the novel magnetostructural phases in…

Strongly Correlated Electrons · Physics 2015-05-28 M. Kim , X. M. Chen , X. Wang , C. S. Nelson , R. Budakian , P. Abbamonte , S. L. Cooper

The ferrimagnetic spinel Mn3O4 exhibits large and anisotropic changes in electronic and structural properties in response to an applied magnetic field. These changes are thought to result from the field-dependent tuning---via strong…

Strongly Correlated Electrons · Physics 2016-06-22 T. Byrum , S. L. Gleason , A. Thaler , G. J. MacDougall , S. L. Cooper

The magnetic-field and temperature dependencies of ultrasound propagation and magnetization of single-crystalline CoCr2O4 have been studied in static and pulsed magnetic fields up to 14 T and 62 T, respectively. Distinct anomalies with…

Tetragonal distorted spinel of CuMn2-xTixO4 (x = 0, 0.25 and 0.50) was prepared by solid state reaction method followed by neutron diffraction, FTIR spectroscopy, dielectric spectroscopy and magnetization measurements. The neutron…

Materials Science · Physics 2020-12-01 P. Patra , I. Naik , S. D. Kaushik , S. Mohanta

Cubic spinel GeNi2O4 exhibits intriguing magnetic properties with two successive antiferromagnetic phase transitions (TN1 12.1 and TN2 11.4 K) with the absence of any structural transition. We have performed detailed heat capacity and…

Strongly Correlated Electrons · Physics 2020-12-02 T. Basu , T. Zou , Z. Dun , C. Q. Xu , C. R. Dela Cruz , Tao Hong , H. B. Cao , K. M. Taddei , H. D. Zhou , X. Ke

Cooperative Jahn-Teller ordering is well-known to drive the cubic $Fd\overline{3}m$ to tetragonal $I$4$_1$/$amd$ structural distortion in Mn$_3$O$_4$ at 1170 $^{\circ}$C. Further structural distortion occurs in Mn$_3$O$_4$ upon magnetic…

Materials Science · Physics 2014-08-26 Moureen C. Kemei , Jaye K. Harada , Ram Seshadri , Matthew R. Suchomel

Neutron and X-ray diffraction, magnetic susceptibility, and specific heat measurements have been used to investigate the magnetic and structural phase transitions of the spinel system Fe1+xCr2-xO4(0.0<=x<=1.0). The temperature versus Fe…

Co10Ge3O16 crystallizes in an intergrowth structure featuring alternating layers of spinel and rock salt. Variable-temperature powder synchrotron X-ray and neutron diffraction, magnetometry, and heat capacity experiments reveal a…

Materials Science · Physics 2013-07-12 Phillip T. Barton , Ram Seshadri , Anna Llobet , Matthew R. Suchomel

The phase stability of the MgMn2O4 spinel has been studied by means of high-pressure X-ray diffraction for pressures up to 30 GPa. Two samples with different inversion degrees have been considered. Both spinels undergo a phase transition…

Materials Science · Physics 2009-11-10 Lorenzo Malavasi , Cristina Tealdi , Monica Amboage , M. Cristina Mozzati , Giorgio Flor

Highly-strained BiFeO3 exhibits a "tetragonal-like, monoclinic" crystal structure found only in epitaxial films (with an out-of-plane lattice parameter exceeding the in-plane value by >20%). Previous work has shown that this phase is…

Materials Science · Physics 2011-08-17 Wolter Siemons , Michael D. Biegalski , Joong Hee Nam , Hans M. Christen

The crystal and magnetic structures of the spinel compounds ZnCr$_2$S$_4$ and ZnCr$_2$Se$_4$ were investigated by high resolution powder synchrotron and neutron diffraction. ZnCr$_2$Se$_4$ exhibits a first order phase transition at $T_N=21$…

Strongly Correlated Electrons · Physics 2009-11-13 F. Yokaichiya , A. Krimmel , V. Tsurkan , I. Margiolaki , P. Thompson , H. N. Bordallo , A. Buchsteiner , N. Stüßer , D. N. Argyriou , A. Loidl

Room temperature angle-dispersive x-ray diffraction measurements on spinel ZnGa2O4 up to 56 GPa show evidence of two structural phase transformations. At 31.2 GPa, ZnGa2O4 undergoes a transition from the cubic spinel structure to a…

Materials Science · Physics 2010-05-04 D. Errandonea , Ravhi S. Kumar , F. J. Manjon , V. V. Ursaki , E. V. Rusu

Using polarization-resolved Raman spectroscopy, we investigate layer number, temperature, and magnetic field dependence of Raman spectra in one- to four-layer $\mathrm{CrI_{3}}$. Layer-number-dependent Raman spectra show that in the…

The ferrimagnetic spinel $\mathrm{CoV_2O_4}$ has been a topic of intense recent interest, both as a frustrated insulator with unquenched orbital degeneracy and as a near-itinerant magnet which can be driven metallic with moderate applied…

Strongly Correlated Electrons · Physics 2016-02-03 D. Reig-i-Plessis , D. Casavant , V. O. Garlea , A. A. Aczel , M. Feygenson , J. Neuefeind , H. D. Zhou , S. E. Nagler , G. J. MacDougall

The structural and magnetic properties of the hexagonal four-layer form of SrMnO$_3$ have been investigated by combining magnetization measurements, electron diffraction and high-resolution synchrotron X-ray and neutron powder diffraction.…

Strongly Correlated Electrons · Physics 2007-05-23 A. Daoud-Aladine , C. Martin , L. C. Chapon , M. Hervieu , K. S. Knight , M. Brunelli , P. G. Radaelli

The single layered manganite Pr$_{0.22}$Sr$_{1.78}$MnO$_4$ undergoes structural transition from high temperature tetragonal phase to low temperature orthorhombic phase below room temperature. The orthorhombic phase was reported to have two…

Strongly Correlated Electrons · Physics 2012-04-25 S. Chattopadhyay , S. Giri , S. Majumdar

The local structure of V$_{2}$O$_{3}$, an archetypal strongly correlated electron system that displays a metal-insulator transition around 160 K, has been investigated via pair distribution function (PDF) analysis of neutron and x-ray total…

Strongly Correlated Electrons · Physics 2021-11-30 Ethan R. A. Fletcher , Kentaro Higashi , Yoav Kalcheim , Hiroshi Kageyama , Benjamin A. Frandsen

Neutron diffraction experiments of TmFeO$_3$ single crystals were performed in the external magnetic fields. The field along $c$-axis increases temperature of spin-reorientation transition $T_{SR}$ from phase ${\Gamma}4$ to ${\Gamma}2$.…

MnCr2O4 that exhibits spin frustration and complex spiral spin order is of great interest from both fundamental as well as application-oriented perspectives. Unlike CoCr2O4 whose ground state presents the coexistence of commensurate spiral…

Ultrasound and magnetization studies of bond-frustrated ZnCr2S4 spinel are performed in static magnetic fields up to 18 T and in pulsed fields up to 62 T. At temperatures below the antiferromagnetic transition at T_N1 14 K the sound…

Strongly Correlated Electrons · Physics 2015-03-19 V. Tsurkan , S. Zherlitsyn , V. Felea , S. Yasin , Yu. Skourski , J. Deisenhofer , H. -A. Krug von Nidda , P. Lemmens , J. Wosnitza , A. Loidl
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