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The search for large polycyclic aromatic hydrocarbons (PAHs) with over 100 carbon atoms is crucial to resolving the origin of unidentified infrared emission (UIE) bands. These bands are commonly observed in nebulae and the interstellar…

Astrophysics of Galaxies · Physics 2025-08-22 Yi Shao , Yong Zhang , Xu-Jia Ouyang , Chuan-Peng Zhang

Because the 8 {\mu}m polycyclic aromatic hydrocarbon (PAH) emission has been found to correlate with other well-known star formation tracers, it has widely been used as a star formation rate (SFR) tracer. There are, however, studies that…

Evolved stars are primary sources for the formation of polycyclic aromatic hydrocarbons (PAHs) and dust grains. Their circumstellar chemistry is usually designated as either oxygen-rich or carbon-rich, although dual-dust chemistry objects,…

Solar and Stellar Astrophysics · Physics 2015-12-23 N. L. J. Cox , P. Pilleri , O. Berne , J. Cernicharo , C. Joblin

Context: Hydrogenation reactions are expected to be among the most important surface reactions on interstellar ices. However, solid state astrochemical laboratory data on reactions of H-atoms with common interstellar ice constituents are…

Astrophysics · Physics 2009-11-13 S. E. Bisschop , G. W. Fuchs , E. F. van Dishoeck , H. Linnartz

We present resolved $3.6-250~\mu$m dust spectral energy distribution (SED) fitting for $\sim 800$ nearby galaxies. We measure the distribution of radiation field intensities heating the dust, the dust mass surface density ($\Sigma_{\rm…

Clusters of polycyclic aromatic hydrocarbons (PAHs) have been proposed as candidates for evaporating very small grains, which are thought to be precursors of free-flying PAHs. Evaporation rates have been calculated so far only for species…

Astrophysics of Galaxies · Physics 2014-09-05 Julien Montillaud , Christine Joblin

The formation of Polycyclic Aromatic Hydrocarbons in the circumstellar outflows of evolved stars is reviewed, with an emphasis on carbon stars on the Asymptotic Giant Branch. Evidence for PAHs present in their winds is provided by…

Solar and Stellar Astrophysics · Physics 2015-05-20 Isabelle Cherchneff

The high interstellar abundances of polycyclic aromatic hydrocarbons (PAHs) and their size distribution are the result of complex chemical processes implying dust, UV radiation, and the main gaseous components (H, C+, and O). These…

Astrophysics of Galaxies · Physics 2021-07-07 A. Omont , H. F. Bettinger

Polycyclic aromatic hydrocarbon (PAH) molecules are widely considered as the preferred candidate for the carrier of the unidentified infrared emission bands observed in the interstellar medium and circumstellar envelopes. In this paper we…

Solar and Stellar Astrophysics · Physics 2015-06-23 Yong Zhang , Sun Kwok

Recent calculations have shown that the UV bump at about 217.5 nm in the extinction curve can be explained by a complex mixture of PAHs in several charge states. Other studies proposed that the carriers are a restricted population made of…

Astrophysics · Physics 2009-11-13 G. Malloci , G. Mulas , C. Cecchi-Pestellini , C. Joblin

Interstellar ubiquitous infrared spectrum (IR) due to polycyclic aromatic hydrocarbon (PAH) was observed in many astronomical dust clouds. A capable astronomical chemical evolution path from graphene to PAH was studied based on the first…

Mesoscale and Nanoscale Physics · Physics 2017-03-20 Norio Ota

OH is a cornerstone molecule in the chemistry of interstellar and circumstellar media and is ubiquitously detected in warm gas thanks to its infrared rotational lines. However, the excitation processes of OH remain poorly characterized. We…

As images and spectra from ISO and Spitzer have provided increasingly higher-fidelity representations of the mid-infrared (MIR) and Polycyclic Aromatic Hydrocarbon (PAH) emission from galaxies and galactic and extra-galactic regions, more…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-20 Daniela Calzetti

We present new spectroscopic observations of the inner circumgalactic medium (CGM) of NGC 891 taken with the Mid-Infrared Imager/Medium Resolution Spectroscopy instrument onboard JWST, in four positions: two near the bulge and two at…

We investigate the variation in the mid-infrared spectral energy distributions of 373 low-redshift ($z<0.4$) star-forming galaxies, which reflects a variety of polycyclic aromatic hydrocarbon (PAH) emission features. The relative strength…

Carbonaceous grains represent a major component of cosmic dust. In order to understand their formation pathways, they have been prepared in the laboratory by gas-phase condensation reactions such as laser pyrolysis and laser ablation. Our…

Astrophysics of Galaxies · Physics 2011-02-11 C. Jäger , H. Mutschke , I. Llamas Jansa , Th. Henning , F. Huisken

We present results of mid-infrared spectroscopic mapping observations of six star-forming regions in the Small Magellanic Cloud from the Spitzer Spectroscopic Survey of the SMC (S4MC). We detect the mid-IR emission from polycyclic aromatic…

Various studies have emphasized variations of the charge state and composition of the interstellar polycyclic aromatic hydrocarbon (PAH) population in photodissociation regions (PDRs). We aim to model the spatial evolution of the charge and…

Astrophysics of Galaxies · Physics 2015-06-12 J. Montillaud , C. Joblin , D. Toublanc

In this Letter we report the results of density functional theory calculations on medium-sized neutral Polycyclic Aromatic Hydrocarbon (PAH) molecules with armchair edges. These PAH molecules possess strong C-H stretching and bending modes…

Astrophysics of Galaxies · Physics 2014-10-09 A. Candian , P. J. Sarre , A. G. G. M. Tielens

Methylated polycyclic aromatic hydrocarbons (PAHs) have been hypothesised to be present in the interstellar medium (ISM) through their 3.4 and 6.9 $\mu$m absorption bands. To investigate the hydrogenation of these methylated PAHs, the…

Astrophysics of Galaxies · Physics 2026-02-11 A. T. Hopkinson , F. G. Doktor , J. Pitfield , M. Moll , J. D. Thrower , L. Hornekær