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Neutron diffraction experiments have been carried out on a Sn-flux grown BaFe2As2 single crystal, the parent compound of the A-122 family of FeAs-based high-Tc superconductors. A tetragonal to orthorhombic structural phase transition and a…

We report the structure and magnetism of PrOFeAs, one of the parent phases of the newly discovered Fe-As superconductors, as measured by neutron powder diffraction. In common with other REOFeAs materials, a tetragonal-orthorhombic phase…

Neutron powder diffraction has been used to investigate the structural and magnetic behavior of the isoelectronically doped Fe pnictide material PrFe1-xRuxAsO. Substitution of Ru for Fe suppresses the structural and magnetic phase…

Superconductivity · Physics 2016-11-11 Yuen Yiu , V. Ovidiu Garlea , Michael A. McGuire , Ashfia Huq , David Mandrus , Stephen E. Nagler

Synchrotron x-ray diffraction experiments were performed on BaFe$_2$As$_2$ and Sr(Fe$_{1-x}$Co$_{x}$)$_2$As$_2$ single crystals as a function of temperature and applied magnetic field along the tetragonal $[1 \bar{1} 0]$ direction,…

Superconductivity · Physics 2018-07-02 U. F. Kaneko , C. B. R. Jesus , M. E. Saleta , P. G. Pagliuso , R. R. Urbano , E. Granado

Neutron diffraction measurements of a high quality single crystal of CaFe2As2 are reported. A sharp transition was observed between the high temperature tetragonal and low temperature orthorhombic structures at TS = 172.5K (on cooling) and…

Neutron powder diffraction experiments were carried out on polycrystalline SrFe$_2$As$_2$ in order to determine the magnetic structure and its relationship with the crystallographic one. Below $T_0$=205 K, magnetic reflections appear…

Superconductivity · Physics 2009-01-06 K. Kaneko , A. Hoser , N. Caroca-Canales , A. Jesche , C. Krellner , O. Stockert , C. Geibel

The structural and magnetic phase transitions of the ternary iron arsenides SrFe2As2 and EuFe2As2 were studied by temperature-dependent x-ray powder diffraction and 57-Fe Moessbauer spectroscopy. Both compounds crystallize in the tetragonal…

The new quaternary iron arsenide-fluoride SrFeAsF with the tetragonal ZrCuSiAs-type structure was synthesized and the crystal structure was determined by X-ray powder diffraction (P4/nmm, a = 399.30(1), c = 895.46(1) pm). SrFeAsF undergoes…

Superconductivity · Physics 2009-01-06 M. Tegel , S. Johansson , V. Weiss , I. Schellenberg , W. Hermes , R. Poettgen , Dirk Johrendt

SrFe2As2 is the end-member for a series of iron-pnictide superconductors and has a tetragonal-to-orthorhombic phase transition near 200 K. Previous macroscopic measurements to determine the nature of the transition gave seemingly…

Superconductivity · Physics 2015-05-18 J. C. Loudon , C. J. Bowell , J. Gillett , S. E. Sebastian , P. A. Midgley

We report investigation of structural phase transitions in technologically important material sodium niobate as a function of temperature on heating over 300-1075 K. Our high resolution powder neutron diffraction data show variety of…

Materials Science · Physics 2015-05-20 S. K. Mishra , R. Mittal , V. Yu. Pomjakushin , S. L. Chaplot

We present results from a detailed experimental investigation of LaFeAsO, the parent material in the series of "FeAs" based oxypnictide superconductors. Upon cooling this material undergoes a tetragonal-orthorhombic crystallographic phase…

We report a comprehensive neutron diffraction study of the crystal structure and magnetic order in a series of single-crystal and powder samples of SrFeO$_{3-\delta}$ in the vacancy range $0 \leq \delta \leq 0.23$. The data provide detailed…

Strongly Correlated Electrons · Physics 2015-06-05 M. Reehuis , C. Ulrich , A. Maljuk , Ch. Niedermayer , B. Ouladdiaf , A. Hoser , T. Hofmann , B. Keimer

The structural, magnetic and resistive properties of (La1-yYy)FeAsO compounds (y = 0.10, 0.20, 0.30) have been investigated by means of X-ray and neutron powder diffraction as well as by resistivity measurements. The temperatures at which…

Materials Science · Physics 2015-05-14 A. Martinelli , A. Palenzona , M. Tropeano , C. Ferdeghini , M. R. Cimberle , C. Ritter

A neptunium analogue of the LaFeAsO tetragonal layered compound has been synthesized and characterized by a variety of experimental techniques. The occurrence of long-range magnetic order below a critical temperature T_N = 57 K is suggested…

We report the temperature dependent x-ray powder diffraction of the FeAs-based superconductors in the range between 300 K and 95 K. In the case of NdOFeAs we have detected the structural phase transition from the tetragonal phase, with…

Superconductivity · Physics 2009-01-12 Alessandro Ricci , Michela Fratini , Antonio Bianconi

The structural properties of the CaFe2As2 have been investigated by x-ray and neutron powder diffraction techniques as a function of temperature. Unambiguous experimental evidence is shown for coexistence of tetragonal and orthorhombic…

Superconductivity · Physics 2013-11-27 S. K. Mishra , R. Mittal , P. S. R. Krishna , P. U. Sastry , S. L. Chaplot , P. D. Babu , S. Matsuishi , H. Hosono

Elastic neutron scattering studies of an optimized LaFeAsO single crystal reveal that upon cooling, an onset of the tetragonal (T)-to-orthorhombic (O) structural transition occurs at $T_\texttt{S} \approx 156$ K, and it exhibits a sharp…

Superconductivity · Physics 2015-05-19 H. -F. Li , W. Tian , J. -Q. Yan , J. L. Zarestky , R. W. McCallum , T. A. Lograsso , D. Vaknin

We report systematic investigation of high pressure crystal structures and structural phase transition upto 46 GPa in CaFeAsF and 40 GPa in SrFeAsF at 40 K using powder synchrotron x-ray diffraction experiments and Rietveld analysis of the…

The structural and magnetic phase transitions have been studied on NdFeAsO single crystals by neutron and x-ray diffraction complemented by resistivity and specific heat measurements. Two low-temperature phase transitions have been observed…

The fluorine-doped rare-earth iron oxypnictide series SmFeAsO$_{1-x}$F$_x$ (0 $\leq x \leq$ 0.10) was investigated with high resolution powder x-ray scattering. In agreement with previous studies, the parent compound SmFeAsO exhibits a…

Superconductivity · Physics 2018-02-26 H. D. Zhou , P. M. Sarte , B. S. Conner , L. Balicas , C. R. Wiebe , X. H. Chen , T. Wu , G. Wu , R. H. Liu , H. Chen , D. F. Fang
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