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Multiferroic BiFeO3 epitaxial films with thickness ranging from 40 nm to 960 nm were grown by pulsed laser deposition on SrTiO3 (001) substrates with SrRuO3 bottom electrodes. X-ray characterization shows that the structure evolves from…

Materials Science · Physics 2009-11-13 Dae Ho Kim , Ho Nyung Lee , Michael D. Biegalski , Hans M. Christen

The balance between interfacial chemistry, electrostatics, and epitaxial strain plays a crucial role in stabilizing polarization in ferroelectric thin films. Here, we bring these contributions into competition in BiFeO$_3$ (BFO) thin films…

Materials Science · Physics 2026-01-27 Elzbieta Gradauskaite , Natascha Gray , Quintin N. Meier , Marta D. Rossell , Morgan Trassin

Magnetite has long been investigated across many disciplines due to the interplay between its ferroic order parameters, namely its ferrimagnetism, ferroelasticity and ferroelectricty. Despite this, the experimental difficulty in measuring…

Materials Science · Physics 2023-10-25 S. D. Seddon , A. Cooper , T. Fricke , S. G. Ebbinghaus , M. Walker , T. P. A. Hase , W. J. A. Blackmore , M. Alexe

To minimize their electrostatic energy, insulating ferroelectric films tend to break up into nanoscale ``Kittel'' domains of opposite polarization that are separated by uncharged 180$^\circ$ domain walls. Here, I report on self-consistent…

Mesoscale and Nanoscale Physics · Physics 2022-10-14 W. A. Atkinson

Ferroelectric switching in BiFeO$_3$ multiferroic thin films with intrinsic ``stripe-like'' and ``bubble-like'' polydomain configurations was studied by piezoresponse force microscopy. Using the local electric field applied by a scanning…

Materials Science · Physics 2009-07-28 H. Béa , M. Bibes , A. Barthélémy , P. Paruch

Multiferroics have received intense attention due to their great application potential in multi-state information storage devices and new types of sensors. Coupling among ferroic orders such as ferroelectricity, (anti-)ferromagnetism,…

Structural features of ferroic domains are fundamentally important for the understanding of microstructure and physical properties of ferroic materials, and they are also of technological significance for information storage and electronic…

Materials Science · Physics 2012-05-22 J. Q. Li , J. Li , H. X. Yang , H. F. Tian , S-W. Cheong , C. Ma , S. Zhang , Y. G. Zhao

Flat phonon bands in fluorite ferroelectrics (HfO2 or ZrO2) shrink polar domains laterally to an irreducible half-unit-cell width (0.27 nm) within which the vertical arrangement of dipoles is expected to remain uniform. We report on the…

The structural evolution of a polydomain ferroelectric Pb(Zr0.2Ti0.8)O3 film was studied by temperature dependent X-ray diffraction. Two critical temperatures were evidenced: T*=740K, corresponding to a change in the domain structure…

We report on growth and ferroelectric (FE) properties of superlattices (SLs) composed of the FE BaTiO3 and the paraelectric (PE) CaTiO3. Previous theories have predicted that the polarization in (BaTiO3)n/(CaTiO3)n SLs increases as the…

Materials Science · Physics 2013-09-09 Sung Seok A. Seo , Ho Nyung Lee

Domain pattern transfer from ferroelectric to ferromagnetic materials is a critical step for the electric field control of magnetism and has the potential to provide new schemes for low-power data storage and computing devices. Here we…

Materials Science · Physics 2023-07-06 Robbie G. Hunt , Kévin J. A. Franke , Philippa M. Shepley , Thomas A. Moore

Artificial superlattices of (BiFeO3)m(SrTiO3)m (m= 1 to 10 unit cells) consisting of multiferroic BiFeO3 and insulating SrTiO3 layers were fabricated on (100)-oriented SrTiO3 substrates by pulsed laser ablation. The remnant polarization and…

Materials Science · Physics 2009-11-13 R. Ranjith , B. Kundys , W. Prellier

Large magnetoelectric response in thin films is highly desired for high-throughput and high-density microelectronic applications. However, the d0 rule in single-phase compounds usually results in a weak interaction between ferroelectric and…

Strongly Correlated Electrons · Physics 2019-10-07 Xin Liu , Peipei Lu , Mei Wu , Yuanwei Sun , Jingdi Lu , Jing Wang , Dayu Yan , Youguo Shi , Zhiping Yin , Nian Xiang Sun , Peng Gao , Young Sun , Fa Wang , Ce-Wen Nan , Jinxing Zhang

Using density functional theory calculations, ultrathin films of SrVO3(d1) and SrCrO3(d2) on SrTiO3 substrates have been studied as possible multiferroics. Although both are metallic in the bulk limit, they are found to be insulating as a…

Materials Science · Physics 2015-06-16 Kapil Gupta , Priya Mahadevan , Phivos Mavropoulos , Marjana Lezaic

We carry out first-principles calculations for CaTiO$_3$/BaTiO$_3$ superlattices with epitaxial strain corresponding to growth on a SrTiO$_3$ substrate, and consider octahedral rotations as well as ferroelectric distortions. The…

Materials Science · Physics 2015-05-19 Xifan Wu , Karin M. Rabe , David Vanderbilt

The equilibrium sizes of micro- and nano-domains caused by electric field of atomic force microscope tip in ferroelectric semiconductor crystals have been calculated. The domain was considered as a prolate semi-ellipsoid with rather thin…

Materials Science · Physics 2009-11-11 Anna N. Morozovska , Eugene A. Eliseev

A key property that drives research in ferroelectric perovskite oxides is their strong piezoelectric response in which an electric field is induced by an applied strain, and vice-versa for the converse piezoelectric effect. We have achieved…

Materials Science · Physics 2015-06-11 J. Sinsheimer , S. J. Callori , B. Bein , Y. Benkara , J. Daley , J. Coraor , D. Su , P. W. Stephens , M. Dawber

Perovskite BaSnO3 has an Sn s-orbital conduction band minimum, which makes it of interest as a transparent-conducting oxide parent compound but also contraindicates the ferroelectric instability characteristic of the related compound…

Materials Science · Physics 2025-01-07 Jing Li , Qing Zhang , Karin M. Rabe , Xiaohui Liu

We propose the thermodynamical theory of nanodomain tailoring with the help of atomic force microscope electric field in thin ferroelectric-semiconductor films. We modified the existing thermodynamical models of domain formation allowing…

Materials Science · Physics 2007-05-23 Anna N. Morozovska , Eugene A. Eliseev

Crystal and domain structures of tensile-strained BiFeO3 films grown on orthorhombic (110)o PrScO3 substrates were investigated. All films possess a MB-type monoclinic structure with 109o stripe domains oriented along the [\=i10]o…

Materials Science · Physics 2013-09-04 Zuhuang Chen , Yajun Qi , Lu You , Ping Yang , C. W. Huang , Junling Wang , Thirumany Sritharan , Lang Chen