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We employ scanning probe microscopy to reveal atomic structures and nanoscale morphology of graphene-based electronic devices (i.e. a graphene sheet supported by an insulating silicon dioxide substrate) for the first time. Atomic resolution…

Materials Science · Physics 2008-11-05 Masa Ishigami , J. H. Chen , W. G. Cullen , M. S. Fuhrer , E. D. Williams

Graphene oxide (GO), the functionalized graphene with oxygenated groups (mainly epoxy and hydroxyl), has attracted resurgent interests in the past decade owing to its large surface area, superior physical and chemical properties, and easy…

Materials Science · Physics 2020-01-14 Xiaoming Huang , Lizhao Liu , Si Zhou , Jijun Zhao

We present a fabrication method producing large and flat graphene flakes that have a few layers down to a single layer based on substrate bonding of a thick sample of highly oriented pyrolytic graphite (HOPG), followed by its controlled…

Mesoscale and Nanoscale Physics · Physics 2012-07-03 Vincent Huc , Nedjma Bendiab , Noel Rosman , Thomas Ebbesen , Cecile Delacour , Vincent Bouchiat

Nanocomposite material proves to be the best candidate to match todays technological need as fascinating properties can be achieved by combining two or more nanomaterials. Among various nanomaterials, graphene is able to stand out far ahead…

Applied Physics · Physics 2019-11-06 Joydip Sengupta

Nano-holes, etched under an electron beam at room temperature in singlelayer graphene sheets as a result of their interaction with metalimpurities, are shown to heal spontaneously by filling up with either non-hexagon, graphene-like, or…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Recep Zan , Quentin M. Ramasse , Ursel Bangert , Konstantin S. Novoselov

Graphene is a very promising material for nanoelectronics applications due to its unique and remarkable electronic and thermal properties. However, when deposited on metallic electrodes the overall thermal conductivity is significantly…

Bulk quantities of graphene nanosheets and nanodots have been selectively fabricated by mechanical grinding exfoliation of natural graphite in a small quantity of ionic liquids. The resulting graphene sheets and dots are solvent free with…

Graphene is a material of great potential in a broad range of applications, for each of which specific tuning of the materials properties is required. This can be achieved, for example, by covalent functionalization. We have exploited two…

Two different types of boron-doped graphene/copper interfaces synthesized using two different flow rates of Ar through the bubbler containing the boron source were studied. X-ray photoelectron spectra (XPS) and optically stimulated electron…

We report energy estimated to dissociate a C-C bond of a graphene sheet to form nanoribbons of armchair and zigzag configurations using first principles calculations. For the ground state energy calculations, the configurations considered…

Materials Science · Physics 2014-02-19 Deepika , T. J. Dhilip Kumar , Nitin K. Goel , Rakesh Kumar

We demonstrate a bottom-up synthesis of structures similar to graphene oxide via a two dimensional polymerization. Experimental evidence and discussion are conveyed as well as a general framework for this two dimensional polymerization. The…

Heat transfer between graphene and water is pivotal for various applications, including solarthermal vapor generation and the advanced manufacturing of graphene-based hierarchical structures in solution. In this study, we employ a…

Materials Science · Physics 2024-09-02 Haoran Cui , Iyyappa Rajan Panneerselvam , Pranay Chakraborty , Qiong Nian , Yiliang Liao , Yan Wang

A new formula for elastic bending modulus of monolayer graphene is derived analytically from an empirical potential for solid-state carbon-carbon bonds. Two physical origins are identified for the non-vanishing bending modulus of the…

Materials Science · Physics 2015-05-13 Qiang Lu , Marino Arroyo , Rui Huang

High quality epitaxial graphene films can be applied as templates for tailoring graphene-substrate interfaces that allow for precise control of the charge carrier behavior in graphene through doping and many-body effects. By combining…

Graphite has been one of the promising materials in diverse application domains owing to its high conductivity, tunability into different structures and mechanical strength its. The effectiveness of graphite and its derivatives has been…

Applied Physics · Physics 2018-06-06 Amit R. Morarka , Aditee C. Joshi

Graphynes are 2D porous structures deriving from graphene featuring triangular and regularly distributed subnanometer pores, which may be exploited to host small gaseous species. First principles adsorption energies of molecular hydrogen…

Chemical Physics · Physics 2015-10-06 Massimiliano Bartolomei , Estela Carmona-Novillo , Giacomo Giorgi

A body-centered tetragonal carbon (bct-Carbon) allotrope has been predicted to be a transparent carbon polymorph obtained under pressure. The structural transition pathways from graphite to diamond, M-Carbon, and bct-Carbon are simulated…

Materials Science · Physics 2010-11-02 Xiang-Feng Zhou , Xiao Dong , Guang-Rui Qian , Lixin Zhang , Yonjun Tian , Hui-Tian Wang

We demonstrate a method by which few-layer graphene samples can be etched along crystallographic axes by thermally activated metallic nanoparticles. The technique results in long (>1 micron) crystallographic edges etched through to the…

Materials Science · Physics 2009-05-08 Sujit S. Datta , Douglas R. Strachan , Samuel M. Khamis , A. T. Charlie Johnson

Electrochemical exfoliation is one of the most promising methods for scalable production of graphene. However, limited understanding of its Raman spectrum as well as lack of measurement standards for graphene strongly limit its industrial…

Novel route for the establishing of magnetism in realistic oxidized graphene nanoribbons is proposed. Modelling of the migration of hydroxyl groups from central part to the zig-zag edges of graphene nanoribbons passivated by oxygen are…

Materials Science · Physics 2015-05-20 D. W. Boukhvalov