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We carried out fully atomistic reactive molecular dynamics simulations to study the mechanical behavior of six newly proposed hybrid schwarzite-based structures (interlocked petal-schwarzites). Schwarzites are carbon crystalline…

Schwarzites are 3D crystalline porous materials exhibiting the shape of Triply Periodic Minimal Surfaces (TPMS). They possess negative Gaussian curvature, created by the presence of rings with more than six sp2-hybridized carbon atoms.…

Materials Science · Physics 2020-01-20 Levi C. Felix , Cristiano F. Woellner , Douglas S. Galvao

Since graphene was synthesized the interest for building new 2D and 3D structures based on the carbon allotropes has been growing every day. One of these 3D structures is know as carbon schwarzites. Schwarzites consist of carbon…

Materials Science · Physics 2020-08-26 Raphael M. Tromer , Levi C. Felix , Cristiano F. Woellner , Douglas S. Galvao

Schwarzites are crystalline, 3D porous structures with stable negative curvature formed of sp2-hybridized carbon atoms. These structures present topologies with tunable porous size and shape and unusual mechanical properties. In this work,…

Mesoscale and Nanoscale Physics · Physics 2018-01-18 Cristiano F. Woellner , Tiago Botari , Eric Perim , Douglas S. Galvao

Schwarzites are porous structures that present negative Gaussian curvatures. Although initially proposed for carbon, in principle, schwarzites of other elements are possible. In this work, we have carried out a detailed investigation of the…

Materials Science · Physics 2022-08-23 Raphael M. Tromer , Levi C. Felix , Cristiano F. Woellner , Douglas S. Galvao

Negative Gaussian curvature provides an unusual route for designing electronic structure in extended sp2 carbon networks. Here I report ab initio density-functional calculations on the D-type carbon schwarzite C136, focusing on the response…

Materials Science · Physics 2026-05-08 Eugene Yashin

We report production of nanostructured carbon foam by a high-repetition-rate, high-power laser ablation of glassy carbon in Ar atmosphere. A combination of characterization techniques revealed that the system contains both sp2 and sp3…

Schwarzites are porous crystalline structures with Gaussian negative curvature. In this work, we investigated the mechanical behavior and energy absorption properties of two carbon-based diamond schwarzites (D688 and D8bal). We carried out…

Nature-occurring structures exhibiting unique topological features such as complex and gradient porosity has been the basis to create new materials and/or structures. Most studies have been focused on complex periodic porous structures but…

Materials Science · Physics 2021-11-15 Eliezer F. Oliveira , Rushikesh S. Ambekar , Douglas S. Galvao , Chandra S. Tiwary

The 3D porous carbon-based structures called Schwarzites have been recently a subject of renewed interest due to the possibility of being synthesized in the near future. These structures exhibit negatively curvature topologies with tuneable…

Computational Physics · Physics 2018-01-22 Daiane Damasceno Borges , Douglas S. Galvao

Carbon atoms can form structures in one, two, and three dimensions due to its unique chemical versatility. In terms of thermal conductivity, carbon polymorphs cover a wide range from very low values with amorphous carbon to very high values…

Materials Science · Physics 2013-10-22 Luiz Felipe C. Pereira , Ivana Savić , Davide Donadio

Carbon foams are hypothetical carbon allotropes that contain graphite-like (sp$^2$ carbon) segments, connected by sp$^3$ carbon atoms, resulting in porous structures. In this work the DFTB (Density Functional based Tight-Binding) method…

Materials Science · Physics 2013-02-15 Gotthard Seifert , Agnieszka Kuc , Thomas Heine

First principles FPLAPWcalculations were performed in the framework of Density Functional Theory (DFT), to study the electronic structures and magnetic properties for the new full-Heusler compounds: Sc2CoZ (Z=Si, Ge, Sn). The investigated…

Materials Science · Physics 2014-03-25 A. Birsan

We investigated through fully atomistic molecular dynamics simulations, the mechanical behavior (compressive and tensile) and energy absorption properties of two families (primitive (P688 and P8bal) and gyroid (G688 and G8bal)) of…

Materials Science · Physics 2019-09-10 Levi C. Felix , Cristiano F. Woellner , Douglas S. Galvao

We use ab initio density functional calculations to study the formation and structural as well as thermal stability of cellular foam-like carbon nanostructures. These systems with a mixed $sp^2/sp^3$ bonding character may be viewed as…

Materials Science · Physics 2015-06-11 Zhen Zhu , David Tománek

The widely used crystal structures for both heptazine-based and triazine-based two-dimensional (2D) graphitic carbon nitride (g-C$_3$N$_4$) are the flat P-6m2 configurations. However, the experimentally synthesized 2D g-C$_3$N$_4$ possess…

Materials Science · Physics 2021-02-03 Luneng zhao , Xizhi Shi , Jin Li , Tao Ouyang , Chunxiao Zhang , Chao Tang , Chaoyu He , Jianxin Zhong

Nanoporous carbon materials containing small domains of sp2-carbon with highly disordered structures are promising for supercapacitor applications. Herein, we synthesize amorphous carbon nanofoam with 98% volumetric void fraction and low…

Carbon atomic wires, a linear atomic chain of sp-carbon, is theoretically predicted to have around five times higher surface area than graphene, notable charge mobilities, as well as excellent optical and thermal properties. Despite these…

Applied Physics · Physics 2025-03-19 Subrata Ghosh , Massimiliano Righi , Simone Melesi , Yu Qiu , Rik R. Tykwinski , Carlo S. Casari

Pulsed laser-deposited amorphous carbon nanofoams are potential candidate for electrochemical energy storage applications due to ultra-light weight, large volumetric void fractions, and co-existence of sp, sp2 and sp3 carbon hybridization.…

While crystalline two-dimensional materials have become an experimental reality during the past few years, an amorphous 2-D material has not been reported before. Here, using electron irradiation we create an sp2-hybridized one-atom-thick…

Materials Science · Physics 2011-03-22 J. Kotakoski , A. V. Krasheninnikov , U. Kaiser , J. C. Meyer
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