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Honeycomb layered oxides with monovalent or divalent, monolayered cationic lattices generally exhibit myriad crystalline features encompassing rich electrochemistry, geometries and disorders, which particularly places them as attractive…

Electronic states of single-component molecular metals M(tmdt)2 (M = Ni, Au) are studied theoretically. We construct an effective three-band Hubbard model for each material by numerical fitting to first-principles band calculations, while…

Strongly Correlated Electrons · Physics 2008-02-19 Hitoshi Seo , Shoji Ishibashi , Yoshinori Okano , Hayao Kobayashi , Akiko Kobayashi , Hidetoshi Fukuyama , Kiyoyuki Terakura

Graphene devices require electric contacts with metals, particularly with gold. Scanning tunneling spectroscopy studies of electron local density of states performed on mono-, bi- and tri- graphene layer deposited on metallic conductive…

Materials Science · Physics 2009-01-05 Z. Klusek , P. Dabrowski , P. Kowalczyk , W. Kozlowski , P. Blake , M. Szybowicz , T. Runka , W. Olejniczak

Monolayer structures made up of purely one kind of atoms are fascinating. Many kinds of honeycomb systems including carbon, silicon, germanium, tin, phosphorus and arsenic have been shown to be stable. However, so far the structures are…

Mesoscale and Nanoscale Physics · Physics 2015-08-25 C. Kamal , Aparna Chakrabarti , Motohiko Ezawa

This work reports optical and electronic numerical modelling of a novel emerging structure which is the GaAs nanocrystal on Si tandem solar cell by epitaxial lateral overgrowth, a technique which allows defect free material growth. The…

In the search for evidence of silicene, a two-dimensional honeycomb lattice of silicon, it is important to obtain a complete picture for the evolution of Si structures on Ag(111), which is believed to be the most suitable substrate for…

Materials Science · Physics 2015-06-04 Baojie Feng , Zijing Ding , Sheng Meng , Yugui Yao , Xiaoyue He , Peng Cheng , Lan Chen , Kehui Wu

Heterostructures are ubiquitous in many optoelectronic devices and as photocatalysts. One of the key features of a heterojunction is the proper band alignment between the two materials. Estimation of the correct relative band positions with…

Mesoscale and Nanoscale Physics · Physics 2024-08-13 Raheel Hammad , Snehith Adabala , Soumya Ghosh

We present a so far undetected submonolayer phase of copper telluride on Cu(111) with $\left(5 \times \sqrt{3}\right)_{\text{rect}}$ periodicity and coverage of 0.40 ML Tellurium (Te), which can be grown with perfect long-range order. It is…

Materials Science · Physics 2021-11-18 Lutz Hammer , Tilman Kißlinger , M. Alexander Schneider

On-surface metal-organic coordination provides a promising way for synthesizing different two-dimensional lattice structures that have been predicted to possess exotic electronic properties. Using scanning tunneling microscopy (STM) and…

Materials Science · Physics 2019-10-04 Linghao Yan , Ilona Pohjavirta , Benjamin Alldritt , Peter Liljeroth

We devise a scheme to characterize tunneling of an excess electron shared by a pair of tunnel-coupled dangling bonds on a silicon surface -- effectively a two-level system. Theoretical estimates show that the tunneling should be highly…

Mesoscale and Nanoscale Physics · Physics 2014-02-05 Zahra Shaterzadeh-Yazdi , Lucian Livadaru , Marco Taucer , Josh Mutus , Jason Pitters , Robert A. Wolkow , Barry C. Sanders

We report on the formation of lobe-lobe (bi-lobed) Au-Ge nanostructures under ultra high vacuum (UHV) conditions (\approx 3\times 10^{-10} mbar) on clean Si(100) surfaces. For this study, \approx 2.0 nm thick Au samples were grown on the…

Mesoscale and Nanoscale Physics · Physics 2017-11-27 Ashutosh Rath , J. K. Dash , R. R. Juluri , Marco Schowalter , Knut Mueller , A. Rosenauer , P. V. Satyam

The electronic properties of the two-dimensional (2D) $\alpha$ phase of antimonene are unique, featuring unpinned Dirac cones that can be moved with strain. Here we investigate the structural and electronic properties of an epitaxial 2D…

Combined gold and silicon nano-system has spurred tremendous interest in the scientific community due to its application in different metal-semiconductor electronic devices and solar driven water splitting cells. Silicon, fabricated on gold…

Materials Science · Physics 2024-06-19 Shahriar Nahian , Shahriar Muhammad Nahid , Mohammad Motalab , Pritom Bose

Honeycomb structures lead to conically degenerate points on the dispersion surfaces. These spectral points, termed as Dirac points, are responsible for various topological phenomena. In this paper, we investigate the generalized…

Analysis of PDEs · Mathematics 2024-02-23 Borui Miao , Yi Zhu

By means of ab initio molecular dynamics and band structure calculations, as well as using calculated STM images, we have singled out one structural model for the (3x2) reconstruction of the Si-terminated (001) surface of cubic SiC, amongst…

Materials Science · Physics 2009-10-31 L. Pizzagalli , A. Catellani , G. Galli , F. Gygi , A. Baratoff

In this study, we systematically investigated the structural, mechanical, electronic and optical properties of Sn2Bi monolayer, a sheet experimentally synthesized recently [PRL, 121, 126801 (2018)] which has been hydrogenated (Sn2BiH2) to…

Materials Science · Physics 2020-01-29 Mohammad Ali Mohebpour , Sahar Izadi Vishkayi , Meysam Bagheri Tagani

Atomically precise thiolate-stabilized gold nanoclusters are currently of interest for many cross-disciplinary applications in chemistry, physics and molecular biology. Very recently, synthesis and electronic properties of "nanoalloy"…

Atomic and Molecular Clusters · Physics 2011-09-05 Sami Malola , Hannu Häkkinen

Structural phase transitions between semiconductors and topological insulators have rich applications in nanoelectronics but are rarely found in two-dimensional (2D) materials. In this work, by combining ab initio computations and…

Materials Science · Physics 2021-02-24 Xin Chen , Raquel Esteban-Puyuelo , Linyang Li , Biplab Sanyal

We study the dipole formation at the surface formed by -CH3 and -CF3 terminated shortchain alkyl-thiolate monolayers on Au(111). In particular, we monitor the change in work function upon chemisorption using density functional theory…

Materials Science · Physics 2007-05-23 P. C. Rusu , G. Brocks

We have carried out an ab-initio study of $\alpha$-Sn (111), with the aim of predicting and understanding its structure, reconstructions, and electronic states. We consider a variety of structural possibilities, and optimize them by moving…

Condensed Matter · Physics 2009-10-28 Zhong-Yi Lu , Guido L. Chiarotti , S. Scandolo , E. Tosatti