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The lattice dynamics of TiO$_2$ in the rutile crystal structure was studied by a combination of thermal diffuse scattering, inelastic x-ray scattering and density functional perturbation theory. We experimentally confirm the existence of an…

Materials Science · Physics 2016-01-13 Björn Wehinger , Alexeï Bosak , Paweł T. Jochym

In this paper, I demonstrate a density functional theory plus dynamical mean field theory study on the electronic properties of doped $TiO_2$ rutile as well as another tetragonal phase anatase with oxygen vacancy. The density of states and…

Strongly Correlated Electrons · Physics 2021-12-24 S. Koley

We carried out density functional theory calculations to model the electronic structure and the magnetic interactions in copper doped anatase and rutile titanium dioxide in order to shed light on the potential of these systems as magnetic…

Materials Science · Physics 2013-08-26 M. Hussein. N. Assadi , Dorian A. H. Hanaor

The ferroelectric trends of rutile (TiO$_2$) in bulk and at the (110) surface are investigated by means of ab initio density functional theory. We discuss the underlying mechanism of the incipient ferroelectric behavior of rutile in terms…

Materials Science · Physics 2015-06-12 Anna Grünebohm , Peter Entel , Claude Ederer

Room-temperature ferromagnetism has been recently discovered in Co-doped TiO$_2$ rutile. Our $ab$ $initio$ density-functional theory investigations show that the substitutional Co ions incorporated into TiO$_2$ rutile tend to cluster and…

Materials Science · Physics 2007-05-23 W. T. Geng , K. S. Kim

A combination of Scanning Tunneling Microscopy/Spectroscopy and Density Functional Theory (DFT+U) is used to characterize excess electrons in TiO$_2$ rutile and anatase, two prototypical materials with identical chemical composition but…

We present ab initio time-dependent-density-functional calculations and non-resonant inelastic x-ray scattering measurements of the dynamical structure factor of rutile TiO2. Our calculations are in good agreement with experiment and prove…

Materials Science · Physics 2009-11-10 I. G. Gurtubay , Wei Ku , J. M. Pitarke , A. G. Eguiluz , B. C. Larson , J. Tischler , P. Zschack

Titanium dioxide has been extensively studied in the rutile or anatase phases, while its high-pressure phases are less well understood, despite that many are thought to have interesting optical, mechanical and electrochemical properties.…

Materials Science · Physics 2022-03-14 Jacob G. Lee , Chris J. Pickard , Bingqing Cheng

Using density-functional theory (DFT) we calculate the Gibbs free energy to determine the lowest-energy structure of a RuO_2(110) surface in thermodynamic equilibrium with an oxygen-rich environment. The traditionally assumed stoichiometric…

Materials Science · Physics 2009-11-07 Karsten Reuter , Matthias Scheffler

Using first-principal density functional theory (DFT) we explained the importance of pseudopotential for decribing the electronic and vibrational properties of rutile TiO2 (R-TiO2). Calculations were performed using the generalized gradient…

Chemical Physics · Physics 2018-11-12 Sugata Chowdhury , Nacole King , Winnie Wong-Ng

We derive simple analytical expressions for the particle density $\rho(r)$ and the kinetic energy density $\tau(r)$ for a system of noninteracting fermions in a $d-$dimensional isotropic harmonic oscillator potential. We test the…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 Matthias Brack , Brandon P. van Zyl

The martensitic {\alpha} --> {\omega} transition was investigated in Ti under hydrostatic pressure. The calculations were carried out using the density functional theory (DFT) framework in combination with the Birch-Murnaghan equation of…

Materials Science · Physics 2013-10-07 M. Jafari , M. Nobakhti , H. Jamnezhad , K. Bayati

Electron dynamics of anatase TiO$_2$ under the influence of ultrashort and intense laser field is studied using the real-time time-dependent density functional theory (TDDFT). Our findings demonstrate the effectiveness of TDDFT calculations…

Atomic and electronic structures of TiO_2(110) surface with possible adsorptional, substitutional and interstitial Au or Pt elemental impurities at full and one-sixth monolayer concentrations were investigated by density functional theory…

Strongly Correlated Electrons · Physics 2012-11-19 Ersen Mete , Oğuz Gülseren , Şinasi Ellialtıoğlu

We introduce an open-source, fully atomistic second-principles interatomic potential for lead titanate (PbTiO3), a benchmark ferroelectric material known for its strong polarization and hightemperature phase transitions. While density…

Materials Science · Physics 2025-10-10 Louis Bastogne , Philippe Ghosez

We determine the stability and properties of interfaces of low-index Au surfaces adhered to TiO2(110), using density functional theory energy density calculations. We consider Au(100) and Au(111) epitaxies on rutile TiO2(110) surface, as…

Materials Science · Physics 2012-02-28 Min Yu , Dallas R. Trinkle

A detailed reexamination of the (110) surface structure of rutile TiO2 has been carried out using first-principles total-energy methods. This investigation is in response to a recent high-precision LEED-IV measurement revealing certain…

Materials Science · Physics 2009-11-11 Scott J. Thompson , Steven P. Lewis

Transition metal oxides are considered promising thermoelectric materials for harvesting high-temperature waste heat due to their stability, abundance and low toxicity. Despite their typically strong ionic character, they can exhibit…

Materials Science · Physics 2019-12-04 Simon Thébaud , Christophe Adessi , Georges Bouzerar

Rutile TiO2 is a paradigmatic transition metal oxide with applications in optics, electronics, photocatalysis, etc., that are subject to pervasive electron-phonon interaction. To understand how energies of its electronic bands, and in…

In this paper the relationship between the density functional theory of freezing and phase field modeling is examined. More specifically a connection is made between the correlation functions that enter density functional theory and the…

Materials Science · Physics 2007-05-23 K. R. Elder , Nikolas Provatas , Joel Berry , Peter Stefanovic , Martin Grant
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