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We investigated the photocurrent in poly(3-hexylthiophene-2,5-diyl) (P3HT):[6,6]-phenyl-C$_{61}$ butyric acid methyl ester (PCBM) solar cells by applying a pulsed measurement technique. For annealed samples, a point of optimal symmetry…

Materials Science · Physics 2010-02-02 M. Limpinsel , A. Wagenpfahl , M. Mingebach , C. Deibel , V. Dyakonov

We present a pipeline to study the device performance of organic solar cells in silico. We introduce a mathematical model that includes the dynamics of excitons as well as their dissociation at bulk heterojunctions within the nanomorphology…

Understanding the relationship between morphology and performance in organic solar cells is essential for developing devices that are both high performing and resilient to aging. This work introduces a unique method capable of calculating…

Materials Science · Physics 2026-05-20 Yasin Ameslon , Larry Lüer , Jens Harting , Olga Wodo , Olivier J. J. Ronsin

The open circuit voltage Voc and the corresponding charge carrier density were measured in dependence of temperature and illumination intensity by current-voltage and charge extraction measurements for P3HT:PCBM and P3HT:bisPCBM solar…

Materials Science · Physics 2011-10-05 Daniel Rauh , Alexander Wagenpfahl , Carsten Deibel , Vladimir Dyakonov

Transient photovoltage (TPV) and voltage dependent charge extraction (CE) measurements were applied to poly(3-hexylthiophene)(P3HT):[6,6]-phenyl-C61 butyric acid methyl ester (PCBM) bulk heterojunction solar cells to analyze the limitations…

Materials Science · Physics 2012-08-23 Markus Gluecker , Alexander Foertig , Vladimir Dyakonov , Carsten Deibel

The performance of organic solar cells strongly depends on the bulk heterojunction (BHJ) morphology of the photoactive layer. This BHJ forms during the drying of the wet-deposited solution, because of physical processes such as…

Materials Science · Physics 2022-09-29 Olivier Ronsin , Jens Harting

Organic heterojunction solar cells are analyzed within a minimal model that includes the essential physical features of such systems. The dynamical properties of this model, calculated using a master equation approach, account for the…

Materials Science · Physics 2011-11-11 Mario Einax , Marcel Dierl , Abraham Nitzan

The physics of organic bulk heterojunction solar cells is studied within a six state model, which is used to analyze the factors that affect current-voltage characteristics, power-voltage properties and efficiency, and their dependence on…

Materials Science · Physics 2015-06-18 Mario Einax , Marcel Dierl , Philip R. Schiff , Abraham Nitzan

In polymer:fullerene solar cells, the origin of the losses in the field-dependent photocurrent is still controversially debated. We contribute to the ongoing discussion by performing photo-induced charge extraction measurements on…

Materials Science · Physics 2009-12-03 C. Deibel

The photocurrent density-voltage (J(V)) curve is the fundamental characteristic to assess opto-electronic devices, in particular solar cells. However, it only yields information on the performance integrated over the entire active device…

We investigated the influence of oxygen on the performance of P3HT:PCBM (poly(3-hexylthiophene):[6,6]-phenyl C61 butyric acid methyl ester) solar cells by current--voltage, thermally stimulated current (TSC) and charge extraction by…

The time dependence of device performance has been measured for photocells using blends containing the conjugated polymer, poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) with two different functionalized C60 electron…

Time-dependent measurements of both power conversion efficiency and ultraviolet-visible absorption spectroscopy have been observed for solar cell blends containing the polymer poly(3-hexylthiophene-2,5-diyl) (P3HT) with two different…

Recombination of photogenerated charge carriers in polymer bulk heterojunction (BHJ) solar cells reduces the short circuit current (Jsc) and the fill factor (FF). Identifying the mechanism of recombination is, therefore, fundamentally…

Materials Science · Physics 2015-05-20 Sarah R. Cowan , Anshuman Roy , Alan J. Heeger

Machine learning has emerged as a promising approach for estimating material parameters in solar cells. Traditional methods for parameter extraction often rely on time-consuming numerical simulations that fail to capture the full complexity…

Materials Science · Physics 2025-06-17 Eunchi Kim , Paula Hartnagel , Barbara Urbano , Leonard Christen , Thomas Kirchartz

In this article, we continue our mathematical study of organic solar cells (OSCs) and propose a two-scale (micro- and macro-scale) model of heterojunction OSCs with interface geometries characterized by an arbitrarily complex morphology.…

Numerical Analysis · Mathematics 2012-07-02 Carlo de Falco , Matteo Porro , Riccardo Sacco , Maurizio Verri

We obtain theoretical expressions for the photocurrent in the Heterojunction solar cells with Intrinsic Thin layer (HIT cells). Our calculations take into account tunneling of electrons and holes through wide-bandgap layers of $\alpha$-Si:H…

Open circuit voltage decay measurements are performed on methylammonium lead iodide (CH3NH3PbI3) perovskite solar cells to investigate the charge carrier recombination dynamics. The measurements are compared to the two reference…

Materials Science · Physics 2014-07-07 A. Baumann , K. Tvingstedt , M. C. Heiber , S. Väth , C. Momblona , H. J. Bolink , V. Dyakonov

Numerical simulation of a solar cell can provide various information that can be useful to maximize its power conversion efficiency (PCE). In that respect we carried out a set of numerical simulation using AFORS-HET simulation program.…

Optics · Physics 2024-05-13 S. M. Iftiquar , J. Yi

Apparent recombination orders exceeding the value of two expected for bimolecular recombination have been reported for organic solar cells in various publications. Two prominent explanations are bimolecular losses with a carrier…

Soft Condensed Matter · Physics 2012-08-23 D. Rauh , C. Deibel , V. Dyakonov
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