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We present a long-wavelength approximation to the Navier-Stokes Cahn-Hilliard equations to describe phase separation in thin films. The equations we derive underscore the coupled behaviour of free-surface variations and phase separation.…

Analysis of PDEs · Mathematics 2008-05-08 Lennon O Naraigh , Jean-Luc Thiffeault

We study phase separation in thin films using the Navier--Stokes Cahn--Hilliard equations in the lubrication approximation, modeling substrate-film interactions with a van der Waals potential. We investigate the thin-film equations…

Fluid Dynamics · Physics 2007-12-12 Lennon O Naraigh , Jean-Luc Thiffeault

We consider the thin-film equation $\partial_t h + \nabla \cdot \left(h^2 \nabla \Delta h\right) = 0$ in physical space dimensions (i.e., one dimension in time $t$ and two lateral dimensions with $h$ denoting the height of the film in the…

Analysis of PDEs · Mathematics 2018-11-22 Manuel V. Gnann , Mircea Petrache

A thin liquid film covered with an insoluble surfactant in the vicinity of a first-order phase transition is discussed. Within the lubrication approximation we derive two coupled equations to describe the height profile of the film and the…

Pattern Formation and Solitons · Physics 2009-07-15 M. H. Köpf , S. V. Gurevich , R. Friedrich

We consider a class of Cahn-Hilliard equation that characterizes phase separation phenomena of binary mixtures in a bounded domain $\Omega \subset \mathbb{R}^d$ $(d\in \{2,3\})$ with non-permeable boundary. The equations in the bulk are…

Analysis of PDEs · Mathematics 2024-06-03 Maoyin Lv , Hao Wu

We study the instability of a thin film composed of two miscible fluids (binary fluid) placed on a solid planar surface. We include the fact that both the free surface and wetting energies depend on the mixture concentration. By assuming a…

Fluid Dynamics · Physics 2023-07-11 Javier A. Diez , Alejandro G. González , Lou Kondic

In this paper we present a mathematical model to describe the phenomenon of phase separation, which is modelled as space regions where an order parameter changes smoothly. The model proposed, including thermal and mixing effects, is deduced…

Mathematical Physics · Physics 2011-02-08 Alessia Berti , Ivana Bochicchio

The Cahn--Hilliard equation is one of the most common models to describe phase separation processes of a mixture of two materials. For a better description of short-range interactions between the material and the boundary, various dynamic…

Analysis of PDEs · Mathematics 2021-04-27 Patrik Knopf , Kei Fong Lam , Chun Liu , Stefan Metzger

In numerous solution-processed thin films, a complex morphology resulting from liquid-liquid phase separation (LLPS) or from polycrystallization arises during the drying or subsequent processing steps. The morphology has a strong influence…

Applied Physics · Physics 2022-06-28 Olivier J. J. Ronsin , Jens Harting

Differences in activities in colloidal particles are sufficient to drive phase separation between active and passive (or less active) particles, even if they have only excluded volume interactions. In this paper, we study the phase…

Soft Condensed Matter · Physics 2020-05-27 Efe Ilker , Jean-François Joanny

The performance of solution-processed solar cells strongly depends on the geometrical structure and roughness of the photovoltaic layers formed during film drying. During the drying process, the interplay of crystallization and…

We investigate the Cahn-Hilliard equation with nonlinear diffusion and non-degenerate mobility modeling phase separation phenomena in complex systems (e.g., crystals and polymers). Previous results in the literature on this model relied on…

Analysis of PDEs · Mathematics 2025-10-10 Monica Conti , Stefania Gatti , Andrea Giorgini , Giulio Schimperna

In this Letter we investigate the rupture instability of thin liquid films by means of a bifurcation analysis in the vicinity of the short-scale instability threshold. The rupture time estimate obtained in closed form as a function of the…

Fluid Dynamics · Physics 2009-11-10 A. M. Leshansky , B. Y. Rubinstein

We consider the Cahn-Hilliard equation with Neumann boundary conditions in a three-dimensional curved thin domain around a given closed surface. When the thickness of the curved thin domain tends to zero, we show that the weighted average…

Analysis of PDEs · Mathematics 2025-12-16 Tatsu-Hiko Miura

The paper presents a model of lateral phase separation in a two component material surface. The resulting fourth order nonlinear PDE can be seen as a Cahn-Hilliard equation posed on a time-dependent surface. Only elementary tangential…

Numerical Analysis · Mathematics 2020-03-18 Vladimir Yushutin , Annalisa Quaini , Maxim Olshanskii

The Cahn-Hilliard equation is the most common model to describe phase separation processes of a mixture of two components. For a better description of short-range interactions of the material with the solid wall, various dynamic boundary…

Analysis of PDEs · Mathematics 2020-10-20 Harald Garcke , Patrik Knopf

We derive a novel thermodynamically consistent Navier--Stokes--Cahn--Hilliard system with dynamic boundary conditions. This model describes the motion of viscous incompressible binary fluids with different densities. In contrast to previous…

Analysis of PDEs · Mathematics 2023-10-25 Andrea Giorgini , Patrik Knopf

The Cahn--Hilliard equation is a fundamental model that describes phase separation processes of binary mixtures. In recent years, several types of dynamic boundary conditions have been proposed in order to account for possible short-range…

Analysis of PDEs · Mathematics 2023-07-28 Chun Liu , Hao Wu

We consider the incompressible flow of two immiscible fluids in the presence of a solid phase that undergoes changes in time due to precipitation and dissolution effects. Based on a seminal sharp interface model a phase field approach is…

Analysis of PDEs · Mathematics 2019-12-20 Christian Rohde , Lars von Wolff

We consider phase-field models with and without lateral flow for the numerical simulation of lateral phase separation and coarsening in lipid membranes. For the numerical solution of these models, we apply an unfitted finite element method…

Numerical Analysis · Mathematics 2023-06-02 Maxim Olshanskii , Yerbol Palzhanov , Annalisa Quaini
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