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Related papers: Quantum Work Relations under Trial Hamiltonians

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We give a quantum version of the Jarzynski relation between the distribution of work done over a certain time-interval on a system and the difference of equilibrium free energies. The main new ingredient is the identification of work…

Condensed Matter · Physics 2015-05-26 Wojciech De Roeck , Christian Maes

A universal quantum work relation is proved for isolated time-dependent Hamiltonian systems in a magnetic field as the consequence of microreversibility. This relation involves a functional of an arbitrary observable. The quantum Jarzynski…

Statistical Mechanics · Physics 2009-11-13 David Andrieux , Pierre Gaspard

The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasi-static process. This fluctuation…

Quantum Physics · Physics 2025-08-21 Konstantin Beyer , Walter T. Strunz

Free energy fixes the maximum work of a thermodynamic process once the state and Hamiltonian are specified. A work-extraction task asks a different question: how much average work can a single device realize across several preparations and…

Quantum Physics · Physics 2026-05-06 Sumit Rout , Aravinth Balaji Ravichandran , Paweł Horodecki , Anubhav Chaturvedi

The connection between work and changes in the Hamiltonian for a system with a time-dependent Hamiltonian has recently been called into question, casting doubt on the usefulness of the Jarzynski equality for calculating free energy changes.…

Statistical Mechanics · Physics 2015-05-13 Eric N. Zimanyi , Robert J. Silbey

The characteristic function of the work performed by an external time-dependent force on a Hamiltonian quantum system is identified with the time-ordered correlation function of the exponentiated system's Hamiltonian. A similar expression…

Statistical Mechanics · Physics 2009-11-13 Peter Talkner , Eric Lutz , Peter Hanggi

Work is an observable quantity associated with a process, however there is no Hermitian operator associated with its measurement. We consider an ancilla-assisted protocol measuring the work done on a quantum system driven by a…

Quantum Physics · Physics 2022-05-18 Shadi Ali Ahmad , Alexander R. H. Smith

In this work, we show that a universal quantum work relation for a quantum system driven arbitrarily far from equilibrium extend to $\mathcal{PT}$-symmetric quantum system with unbroken $\mathcal{PT}$ symmetry, which is a consequence of…

Statistical Mechanics · Physics 2018-01-17 Bo-Bo Wei

The validity of the Jarzynski equation for a very simple, exactly solvable quantum system is analyzed. The implications of two different definitions of work proposed in the literature are investigated. The first one derives from…

Statistical Mechanics · Physics 2009-11-11 A. Engel , R. Nolte

A result of great theoretical and experimental interest, Jarzynski equality predicts a free energy change $\Delta F$ of a system at inverse temperature $\beta$ from an ensemble average of non-equilibrium exponential work, i.e., $\langle…

Statistical Mechanics · Physics 2017-10-18 Juan D. Jaramillo , Jiawen Deng , Jiangbin Gong

Recent years have witnessed major advances in our understanding of nonequilibrium processes. The Jarzynski equality, for example, provides a link between equilibrium free energy differences and finite-time, nonequilibrium dynamics. We…

Statistical Mechanics · Physics 2016-04-27 Dibyendu Mandal , Michael R. DeWeese

Nonequilibrium work-Hamiltonian connection for a microstate plays a central role in diverse branches of statistical thermodynamics (fluctuation theorems, quantum thermodynamics, stochastic thermodynamics, etc.). We show that the change in…

Statistical Mechanics · Physics 2017-02-03 P. D. Gujrati

Work is a process-based quantity, and its measurement typically requires interaction with a measuring device multiple times. While classical systems allow for non-invasive and accurate measurements, quantum systems present unique challenges…

Quantum Physics · Physics 2025-06-17 Giulia Rubino , Karen V. Hovhannisyan , Paul Skrzypczyk

The imaginary-time path integral representation of the canonical partition function of a quantum system and non-equilibrium work fluctuation relations are combined to yield methods for computing free energy differences in quantum systems…

Statistical Mechanics · Physics 2009-11-13 Ramses van Zon , Lisandro Hernandez de la Pena , Gilles H. Peslherbe , Jeremy Schofield

We discuss the thermodynamics of closed quantum systems driven out of equilibrium by a change in a control parameter and undergoing a unitary process. We compare the work actually done on the system with the one that would be performed…

Quantum Physics · Physics 2015-01-20 F. Plastina , A. Alecce , T. J. G. Apollaro , G. Falcone , G. Francica , F. Galve , N. Lo Gullo , R. Zambrini

The relation between the distribution of work performed on a classical system by an external force switched on an arbitrary timescale, and the corresponding equilibrium free energy difference, is generalized to quantum systems. Using the…

Statistical Mechanics · Physics 2007-05-23 Shaul Mukamel

A superconducting cavity model was proposed as a way to experimentally investigate the work performed in a quantum system. We found a simple mathematical relationship between the free energy variation and visibility measurement in quantum…

A quantum analogue of the Jarzynski equality is constructed. This equality connects an ensemble average of exponentiated work with the Helmholtz free-energy difference in a nonequilibrium switching process subject to a thermal heat bath. To…

Statistical Mechanics · Physics 2009-10-31 Satoshi Yukawa

We consider a (small) quantum mechanical system which is operated by an external agent, who changes the Hamiltonian of the system according to a fixed scenario. In particular we assume that the agent (who may be called a demon) performs…

Statistical Mechanics · Physics 2015-05-20 Yohei Morikuni , Hal Tasaki

The Jarzynski equality equates the mean of the exponential of the negative of the work (per fixed temperature) done by a changing Hamiltonian on a system, initially in thermal equilibrium at that temperature, to the ratio of the final to…

High Energy Physics - Theory · Physics 2012-07-17 Don N. Page
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