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The solid-state electrolyte is critical for achieving next-generation high energy density and high-safety batteries. Solid polymer electrolytes (SPEs) possess great potential for commercial application owing to their compatibility with the…

Materials Science · Physics 2023-07-04 Xiong Xiong Liu , Shengfa Feng , Pengcheng Yuan , Yaping Wang , Long Pan , ZhengMing Sun

Electron-glasses can be readily driven far from equilibrium by a variety of means. Several mechanisms to excite the system and their relative merits are reviewed. In this study we focus on the process of exciting electron-glasses by…

Strongly Correlated Electrons · Physics 2011-06-22 Z. Ovadyahu

Enhancing the ion conduction in solid electrolytes is critically important for the development of high-performance all-solid-state lithium-ion batteries (LIBs). Lithium thiophosphates are among the most promising solid electrolytes, as they…

Materials Science · Physics 2024-01-11 Zhimin Chen , Tao Du , N. M. Anoop Krishnan , Yuanzheng Yue , Morten M. Smedskjaer

Understanding ion-transport under molecular confinement is essential for developing next-generation energy technologies, where ionic motion often occurs within nanoscale or angstrom-scale channels. In this study, we use the model system of…

We describe a model for the thermodynamics and dynamics of glass-forming liquids in terms of excitations from an ideal glass state to a Gaussian manifold of configurationally excited states. The quantitative fit of this three parameter…

Soft Condensed Matter · Physics 2015-06-25 Dmitry V. Matyushov , C. A. Angell

All-solid-state lithium-ion batteries have renewed interest in high-performance solid electrolytes. Li3PS4 (Li2S-P2S5) glasses are among the most studied due to their high ionic conductivity, traditionally ascribed to rotational motion of…

Materials Science · Physics 2026-02-27 J. Pawelko , X. Rocquefelte , A. Tetenoire , D. Le Coq , L. Calvez , E. Furet

We provide broadband dielectric loss spectra of glass-forming glycerol with varying additions of LiCl. The measurements covering frequencies up to 10 THz extend well into the region of the fast beta process, commonly ascribed to caged…

Soft Condensed Matter · Physics 2013-08-07 M. Köhler , P. Lunkenheimer , Y. Goncharov , A. Loidl

Mechanochemically synthesized amorphous 50SISOMO [50AgI-25Ag_2O-25MoO_3] fast ionic conductor shows high ionic conductivity of ~ 6x10^-3 {\Omega}^-1 cm-1 at room temperature. The highest ionic conductivity is achieved for 36 h milled…

Materials Science · Physics 2012-04-10 Saurabh Dayal , K. Shahi

Molecular dynamics simulations are performed to study the lithium jumps in LiPO3 glass. In particular, we calculate higher-order correlation functions that probe the positions of single lithium ions at several times. Three-time correlation…

Condensed Matter · Physics 2009-11-10 Michael Vogel

In the framework of topological constraint theory, network glasses are classified as flexible, stressed--rigid, or isostatic if the number of atomic constraints is smaller, larger, or equal to the number of atomic degrees of freedom. Here,…

Materials Science · Physics 2018-12-13 Ernest Ching , Mathieu Bauchy

We use time-domain electrostatic force spectroscopy (TD-EFS) for characterising the dynamics of mobile ions in a partially crystallised LiAlSiO$_4$ glass ceramic, and we compare the results of the TD-EFS measurements to macroscopic…

Variation of fragility (m) of specially homogenized GexSe100-x melts are established from complex specific heat measurements, and show m(x) has a global minimum at an extremely low value (m=14.8(0.5)) in the 21.5%<x<23% range of Ge. Outside…

Disordered Systems and Neural Networks · Physics 2015-06-17 K. Gunasekera , S. Bhosle , P. Boolchand , M. Micoulaut

Characterizing the frequency-dependent response of amorphous systems and glasses can provide important insights into their physics. Here, we study the response of an electron glass, where Coulomb interactions are important and have…

Disordered Systems and Neural Networks · Physics 2015-06-19 Ariel Amir

Finding new ionic conductors that enable significant advancements in the development of energy-storage devices is a challenging goal of current material science. Aside of material classes as ionic liquids or amorphous ion conductors, the…

Materials Science · Physics 2015-09-02 K. Geirhos , P. Lunkenheimer , M. Michl , D. Reuter , A. Loidl

We present a combined study of thermal expansion and resistance fluctuation spectroscopy measurements exploring the static and dynamic aspects of the charge-glass formation in the quasi-two-dimensional organic conductors…

Strongly Correlated Electrons · Physics 2022-02-03 Tatjana Thomas , Yohei Saito , Yassine Agarmani , Tim Thyzel , Kenichiro Hashimoto , Takahiko Sasaki , Michael Lang , Jens Müller

We present a study of the relaxation dynamics of the photoexcited conductivity of the impurity states in the low-density electronic glass, phosphorous-doped silicon Si:P. Using optical pump-terahertz probe spectroscopy we find strongly…

Disordered Systems and Neural Networks · Physics 2010-09-16 V. K. Thorsmølle , N. P. Armitage

A c-axis magnetotransport and resistance noise study in La_{1.97}Sr_{0.03}CuO_{4} reveals clear signatures of glassiness, such as hysteresis, memory, and slow, correlated dynamics, but only at temperatures (T) well below the spin glass…

Strongly Correlated Electrons · Physics 2008-12-11 I. Raicevic , J. Jaroszynski , Dragana Popovic , C. Panagopoulos , T. Sasagawa

We present a promising mode coupling theory study for the relaxation and glassy dynamics of a system of strongly interacting self-propelled particles, wherein the self-propulsion force is described by Ornstein-Uhlenbeck colored noise and…

Soft Condensed Matter · Physics 2017-02-28 Mengkai Feng , Zhonghuai Hou

We consider the stationary state of a fluid comprised of inelastic hard spheres or disks under the influence of a random, momentum-conserving external force. Starting from the microscopic description of the dynamics, we derive a nonlinear…

Statistical Mechanics · Physics 2013-02-25 W. T. Kranz , M. Sperl , A. Zippelius

Glassy systems are disordered systems characterized by extremely slow dynamics. Examples are supercooled liquids, whose dynamics slow down under cooling. The specific pattern of slowing-down depends on the material considered. This…

Disordered Systems and Neural Networks · Physics 2016-04-12 Le Yan