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We solve a long standing problem with relativistic calculations done with the widely used Multi-Configuration Dirac-Fock Method (MCDF). We show, using Relativistic Many-Body Perturbation Theory (RMBPT), how even for relatively high-$Z$,…

Atomic Physics · Physics 2007-05-23 Paul Indelicato , Eva Lindroth , Jean-Paul Desclaux

The multiconfiguration Dirac-Fock (MCDF) model uses a linear combination of Slater determinants to approximate the electronic $N$-body wave function of a relativistic molecular system, resulting in a coupled system of nonlinear eigenvalue…

Mathematical Physics · Physics 2015-06-15 Antoine Levitt

An overview on various results concerning the Dirac-Fock model, the various variational characterization of its solutions and its nonrelativistic limit. A notion of ground state for this totally unbounded is also defined.

Analysis of PDEs · Mathematics 2017-08-23 Maria J. Esteban , Eric séré

Creation and manipulation of non-classical states of light is rapidly becoming the focus of modern attosecond science. Here, we demonstrate numerically how interaction with such states can trigger the emergence of a many-body system with…

Quantum Physics · Physics 2026-05-15 Nikolai D. Klimkin , Misha Ivanov

The combination of linear and nonlinear potentials, both shaped as a single well, enables competition between the confinement and expulsion induced by the former and latter potentials, respectively. We demonstrate that this setting leads to…

Pattern Formation and Solitons · Physics 2018-10-18 Dmitry A. Zezyulin , Mikhail E. Lebedev , Georgy L. Alfimov , Boris A. Malomed

We test a set of multiconfigurational wavefunction approaches for calculating the ground state electron population for a two-site Anderson model representing a molecule on a metal surface. In particular, we compare (i) a Hartree Fock like…

Chemical Physics · Physics 2022-07-19 Junhan Chen , Wenjie Dou , Joseph Subotnik

We study theoretically the electron states in a system of two vertically stacked quantum dots. We investigate the influence of the geometrical symmetry breaking (caused by the displacement as well as the ellipticity of the dots) on the…

Mesoscale and Nanoscale Physics · Physics 2014-09-05 Krzysztof Gawarecki , Paweł Machnikowski , Tilmann Kuhn

We analytically compute, in the first Born approximation for symmetric and asymmetric coplanar geometries, the triple differential cross sections for electron-impact ionization of hydrogen atom in the metastable 2S-state at both low and…

Atomic Physics · Physics 2020-11-20 M. Jakha , S. Mouslih , S. Taj , B. Manaut

We investigate symmetry-breaking phenomena in semilinear elliptic systems on the unit ball in $\mathbb{R}^3$, focusing on the emergence of non-radial solution branches with prescribed spatial and internal symmetries. Extending previous…

Analysis of PDEs · Mathematics 2025-12-18 Casey Crane , Ziad Ghanem

Coherent state path integrals are applied to a many-body problem for non-relativistic electrons in a central potential and an external magnetic field; however, in comparison to previous coherent state path integrals, we definitely fix the…

Statistical Mechanics · Physics 2009-06-16 Bernhard Mieck

The Hartree-Fock states of the many-electron atomic system can be unstable with respect to a static or dynamic shift of the electron shells. An appropriate non-rigid shell model for atomic clusters is developed. It permits to formulate a…

Strongly Correlated Electrons · Physics 2009-10-30 A. S. Moskvin , V. A. Korotaev , Yu. D. Panov , M. A. Sidorov

We consider the Hamiltonian coupled-mode system that occur in nonlinear optics, photonics, and atomic physics. Spectral stability of gap solitons is determined by eigenvalues of the linearized coupled-mode system, which is equivalent to a…

Dynamical Systems · Mathematics 2009-11-11 M. Chugunova , D. Pelinovsky

Isotope shift of atomic spectra is considered as a probe of new interaction between electrons and neutrons in atoms. We employ the method of seeking a breakdown of King's linearity in the isotope shifts of two atomic transitions. In the…

High Energy Physics - Phenomenology · Physics 2020-10-14 Minoru Tanaka , Yasuhiro Yamamoto

The Interacting Boson Model of nuclear structure is introduced to the unitarity limit. Non relativistic conformal symmetry creates a scale invariant state from which the stationary states of atomic nuclei are obtained. A brief discussion of…

Nuclear Theory · Physics 2019-03-14 P. E. Georgoudis

We investigate the relativistic effects of a moving particle in the field of a pseudo-harmonic oscillatory ring-shaped potential under the spin and pseudo-spin symmetric Dirac wave equation. We obtain the bound state energy eigenvalue…

Quantum Physics · Physics 2017-04-05 Mahdi Eshgh , Hussain Mehraban , Sameer M. Ikhdair

The scalar field is quantized in the discretized light-front framework following the {\em standard} Dirac procedure and its infinite volume limit taken. The background field and the nonzero mode variables do not commute for finite volume;…

High Energy Physics - Theory · Physics 2007-05-23 Prem P. Srivastava

The bound state spectra of the doublet states in three-electron atomic systems are investigated. By using different variational expansions we determine various bound state properties in these systems. Such properties include the…

Atomic Physics · Physics 2015-06-19 Alexei M. Frolov , Maria Belen Ruiz , David M. Wardlaw

Atomic properties such as field shift constants, magnetic dipole and electric quadrupole hyperfine structure constants, Land\'e $g_J$ factors, and electric quadrupole moments that are described by electronic operators with different ranks…

Atomic Physics · Physics 2018-03-14 Pradeep Kumar , Cheng-Bin Li , B. K. Sahoo

The symmetry-projected Hartree--Fock ansatz for the electronic structure problem can efficiently account for static correlation in molecules, yet it is often unable to describe dynamic correlation in a balanced manner. Here, we consider a…

Strongly Correlated Electrons · Physics 2015-06-17 Carlos A. Jiménez-Hoyos , R. Rodríguez-Guzmán , Gustavo E. Scuseria

Perturbation theory is used systematically to investigate the symmetries of the Dirac Hamiltonian and their breaking in atomic nuclei. Using the perturbation corrections to the single-particle energies and wave functions, the link between…

Nuclear Theory · Physics 2011-04-15 Haozhao Liang , Pengwei Zhao , Ying Zhang , Jie Meng , Nguyen Van Giai
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