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A fundamental weakness of density functional theory (DFT) is the difficulty in making systematic improvements to approximations for the exchange and correlation functionals. In this paper, we follow a wave-function-based approach [N.I.…

Chemical Physics · Physics 2018-10-05 Timothy J. Callow , Nikitas I. Gidopoulos

Configuration Interaction (CI) calculations on the ground state of the C atom are carried out using a small basis set of Slater orbitals [7s6p5d4f3g]. The configurations are selected according to their contribution to the total energy. One…

Atomic Physics · Physics 2017-08-01 María Belén Ruiz , Robert Tröger

Fractional Chern insulators (FCI) were proposed theoretically about a decade ago. These exotic states of matter are fractional quantum Hall states realized when a nearly flat Chern band is partially filled, even in the absence of an…

Strongly Correlated Electrons · Physics 2023-12-12 Xiaodong Hu , Di Xiao , Ying Ran

Employing a local formula for the electron-electron interaction energy, we derive a self-consistent approximation for the total energy of a general $N$-electron system. Our scheme works as a local variant of the Thomas-Fermi approximation…

Chemical Physics · Physics 2013-10-31 E. Rasanen , A. Odriazola , I. Makkonen , A. Harju

Despite of its huge successes in vast amount of applications, the Kohn-Sham scheme of density functional theory (DFT-Kohn-Sham) has not been able to get reliable ionization potentials (IP) for semiconductors, due to self-interaction error…

Materials Science · Physics 2016-04-07 Lin-Hui Ye

The exchange-correlation energy in Kohn-Sham density functional theory is expressed as a functional of the electronic density and the Kohn-Sham orbitals. An alternative to Kohn-Sham theory is to express the energy as a functional of the…

Computational Physics · Physics 2009-10-31 S. Goedecker , C. Umrigar

Full Waveform Inversion (FWI) is a successful and well-established inverse method for reconstructing material models from measured wave signals. In the field of seismic exploration, FWI has proven particularly successful in the…

Computational Engineering, Finance, and Science · Computer Science 2023-12-05 Tim Bürchner , Philipp Kopp , Stefan Kollmannsberger , Ernst Rank

Variational (Rayleigh-Ritz) methods are applied to local quantum field theory. For scalar theories the wave functional is parametrized in the form of a superposition of Gaussians and the expectation value of the Hamiltonian is expressed in…

High Energy Physics - Theory · Physics 2016-08-25 George Tiktopoulos

The effective potential of electron--electron interaction and the two-particle \textquotedblleft density--density\textquotedblright\ correlation function have been calculated for a simple semiinfinite metal making allowance for the…

Mesoscale and Nanoscale Physics · Physics 2015-03-29 B. M. Markovych , I. M. Zadvorniak

One-dimensional multi-component Fermi or Bose systems with strong zero-range interactions can be described in terms of local exchange coefficients and mapping the problem into a spin model is thus possible. For arbitrary external confining…

The universal functional of Hohenberg-Kohn is given as a coupling-constant integral over the density as a functional of the potential. Conditions are derived under which potential-functional approximations are variational. Construction via…

Other Condensed Matter · Physics 2011-06-13 Attila Cangi , Donghyung Lee , Peter Elliott , Kieron Burke , E. K. U. Gross

Full-Waveform Inversion (FWI) is a high-resolution technique used in geophysics to evaluate the physical parameters and construct subsurface models in a noisy and limited data scenario. The ill-posed nature of the FWI turns this a…

We investigate the dynamics of spontaneous fission in a configuration-interaction (CI) approach. In that formalism the decay rate is governed by an effective interaction coupling the ground-state configuration and a fission doorway…

Nuclear Theory · Physics 2020-08-19 K. Hagino , G. F. Bertsch

Composite fermion wavefuctions have been used to describe electrons in a strong magnetic field. We show that the polynomial part of these wavefunctions can be obtained by applying a normal ordered product of suitably defined annihilation…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 V. Ruuska , M. Manninen

Quantum computers promise to revolutionise electronic simulations by overcoming the exponential scaling of many-electron problems. While electronic wave functions can be represented using a product of fermionic unitary operators, shallow…

Quantum Physics · Physics 2022-07-04 Hugh G. A. Burton , Daniel Marti-Dafcik , David P. Tew , David J. Wales

Recent variational studies have demonstrated that the strongly correlated ground states of the fractional quantum Hall (FQH) effect can be captured using machine learning approaches starting from no prior knowledge of the underlying…

Strongly Correlated Electrons · Physics 2025-12-02 Mytraya Gattu

Antiferromagnetic and charge ordered Hartree-Fock solutions of the one-band Hubbard model with on-site and nearest-neighbor Coulomb repulsions are exactly mapped onto an auxiliary local Kohn-Sham (KS) problem within a density-functional…

Strongly Correlated Electrons · Physics 2007-05-23 I. V. Solovyev

In this work we propose a novel approach to solve the Schr\"{o}dinger equation which combines projection onto the ground state with a path-filtering truncation scheme. The resulting projector configuration interaction (PCI) approach…

Chemical Physics · Physics 2016-06-29 Tianyuan Zhang , Francesco A. Evangelista

In a previous paper we proposed a Projected Configuration Interaction method that uses sets of axially deformed single particle states to build up the many body basis. We show that the choice of the basis set is essential for the efficiency…

Nuclear Theory · Physics 2013-05-29 Zao-Chun Gao , Mihai Horoi , Y. S. Chen

The higher dimensional quantum Hall liquid constructed recently supports stable topological membrane excitations. Here we introduce a microscopic interacting Hamiltonian and present its exact ground state wave function. We show that this…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Shou-Cheng Zhang