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A viable qubit must have a long coherence time $T_2$. In molecular nanomagnets $T_2$ is often limited at low temperatures by the presence of dipole and hyperfine interactions, which are often mitigated through sample dilution, chemical…

Recent experimental progress in cooling, trapping, and quantum logic spectroscopy of highly-charged ions (HCIs) made HCIs accessible for high resolution spectroscopy and precision fundamental studies. Based on these achievements, we explore…

We calculate the shift, due to interatomic interactions, of an optical transition in an atomic Fermi gas trapped in an optical lattice, as in recent experiments of Campbell {\it et al.}, Science {\bf 324}, 360 (2009). Using a pseudospin…

Quantum Gases · Physics 2010-01-11 Zhenhua Yu , C. J. Pethick

Recent developments in frequency metrology and optical clocks have been based on electronic transitions in atoms and singly charged ions as references. These systems have enabled relative frequency uncertainties at a level of a few parts in…

Atomic Physics · Physics 2018-12-06 M. G. Kozlov , M. S. Safronova , J. R. Crespo López-Urrutia , P. O. Schmidt

An electronically variational approach to the calculation of atomic hyperfine structure transition energies under the influence of static external electric fields is presented. The method avoids the calculation of intermediate atomic states…

Atomic Physics · Physics 2025-08-29 Timo Fleig

In many applications a source of the black-body radiation (BBR) can be highly anisotropic. This leads to the BBR shift that depends on tensor polarizability and on the projection of the total angular momentum of ions and atoms in a trap. We…

Atomic Physics · Physics 2016-02-23 Victor V. Flambaum , Sergey G. Porsev , Marianna S. Safronova

Bismuth donors ion-implanted in $^{28}$Si and $^\text{nat}$Si are studied using magnetic resonance spectroscopy based on spin dependent recombination. The hyperfine clock transition, at which the linewidth is significantly narrowed, is…

Theoretical prediction of the 2nd-order magnetic transition temperature (TM) used to be arduous. Here, we develop a first principle-based, fully automatic structure-to-TM method for two-dimensional (2D) magnets whose effective Hamiltonians…

Materials Science · Physics 2023-12-08 Haichang Lu , Tai Yang , Zhimei Sun , John Robertson , Weisheng Zhao

First-order phase transitions produce gravitational waves and primordial black holes. They always occur in field theories where symmetries are radiatively broken and masses are correspondingly generated. These theories predict a period of…

High Energy Physics - Phenomenology · Physics 2026-05-19 Alberto Salvio

We demonstrate that several metastable excited states in Hf$~$II, Hf$~$IV and W$~$VI ions may be good clock states since they are sufficiently long-living and are not sensitive to the perturbations. Cooling E1 transitions are available.…

Atomic Physics · Physics 2022-09-20 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

The frequencies of transitions between hyperfine levels of ground-state atoms can be measured with exquisite precision using magnetic-resonance techniques. This makes hyperfine transitions ideal probes of QED effects originating from the…

Quantum Physics · Physics 2021-06-28 Davide Iacobacci , Giuseppe Bimonte , Thorsten Emig

Atomic microwave clocks based on hyperfine transitions, such as the caesium standard, tick with a frequency that is proportional to the magnetic moment of the nucleus. This magnetic moment varies strongly between isotopes of the same atom,…

Atomic Physics · Physics 2011-10-21 J. C. Berengut , V. V. Flambaum , E. M. Kava

Calculations of the magnetic hyperfine structure rely on the input of nuclear properties -- nuclear magnetic moments and nuclear magnetization distributions -- as well as quantum electrodynamic (QED) radiative corrections for high-accuracy…

Atomic Physics · Physics 2018-09-19 J. S. M. Ginges , A. V. Volotka

We consider hyperfine-mediated effects for clock transitions in $^{176}$Lu$^+$. Mixing of fine structure levels due to the hyperfine interaction bring about modifications to Land\'e $g$-factors and the quadrupole moment for a given state.…

Atomic Physics · Physics 2020-09-08 Zhiqiang Zhang , K. J. Arnold , R. Kaewuam , M. S. Safronova , M. D. Barrett

We report the theoretical evaluations of the static scalar polarizability of the 133Cs ground state and of the black body radiation shift induced on the transition frequency between the two hyperfine levels with m_F = 0. This shift is of…

Atomic Physics · Physics 2009-11-10 S. Micalizio , A. Godone , D. Calonico , F. Levi , L. Lorini

To search for the temporal variation of the fundamental constants one needs to know dependence of atomic transition frequencies on these constants. We study the dependence of the hyperfine structure of atomic $s$-levels on nuclear radius…

Atomic Physics · Physics 2010-11-02 T. H. Dinh , A. Dunning , V. A. Dzuba , V. V. Flambaum

We use advanced computational techniques to study the electronic structure of the Hf$^{12+}$ ion, with the goal of assessing its potential for use in highly accurate atomic optical clocks and search for new physics. Such clocks should…

Atomic Physics · Physics 2025-11-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

Magnetic moment of electron at finite temperature is directly related to the modified electron mass in the background heat bath. Magnetic moment of electron gets modified when it couples with the magnetic field at finite temperature through…

High Energy Physics - Theory · Physics 2015-06-04 Samina S. Masood , Mahnaz Q. Haseeb

Black-body radiation (BBR) shift is an important systematic correction for the atomic frequency standards realizing the SI unit of time. Presently, there is a controversy over the value of the BBR shift for the primary $^{133}$Cs standard.…

Atomic Physics · Physics 2009-11-11 K. Beloy , U. I. Safronova , A. Derevianko

Quasi-forbidden electronic transitions in atoms and quasi-degenerate vibronic transitions in molecules serve as powerful probes of hypothetical temporal variations of fundamental constants. Computation of the sensitivity of a transition to…

Chemical Physics · Physics 2025-11-17 Carsten Zülch , Konstantin Gaul , Robert Berger